Citation: LIU Na, ZHANG Hui, XUE Nian-Hua, DING Wei-Ping. Influence of Tungsten Loadings on the 1-Butene Metathesis Reaction over W/SiO₂/Al₂O₃ Catalysts[J]. Acta Physico-Chimica Sinica, ;2015, 31(5): 933-940. doi: 10.3866/PKU.WHXB201503032 shu

Influence of Tungsten Loadings on the 1-Butene Metathesis Reaction over W/SiO₂/Al₂O₃ Catalysts

1.
1 College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, P. R. China;
2 Key Laboratory of Mesoscopic Chemistry of MOE, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China

Received Date: 30 December 2014
Available Online: 3 March 2015
Fund Project: 国家自然科学基金(21403164) (21403164)国家大学生创新创业训练项目(S14024)资助 (S14024)

A series of W/SiO₂/Al₂O₃ catalysts with various tungsten loadings were synthesized via the impregnation method. The as-synthesized catalysts were characterized by X-ray diffraction (XRD), Raman spectroscopy, ultraviolet-visible (UV-Vis) spectroscopy, H2 temperature-programmed reduction (H₂-TPR), and NH₃ temperature-programmed desorption (NH₃-TPD). The results reveal that the tungsten loadings were crucial to the dispersion and reducibility of the tungsten oxide species and the acidity of catalysts. The catalytic performances were also investigated during the metathesis of 1-butene to propene. Amongst these catalysts, W/SiO₂/Al₂O₃ with a tungsten mass fraction of 6.0% gave the highest activity and stability during the 1-butene metathesis reaction. The excellent catalytic performance of the catalyst containing a tungsten mass fraction of 6.0% is attributed to its moderate dispersion, suitable reducibility of the WO_x species and suitable acidity. We speculate that these factors are favorable for the formation of active centers for olefin metathesis.
- 1-Butene,
- Protene,
- Metathesis,
- Tungsten loading,
- Catalytic activity
1. [1]
  
