Citation: WANG Wen-Xuan, DENG Shao-Xin, SHI Cheng-Xiang, SUN Ping-Chuan, CHEN Tie-Hong. Synthesis of Mesoporous Silica Using Anionic Surfactant/Cationic Polyamine as a Template[J]. Acta Physico-Chimica Sinica, ;2015, 31(4): 707-714. doi: 10.3866/PKU.WHXB201503027 shu

Synthesis of Mesoporous Silica Using Anionic Surfactant/Cationic Polyamine as a Template

1.
Key Laboratory of Advanced Energy Materials Chemistry (MOE), Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University, Tianjin 300071, P. R. China

Received Date: 7 January 2015
Available Online: 2 March 2015
Fund Project: 国家自然科学基金(21373116, 21421001)资助项目 (21373116, 21421001)

Electrostatic interactions between cationic polyamine and anionic surfactant cause assembly to form composite micelles. The anionic surfactant/cationic polyamine composite micelles can then act as a template to co-assemble with silica precursors to form mesostructured silica. Mesoporous silicas with different mesostructures and morphologies were obtained by changing the synthesis temperature, the amounts of cationic polyelectrolyte or silica precursor and the species of anionic surfactant. This anionic surfactant/cationic polyamine composite micelle template method comprises a general method for synthesizing mesoporous silicas.
- Cationic polyamine,
- Anionic surfactant,
- Biomimetic synthesis,
- Mesoporous silica
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沈阳化工大学材料科学与工程学院沈阳 110142