Citation: LIU Na, ZHANG Hui, XUE Nian-Hua, DING Wei-Ping. Influence of Tungsten Loadings on the 1-Butene Metathesis Reaction over W/SiO₂/Al₂O₃ Catalysts[J]. Acta Physico-Chimica Sinica, ;2015, 31(5): 933-940. doi: 10.3866/PKU.WHXB201503032 shu

Influence of Tungsten Loadings on the 1-Butene Metathesis Reaction over W/SiO₂/Al₂O₃ Catalysts

1.
1 College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, P. R. China;
2 Key Laboratory of Mesoscopic Chemistry of MOE, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China

Received Date: 30 December 2014
Available Online: 3 March 2015
Fund Project: 国家自然科学基金(21403164) (21403164)国家大学生创新创业训练项目(S14024)资助 (S14024)

A series of W/SiO₂/Al₂O₃ catalysts with various tungsten loadings were synthesized via the impregnation method. The as-synthesized catalysts were characterized by X-ray diffraction (XRD), Raman spectroscopy, ultraviolet-visible (UV-Vis) spectroscopy, H2 temperature-programmed reduction (H₂-TPR), and NH₃ temperature-programmed desorption (NH₃-TPD). The results reveal that the tungsten loadings were crucial to the dispersion and reducibility of the tungsten oxide species and the acidity of catalysts. The catalytic performances were also investigated during the metathesis of 1-butene to propene. Amongst these catalysts, W/SiO₂/Al₂O₃ with a tungsten mass fraction of 6.0% gave the highest activity and stability during the 1-butene metathesis reaction. The excellent catalytic performance of the catalyst containing a tungsten mass fraction of 6.0% is attributed to its moderate dispersion, suitable reducibility of the WO_x species and suitable acidity. We speculate that these factors are favorable for the formation of active centers for olefin metathesis.
- 1-Butene,
- Protene,
- Metathesis,
- Tungsten loading,
- Catalytic activity
1. [1]
  