  (1) Lu, H. Q.; Shi, L.; He, C.; Weng, W. Z.; Huang, C. J.; Wan, H. L. Acta Phys. -Chim. Sin. 2012, 28, 2697. [鲁怀乾, 石磊, 何冲, 翁维正, 黄传敬, 万惠霖. 物理化学学报, 2012, 28, 2697.] doi: 10.3866/PKU.WHXB201207091
2. [2]
  (2) Zhu, X. X.; Li, X. J.; Xie, S. J.; Liu, S. L.; Xu, G. L.; Xin, W. J.; Huang, S. J.; Xu, L. Y. Catal. Surv. Asia 2009, 13, 1. doi: 10.1007/s10563-008-9055-3
3. [3]
  (3) Wang, F.; Yan, S. J.; Yong, X. J.; Luo, C. T.; Zhang, Q.; Wen, P. Y.; ng, Y. J.; Dou, T. Acta Phys. -Chim. Sin. 2013, 29, 358. [王峰, 顔蜀雋, 雍晓静, 罗春桃, 张卿, 温鹏宇, 巩雁军, 窦涛. 物理化学学报, 2013, 29, 358.] doi: 10.3866/PKU.WHXB201211143
4. [4]
  (4) Hu, B.; Liu, H.; Tao, K.; Xiong, C. R.; Zhou, S. H. J. Phys. Chem. C. 2013, 117, 26385. doi: 10.1021/jp4098028
5. [5]
  (5) Bouchmella, K.; Stoyanova, M.; Rodemerck, U.; Debecker, D. P.; HubertMutina, P. Catal. Commun. 2015, 58, 183. doi: 10.1016/j.catcom.2014.09.024
6. [6]
  (6) Mazoyer, E.; Szeto, K. C.; Merle, N.; Norsic, S.; Boyron, O.; Basset, J. M.; Taoufik, M.; Nicholas, C. P. J. Catal. 2013, 301, 1. doi: 10.1016/j.jcat.2013.01.016
7. [7]
  (7) Xuan, D.; Liu, S.; Dong, J.; Wang, Y. D. Nat. Gas Chem. Ind. 2014, 39, 29. [宣东, 刘苏, 董静, 王仰东. 天然气化工, 2014, 39, 29.]
8. [8]
  (8) Cui, Y. M.; Liu, N.; Xia, Y. F.; Lü, J. G.; Zheng, S. J.; Xue, N. H.; Peng, L. M.; Guo, X. F.; Ding, W. P. J. Mol. Catal. A: Chem. 2014, 394, 1. doi: 10.1016/j.molcata.2014.06.027
9. [9]
  (9) Liu, H. J.; Zhang, L.; Li, X. J.; Huang, S. J.; Liu, S. L.; Xin, W. J.; Xie, S. J.; Xu, L. Y. J. Nat. Gas Chem. 2009, 18, 331 doi: 10.1016/S1003-9953(08)60113-9
10. [10]
  (10) Li, R.; Yuan, G. M.; Chen, S. L.; Hua, D. R.; Zhou, Z.; Sang, L.; Chen, A. C. J. Fuel Chem. Technol. 2012, 40, 855. [李睿, 袁桂梅, 陈胜利, 华德润, 周政, 桑磊, 陈爱城. 燃料化学学报, 2012, 40, 855.]
11. [11]
  (11) Amakawa, K;Wrabetz, S.; Kröhnert, J.; Tzolova-Müller, G.; Schlögl, R.; Trunschke, A. J. Am. Chem. Soc. 2012, 134, 11462. doi: 10.1021/ja3011989
12. [12]
  (12) Debecker, D. P.; Stoyanova, M.; Rodemerck, U.; Colbeau- Justin, F.; Boissère, C.; Chaumonnot, A.; Bonduelle, A.; Sanchez, C. Appl. Catal. A 2014, 470, 458. doi: 10.1016/j.apcata.2013.06.041
13. [13]
  (13) Xu, F.; Jiang, W. L.; Li, P. D.; Zhou, G. L.; Zhou, H. J. Chem. Ind. Eng. Prog. 2014, 33, 3253. [徐峰, 姜伟丽, 李沛东, 周广林, 周红军. 化工进展2014, 33, 3253. ]
14. [14]
  (14) Hu, J. C.; Wang, Y. D.; Chen, L. F.; Richards, R.; Yang, W. M.; Liu, Z. C.; Xu, W. Microporous Mesoporous Mat. 2006, 93, 158. doi: 10.1016/j.micromeso.2006.02.019
15. [15]
  (15) Hua, D. R.; Chen, S. L.; Yuan, G. M.; Wang, Y. L.; Zhao, Q. F.; Wang, X. L.; Fu, B. Microporous Mesoporous Mat. 2011, 143, 320. doi: 10.1016/j.micromeso.2011.03.012
16. [16]
  (16) Spamer, A.; Dube, T. I.; Moodley, D. J.; van Schalkwyk, C.; Botha, J. M. Appl. Catal. A 2003, 255, 153. doi: 10.1016/S0926-860X(03)00537-4
17. [17]
  (17) Maksasithorn, S.; Debecker, D. P.; Praserthdam, P.; Panpranot, J.; Suriye, K.; Ayudhya, S. K. N. Chin. J. Catal. 2014, 35, 232. doi: 10.1016/S1872-2067(12)60760-8
18. [18]
  (18) Liu, N.; Ding, S. L.; Cui, Y. M.; Xue, N. H.; Peng, L. M.; Guo, X. F.; Ding, W. P. Chem. Eng. Res. Des. 2013, 91, 573. doi: 10.1016/j.cherd.2012.08.008
19. [19]
  (19) Huang, S. J.; Liu, H. J.; Zhang, L.; Liu, S. L.; Xin, W. J.; Li, X. J.; Xie, S. J.; Xu, L. Y. Appl. Catal. A 2011, 404, 113. doi: 10.1016/j.apcata.2011.07.020
20. [20]
  (20) Benitez, V. M.; Fi li, N. S. Catal. Commun. 2002, 3, 487. doi: 10.1016/S1566-7367(02)00192-9
21. [21]
