Citation: LIU Na, ZHANG Hui, XUE Nian-Hua, DING Wei-Ping. Influence of Tungsten Loadings on the 1-Butene Metathesis Reaction over W/SiO₂/Al₂O₃ Catalysts[J]. Acta Physico-Chimica Sinica, ;2015, 31(5): 933-940. doi: 10.3866/PKU.WHXB201503032 shu

Influence of Tungsten Loadings on the 1-Butene Metathesis Reaction over W/SiO₂/Al₂O₃ Catalysts

1.
1 College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, P. R. China;
2 Key Laboratory of Mesoscopic Chemistry of MOE, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China

Received Date: 30 December 2014
Available Online: 3 March 2015
Fund Project: 国家自然科学基金(21403164) (21403164)国家大学生创新创业训练项目(S14024)资助 (S14024)

A series of W/SiO₂/Al₂O₃ catalysts with various tungsten loadings were synthesized via the impregnation method. The as-synthesized catalysts were characterized by X-ray diffraction (XRD), Raman spectroscopy, ultraviolet-visible (UV-Vis) spectroscopy, H2 temperature-programmed reduction (H₂-TPR), and NH₃ temperature-programmed desorption (NH₃-TPD). The results reveal that the tungsten loadings were crucial to the dispersion and reducibility of the tungsten oxide species and the acidity of catalysts. The catalytic performances were also investigated during the metathesis of 1-butene to propene. Amongst these catalysts, W/SiO₂/Al₂O₃ with a tungsten mass fraction of 6.0% gave the highest activity and stability during the 1-butene metathesis reaction. The excellent catalytic performance of the catalyst containing a tungsten mass fraction of 6.0% is attributed to its moderate dispersion, suitable reducibility of the WO_x species and suitable acidity. We speculate that these factors are favorable for the formation of active centers for olefin metathesis.
- 1-Butene,
- Protene,
- Metathesis,
- Tungsten loading,
- Catalytic activity
1. [1]
  
