Citation: YANG Shuo, XU Gui-Yin, HAN Jin-Peng, BING Huan, DOU Hui, ZHANG Xiao-Gang. Nitrogen-Doped Porous Carbon Derived from Dopamine-Modified Polypyrrole and Its Electrochemical Capacitive Behavior[J]. Acta Physico-Chimica Sinica, ;2015, 31(4): 685-692. doi: 10.3866/PKU.WHXB201502022 shu

Nitrogen-Doped Porous Carbon Derived from Dopamine-Modified Polypyrrole and Its Electrochemical Capacitive Behavior

1.
Jiangsu Key Laboratory of Materials and Technology for Energy Conversion, College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China

Received Date: 9 October 2014
Available Online: 2 February 2015
Fund Project: 国家重点基础研究发展规划(973) (2014CB239701) (973) (2014CB239701) 国家自然科学基金(21103091, 21173120, 51372116)以及江苏省自然科学基金(BK2011030)资助项目 (21103091, 21173120, 51372116)以及江苏省自然科学基金(BK2011030)

Carbonization of a nitrogen-containing polymer under inert atmosphere has been used to obtain nitrogen-enriched carbon materials. Herein, we synthesized dopamine-modified polypyrrole (PDA-PPy) via chemical polymerization, which was then carbonized under nitrogen atmosphere to produce nitrogen-doped porous carbon materials (NPC). The structure and morphology of the NPC were investigated by Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). By regulating the molar ratio of pyrrole monomer to dopamine, the morphology of PDA-PPy and the capacitive performance of NPC could be controlled. At a current density of 0.5 A·g^-1, the specific capacitance of NPC-0.5 (the molar ratio of dopamine to pyrrole monomer is 0.5) is ca 210 F·g^-1. Even at a current density of 10 A·g^-1, the specific capacitance of NPC-0.5 is up to 134 F·g^-1 and the retention rate is 63.8%.
- Pyrrole,
- Dopamine,
- Porous carbon,
- Nitrogen-doping,
- Supercapacitor
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