  (21) Huang, S. J.; Chen, F. C.; Liu, S. L.; Zhu, Q. J.; Zhu, X. X.; Xin, W. J.; Feng, Z. C.; Li, C.; Wang, Q. X.; Xu, L. Y. J. Mol. Catal. A: Chem. 2007, 267, 224. doi: 10.1016/j.molcata.2006.11.048
22. [22]
  (22) Horsley, J. A.; Wachs, I. E.; Brown, J. M.; Via, G. H.; Hardcastle, F. D. J. Phys. Chem. 1987, 91, 4014. doi: 10.1021/j100299a018
23. [23]
  (23) Ross-Medgaarden, E. I.; Wachs, I. E. J. Phys Chem. C 2007, 111, 15089. doi: 10.1021/jp074219c
24. [24]
  (24) Ramírez, J.; Gutiérrez-Alejandre, A. J. Catal. 1997, 170 (1), 108. doi: 10.1006/jcat.1997.1713
25. [25]
  (25) Zhao, Q. F.; Chen, S. L.; Gao, J. S.; Xu, C. M. Transition Met. Chem. 2009, 34, 621. doi: 10.1007/s11243-009-9239-3
26. [26]
  (26) Spamer, A.; Dube, T. I.; Moodley, D. J.; van Schalkwyk, C.; Botha, J. M. Appl. Catal. A 2003, 255, 133. doi: 10.1016/S0926-860X(03)00535-0
27. [27]
  (27) Westhoff, R.; Moulijn, J. A. J. Catal. 1977, 46, 414. doi: 10.1016/0021-9517(77)90225-1
28. [28]
  (28) Vermaire, D. C.; Vanberge, P. C. J. Catal. 1989, 116, 309. doi: 10.1016/0021-9517(89)90098-5
29. [29]
  (29) Wang, Y. D.; Chen, Q. L.; Yang, W. M.; Xie, Z. K.; Xu, W.; Huang, D. Y. Appl. Catal. A 2003, 250, 25. doi: 10.1016/S0926-860X(03)00186-8
1. [1]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
2. [2]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
3. [3]
  Rong-Nan Yi , Wei-Min He . Photocatalytic Minisci-type multicomponent reaction for the synthesis of 1-(halo)alkyl-3-heteroaryl bicyclo[1.1.1]pentanes. Chinese Chemical Letters, 2024, 35(10): 110115-. doi: 10.1016/j.cclet.2024.110115
4. [4]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
5. [5]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
6. [6]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
7. [7]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
8. [8]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
9. [9]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
10. [10]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
11. [11]
  Quanliang Chen , Zhaohui Zhou . Research on the Active Site of Nitrogenase over Fifty Years. University Chemistry, 2024, 39(7): 287-293. doi: 10.3866/PKU.DXHX202310133
12. [12]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
13. [13]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
14. [14]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
15. [15]
  Wujun Jian , Mong-Feng Chiou , Yajun Li , Hongli Bao , Song Yang . Cu-catalyzed regioselective diborylation of 1,3-enynes for the efficient synthesis of 1,4-diborylated allenes. Chinese Chemical Letters, 2024, 35(5): 108980-. doi: 10.1016/j.cclet.2023.108980
16. [16]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
17. [17]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
18. [18]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
19. [19]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
20. [20]
  Peng GENG , Guangcan XIANG , Wen ZHANG , Haichuang LAN , Shuzhang XIAO . Hollow copper sulfide loaded protoporphyrin for photothermal-sonodynamic therapy of cancer cells. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1903-1910. doi: 10.11862/CJIC.20240155

Get Citation

PDF

XML

Metrics

PDF Downloads(243)
Abstract views(531)
HTML views(58)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Tungsten Loadings on the 1-Butene Metathesis Reaction over W/SiO2/Al2O3 Catalysts

Metrics

通讯作者: 陈斌, bchen63@163.com

Influence of Tungsten Loadings on the 1-Butene Metathesis Reaction over W/SiO₂/Al₂O₃ Catalysts