  (1) Lu, H. Q.; Shi, L.; He, C.; Weng, W. Z.; Huang, C. J.; Wan, H. L. Acta Phys. -Chim. Sin. 2012, 28, 2697. [鲁怀乾, 石磊, 何冲, 翁维正, 黄传敬, 万惠霖. 物理化学学报, 2012, 28, 2697.] doi: 10.3866/PKU.WHXB201207091
2. [2]
  (2) Zhu, X. X.; Li, X. J.; Xie, S. J.; Liu, S. L.; Xu, G. L.; Xin, W. J.; Huang, S. J.; Xu, L. Y. Catal. Surv. Asia 2009, 13, 1. doi: 10.1007/s10563-008-9055-3
3. [3]
  (3) Wang, F.; Yan, S. J.; Yong, X. J.; Luo, C. T.; Zhang, Q.; Wen, P. Y.; ng, Y. J.; Dou, T. Acta Phys. -Chim. Sin. 2013, 29, 358. [王峰, 顔蜀雋, 雍晓静, 罗春桃, 张卿, 温鹏宇, 巩雁军, 窦涛. 物理化学学报, 2013, 29, 358.] doi: 10.3866/PKU.WHXB201211143
4. [4]
  (4) Hu, B.; Liu, H.; Tao, K.; Xiong, C. R.; Zhou, S. H. J. Phys. Chem. C. 2013, 117, 26385. doi: 10.1021/jp4098028
5. [5]
  (5) Bouchmella, K.; Stoyanova, M.; Rodemerck, U.; Debecker, D. P.; HubertMutina, P. Catal. Commun. 2015, 58, 183. doi: 10.1016/j.catcom.2014.09.024
6. [6]
  (6) Mazoyer, E.; Szeto, K. C.; Merle, N.; Norsic, S.; Boyron, O.; Basset, J. M.; Taoufik, M.; Nicholas, C. P. J. Catal. 2013, 301, 1. doi: 10.1016/j.jcat.2013.01.016
7. [7]
  (7) Xuan, D.; Liu, S.; Dong, J.; Wang, Y. D. Nat. Gas Chem. Ind. 2014, 39, 29. [宣东, 刘苏, 董静, 王仰东. 天然气化工, 2014, 39, 29.]
8. [8]
  (8) Cui, Y. M.; Liu, N.; Xia, Y. F.; Lü, J. G.; Zheng, S. J.; Xue, N. H.; Peng, L. M.; Guo, X. F.; Ding, W. P. J. Mol. Catal. A: Chem. 2014, 394, 1. doi: 10.1016/j.molcata.2014.06.027
9. [9]
  (9) Liu, H. J.; Zhang, L.; Li, X. J.; Huang, S. J.; Liu, S. L.; Xin, W. J.; Xie, S. J.; Xu, L. Y. J. Nat. Gas Chem. 2009, 18, 331 doi: 10.1016/S1003-9953(08)60113-9
10. [10]
  (10) Li, R.; Yuan, G. M.; Chen, S. L.; Hua, D. R.; Zhou, Z.; Sang, L.; Chen, A. C. J. Fuel Chem. Technol. 2012, 40, 855. [李睿, 袁桂梅, 陈胜利, 华德润, 周政, 桑磊, 陈爱城. 燃料化学学报, 2012, 40, 855.]
11. [11]
  (11) Amakawa, K;Wrabetz, S.; Kröhnert, J.; Tzolova-Müller, G.; Schlögl, R.; Trunschke, A. J. Am. Chem. Soc. 2012, 134, 11462. doi: 10.1021/ja3011989
12. [12]
  (12) Debecker, D. P.; Stoyanova, M.; Rodemerck, U.; Colbeau- Justin, F.; Boissère, C.; Chaumonnot, A.; Bonduelle, A.; Sanchez, C. Appl. Catal. A 2014, 470, 458. doi: 10.1016/j.apcata.2013.06.041
13. [13]
  (13) Xu, F.; Jiang, W. L.; Li, P. D.; Zhou, G. L.; Zhou, H. J. Chem. Ind. Eng. Prog. 2014, 33, 3253. [徐峰, 姜伟丽, 李沛东, 周广林, 周红军. 化工进展2014, 33, 3253. ]
14. [14]
  (14) Hu, J. C.; Wang, Y. D.; Chen, L. F.; Richards, R.; Yang, W. M.; Liu, Z. C.; Xu, W. Microporous Mesoporous Mat. 2006, 93, 158. doi: 10.1016/j.micromeso.2006.02.019
15. [15]
  (15) Hua, D. R.; Chen, S. L.; Yuan, G. M.; Wang, Y. L.; Zhao, Q. F.; Wang, X. L.; Fu, B. Microporous Mesoporous Mat. 2011, 143, 320. doi: 10.1016/j.micromeso.2011.03.012
16. [16]
  (16) Spamer, A.; Dube, T. I.; Moodley, D. J.; van Schalkwyk, C.; Botha, J. M. Appl. Catal. A 2003, 255, 153. doi: 10.1016/S0926-860X(03)00537-4
17. [17]
  (17) Maksasithorn, S.; Debecker, D. P.; Praserthdam, P.; Panpranot, J.; Suriye, K.; Ayudhya, S. K. N. Chin. J. Catal. 2014, 35, 232. doi: 10.1016/S1872-2067(12)60760-8
18. [18]
  (18) Liu, N.; Ding, S. L.; Cui, Y. M.; Xue, N. H.; Peng, L. M.; Guo, X. F.; Ding, W. P. Chem. Eng. Res. Des. 2013, 91, 573. doi: 10.1016/j.cherd.2012.08.008
19. [19]
  (19) Huang, S. J.; Liu, H. J.; Zhang, L.; Liu, S. L.; Xin, W. J.; Li, X. J.; Xie, S. J.; Xu, L. Y. Appl. Catal. A 2011, 404, 113. doi: 10.1016/j.apcata.2011.07.020
20. [20]
  (20) Benitez, V. M.; Fi li, N. S. Catal. Commun. 2002, 3, 487. doi: 10.1016/S1566-7367(02)00192-9
21. [21]
  (21) Huang, S. J.; Chen, F. C.; Liu, S. L.; Zhu, Q. J.; Zhu, X. X.; Xin, W. J.; Feng, Z. C.; Li, C.; Wang, Q. X.; Xu, L. Y. J. Mol. Catal. A: Chem. 2007, 267, 224. doi: 10.1016/j.molcata.2006.11.048
22. [22]
  (22) Horsley, J. A.; Wachs, I. E.; Brown, J. M.; Via, G. H.; Hardcastle, F. D. J. Phys. Chem. 1987, 91, 4014. doi: 10.1021/j100299a018
23. [23]
  (23) Ross-Medgaarden, E. I.; Wachs, I. E. J. Phys Chem. C 2007, 111, 15089. doi: 10.1021/jp074219c
24. [24]
  (24) Ramírez, J.; Gutiérrez-Alejandre, A. J. Catal. 1997, 170 (1), 108. doi: 10.1006/jcat.1997.1713
25. [25]
  (25) Zhao, Q. F.; Chen, S. L.; Gao, J. S.; Xu, C. M. Transition Met. Chem. 2009, 34, 621. doi: 10.1007/s11243-009-9239-3
26. [26]
  (26) Spamer, A.; Dube, T. I.; Moodley, D. J.; van Schalkwyk, C.; Botha, J. M. Appl. Catal. A 2003, 255, 133. doi: 10.1016/S0926-860X(03)00535-0
27. [27]
  (27) Westhoff, R.; Moulijn, J. A. J. Catal. 1977, 46, 414. doi: 10.1016/0021-9517(77)90225-1
28. [28]
  (28) Vermaire, D. C.; Vanberge, P. C. J. Catal. 1989, 116, 309. doi: 10.1016/0021-9517(89)90098-5
29. [29]
  (29) Wang, Y. D.; Chen, Q. L.; Yang, W. M.; Xie, Z. K.; Xu, W.; Huang, D. Y. Appl. Catal. A 2003, 250, 25. doi: 10.1016/S0926-860X(03)00186-8
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沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Tungsten Loadings on the 1-Butene Metathesis Reaction over W/SiO2/Al2O3 Catalysts

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通讯作者: 陈斌, bchen63@163.com

Influence of Tungsten Loadings on the 1-Butene Metathesis Reaction over W/SiO₂/Al₂O₃ Catalysts