  (1) Lu, H. Q.; Shi, L.; He, C.; Weng, W. Z.; Huang, C. J.; Wan, H. L. Acta Phys. -Chim. Sin. 2012, 28, 2697. [鲁怀乾, 石磊, 何冲, 翁维正, 黄传敬, 万惠霖. 物理化学学报, 2012, 28, 2697.] doi: 10.3866/PKU.WHXB201207091
2. [2]
  (2) Zhu, X. X.; Li, X. J.; Xie, S. J.; Liu, S. L.; Xu, G. L.; Xin, W. J.; Huang, S. J.; Xu, L. Y. Catal. Surv. Asia 2009, 13, 1. doi: 10.1007/s10563-008-9055-3
3. [3]
  (3) Wang, F.; Yan, S. J.; Yong, X. J.; Luo, C. T.; Zhang, Q.; Wen, P. Y.; ng, Y. J.; Dou, T. Acta Phys. -Chim. Sin. 2013, 29, 358. [王峰, 顔蜀雋, 雍晓静, 罗春桃, 张卿, 温鹏宇, 巩雁军, 窦涛. 物理化学学报, 2013, 29, 358.] doi: 10.3866/PKU.WHXB201211143
4. [4]
  (4) Hu, B.; Liu, H.; Tao, K.; Xiong, C. R.; Zhou, S. H. J. Phys. Chem. C. 2013, 117, 26385. doi: 10.1021/jp4098028
5. [5]
  (5) Bouchmella, K.; Stoyanova, M.; Rodemerck, U.; Debecker, D. P.; HubertMutina, P. Catal. Commun. 2015, 58, 183. doi: 10.1016/j.catcom.2014.09.024
6. [6]
  (6) Mazoyer, E.; Szeto, K. C.; Merle, N.; Norsic, S.; Boyron, O.; Basset, J. M.; Taoufik, M.; Nicholas, C. P. J. Catal. 2013, 301, 1. doi: 10.1016/j.jcat.2013.01.016
7. [7]
  (7) Xuan, D.; Liu, S.; Dong, J.; Wang, Y. D. Nat. Gas Chem. Ind. 2014, 39, 29. [宣东, 刘苏, 董静, 王仰东. 天然气化工, 2014, 39, 29.]
8. [8]
  (8) Cui, Y. M.; Liu, N.; Xia, Y. F.; Lü, J. G.; Zheng, S. J.; Xue, N. H.; Peng, L. M.; Guo, X. F.; Ding, W. P. J. Mol. Catal. A: Chem. 2014, 394, 1. doi: 10.1016/j.molcata.2014.06.027
9. [9]
  (9) Liu, H. J.; Zhang, L.; Li, X. J.; Huang, S. J.; Liu, S. L.; Xin, W. J.; Xie, S. J.; Xu, L. Y. J. Nat. Gas Chem. 2009, 18, 331 doi: 10.1016/S1003-9953(08)60113-9
10. [10]
  (10) Li, R.; Yuan, G. M.; Chen, S. L.; Hua, D. R.; Zhou, Z.; Sang, L.; Chen, A. C. J. Fuel Chem. Technol. 2012, 40, 855. [李睿, 袁桂梅, 陈胜利, 华德润, 周政, 桑磊, 陈爱城. 燃料化学学报, 2012, 40, 855.]
11. [11]
  (11) Amakawa, K;Wrabetz, S.; Kröhnert, J.; Tzolova-Müller, G.; Schlögl, R.; Trunschke, A. J. Am. Chem. Soc. 2012, 134, 11462. doi: 10.1021/ja3011989
12. [12]
  (12) Debecker, D. P.; Stoyanova, M.; Rodemerck, U.; Colbeau- Justin, F.; Boissère, C.; Chaumonnot, A.; Bonduelle, A.; Sanchez, C. Appl. Catal. A 2014, 470, 458. doi: 10.1016/j.apcata.2013.06.041
13. [13]
  (13) Xu, F.; Jiang, W. L.; Li, P. D.; Zhou, G. L.; Zhou, H. J. Chem. Ind. Eng. Prog. 2014, 33, 3253. [徐峰, 姜伟丽, 李沛东, 周广林, 周红军. 化工进展2014, 33, 3253. ]
14. [14]
  (14) Hu, J. C.; Wang, Y. D.; Chen, L. F.; Richards, R.; Yang, W. M.; Liu, Z. C.; Xu, W. Microporous Mesoporous Mat. 2006, 93, 158. doi: 10.1016/j.micromeso.2006.02.019
15. [15]
  (15) Hua, D. R.; Chen, S. L.; Yuan, G. M.; Wang, Y. L.; Zhao, Q. F.; Wang, X. L.; Fu, B. Microporous Mesoporous Mat. 2011, 143, 320. doi: 10.1016/j.micromeso.2011.03.012
16. [16]
  (16) Spamer, A.; Dube, T. I.; Moodley, D. J.; van Schalkwyk, C.; Botha, J. M. Appl. Catal. A 2003, 255, 153. doi: 10.1016/S0926-860X(03)00537-4
17. [17]
  (17) Maksasithorn, S.; Debecker, D. P.; Praserthdam, P.; Panpranot, J.; Suriye, K.; Ayudhya, S. K. N. Chin. J. Catal. 2014, 35, 232. doi: 10.1016/S1872-2067(12)60760-8
18. [18]
  (18) Liu, N.; Ding, S. L.; Cui, Y. M.; Xue, N. H.; Peng, L. M.; Guo, X. F.; Ding, W. P. Chem. Eng. Res. Des. 2013, 91, 573. doi: 10.1016/j.cherd.2012.08.008
19. [19]
  (19) Huang, S. J.; Liu, H. J.; Zhang, L.; Liu, S. L.; Xin, W. J.; Li, X. J.; Xie, S. J.; Xu, L. Y. Appl. Catal. A 2011, 404, 113. doi: 10.1016/j.apcata.2011.07.020
20. [20]
  (20) Benitez, V. M.; Fi li, N. S. Catal. Commun. 2002, 3, 487. doi: 10.1016/S1566-7367(02)00192-9
