Citation: YUAN Fu-Qing, LIU Dan-Dan, GUO Lan-Lei, ZHU Yang-Wen, XU Zhi-Cheng, HUANG Jian-Bin, ZHANG Lei, ZHANG Lu. Effect of Branched Cationic and Betaine Surfactants on the Wettability of a Poly(tetrafluoroethylene) Surface[J]. Acta Physico-Chimica Sinica, ;2015, 31(4): 715-721. doi: 10.3866/PKU.WHXB201503028 shu

Effect of Branched Cationic and Betaine Surfactants on the Wettability of a Poly(tetrafluoroethylene) Surface

1.
1 College of Petroleum Engineering, China University of Petroleum (Huadong), Qingdao 266555, Shandong Province, P. R. China;
2 Geological Scientific Research Institute of Shengli Oilfield Co. Ltd., SINOPEC, Dongying 257015, Shandong Province, P. R. China;
3 Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
4 College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 8 January 2015
Available Online: 2 March 2015
Fund Project: 国家科技重大专项(2011ZX05011-004)资助项目 (2011ZX05011-004)

The adsorption mechanism and wetting properties of aqueous solutions of branched cationic surfactants, hexadecanol glycidyl ether ammonium chloride (C₁₆GPC), and zwitterionic surfactant, hexadecanol glycidyl ether glycine betaine (C₁₆GPB) on a poly(tetrafluoroethylene) (PTFE) surface were investigated using sessile drop analysis. The influences of surfactant concentration on surface tension, contact angle, adhesional tension, PTFE-solution interfacial tension, and adhesion work were expounded. The results indicate that branched surfactant molecules lie parallel to the PTFE surface through hydrophobic interactions between the multi methylene groups of the alkyl chain and the solid surface below the critical micelle concentration (cmc). C₁₆GPC and C₁₆GPB molecules still adsorb onto PTFE because of the marked hindrance of branched chains to the formation of micelles above the cmc. The methylene group interactions with PTFE decrease and C₁₆GPC and C₁₆GPB molecules become straightened on the solid surface, which results in a clear decrease in PTFE-solution interfacial tension (γ_sl). For branched surfactants, an abrupt decrease in contact angle appears above the cmc.
- Cationic surfactant,
- Zwitterionic surfactant,
- Branched chain,
- Contact angle,
- Poly(tetrafluoroethylene) surface
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