21. [21]
  (21) Huang, S. J.; Chen, F. C.; Liu, S. L.; Zhu, Q. J.; Zhu, X. X.; Xin, W. J.; Feng, Z. C.; Li, C.; Wang, Q. X.; Xu, L. Y. J. Mol. Catal. A: Chem. 2007, 267, 224. doi: 10.1016/j.molcata.2006.11.048
22. [22]
  (22) Horsley, J. A.; Wachs, I. E.; Brown, J. M.; Via, G. H.; Hardcastle, F. D. J. Phys. Chem. 1987, 91, 4014. doi: 10.1021/j100299a018
23. [23]
  (23) Ross-Medgaarden, E. I.; Wachs, I. E. J. Phys Chem. C 2007, 111, 15089. doi: 10.1021/jp074219c
24. [24]
  (24) Ramírez, J.; Gutiérrez-Alejandre, A. J. Catal. 1997, 170 (1), 108. doi: 10.1006/jcat.1997.1713
25. [25]
  (25) Zhao, Q. F.; Chen, S. L.; Gao, J. S.; Xu, C. M. Transition Met. Chem. 2009, 34, 621. doi: 10.1007/s11243-009-9239-3
26. [26]
  (26) Spamer, A.; Dube, T. I.; Moodley, D. J.; van Schalkwyk, C.; Botha, J. M. Appl. Catal. A 2003, 255, 133. doi: 10.1016/S0926-860X(03)00535-0
27. [27]
  (27) Westhoff, R.; Moulijn, J. A. J. Catal. 1977, 46, 414. doi: 10.1016/0021-9517(77)90225-1
28. [28]
  (28) Vermaire, D. C.; Vanberge, P. C. J. Catal. 1989, 116, 309. doi: 10.1016/0021-9517(89)90098-5
29. [29]
  (29) Wang, Y. D.; Chen, Q. L.; Yang, W. M.; Xie, Z. K.; Xu, W.; Huang, D. Y. Appl. Catal. A 2003, 250, 25. doi: 10.1016/S0926-860X(03)00186-8
1. [1]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
2. [2]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
3. [3]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
4. [4]
  Rong-Nan Yi , Wei-Min He . Photocatalytic Minisci-type multicomponent reaction for the synthesis of 1-(halo)alkyl-3-heteroaryl bicyclo[1.1.1]pentanes. Chinese Chemical Letters, 2024, 35(10): 110115-. doi: 10.1016/j.cclet.2024.110115
5. [5]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
6. [6]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
7. [7]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
8. [8]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
9. [9]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
10. [10]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
11. [11]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
12. [12]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
13. [13]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
14. [14]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
15. [15]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
16. [16]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
17. [17]
  Quanliang Chen , Zhaohui Zhou . Research on the Active Site of Nitrogenase over Fifty Years. University Chemistry, 2024, 39(7): 287-293. doi: 10.3866/PKU.DXHX202310133
18. [18]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
19. [19]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
20. [20]
  Wenkai Chen , Yunjia Shen , Xiangmeng Kong , Yanli Zeng . Quantum Chemistry Calculation of Key Physical Quantity in Circularly Polarized Luminescence: Introducing an Exploratory Computational Chemistry Experiment. University Chemistry, 2025, 40(3): 83-91. doi: 10.12461/PKU.DXHX202405018

Get Citation

PDF

XML

Metrics

PDF Downloads(243)
Abstract views(584)
HTML views(72)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Tungsten Loadings on the 1-Butene Metathesis Reaction over W/SiO2/Al2O3 Catalysts

Metrics

通讯作者: 陈斌, bchen63@163.com

Influence of Tungsten Loadings on the 1-Butene Metathesis Reaction over W/SiO₂/Al₂O₃ Catalysts