Citation: YANG Shuo, XU Gui-Yin, HAN Jin-Peng, BING Huan, DOU Hui, ZHANG Xiao-Gang. Nitrogen-Doped Porous Carbon Derived from Dopamine-Modified Polypyrrole and Its Electrochemical Capacitive Behavior[J]. Acta Physico-Chimica Sinica, ;2015, 31(4): 685-692. doi: 10.3866/PKU.WHXB201502022 shu

Nitrogen-Doped Porous Carbon Derived from Dopamine-Modified Polypyrrole and Its Electrochemical Capacitive Behavior

1.
Jiangsu Key Laboratory of Materials and Technology for Energy Conversion, College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China

Received Date: 9 October 2014
Available Online: 2 February 2015
Fund Project: 国家重点基础研究发展规划(973) (2014CB239701) (973) (2014CB239701) 国家自然科学基金(21103091, 21173120, 51372116)以及江苏省自然科学基金(BK2011030)资助项目 (21103091, 21173120, 51372116)以及江苏省自然科学基金(BK2011030)

Carbonization of a nitrogen-containing polymer under inert atmosphere has been used to obtain nitrogen-enriched carbon materials. Herein, we synthesized dopamine-modified polypyrrole (PDA-PPy) via chemical polymerization, which was then carbonized under nitrogen atmosphere to produce nitrogen-doped porous carbon materials (NPC). The structure and morphology of the NPC were investigated by Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). By regulating the molar ratio of pyrrole monomer to dopamine, the morphology of PDA-PPy and the capacitive performance of NPC could be controlled. At a current density of 0.5 A·g^-1, the specific capacitance of NPC-0.5 (the molar ratio of dopamine to pyrrole monomer is 0.5) is ca 210 F·g^-1. Even at a current density of 10 A·g^-1, the specific capacitance of NPC-0.5 is up to 134 F·g^-1 and the retention rate is 63.8%.
- Pyrrole,
- Dopamine,
- Porous carbon,
- Nitrogen-doping,
- Supercapacitor
1. [1]
  
  (1) Xu, G. Y.; Ding, B.; Pan, J.; Nie, P.; Shen, L. F.; Zhang, X. G. Journal of Materials Chemistry A 2014, 2 (32), 12662. doi: 10.1039/C4TA02097A
2. [2]
  (2) Choi, N. S.; Chen, Z.; Freunberger, S. A.; Ji, X.; Sun, Y. K.; Amine, K.; Yushin, G.; Nazar, L. F.; Cho J.; Bruce, P. G. Angewandte Chemie International Edition 2012, 51 (40), 9994. doi: 10.1002/anie.201201429
3. [3]
  (3) Li, L.; He, Y. Q.; Chu, X. F.; Li, Y. M.; Sun, F. F.; Huang, H. Z. Acta Physico-Chimica Sinica 2013, 29 (8), 1681. [李乐, 贺蕴秋, 储晓菲, 李一鸣, 孙芳芳, 黄河洲. 物理化学学报, 2013, 29 (8), 1681.] doi: 10.3866/PKU.WHXB201305223
4. [4]
  (4) Xu, G. Y.; Ding, B.; Nie, P.; Luo, H. J.; Zhang, X. G. Acta Physico-Chimica Sinica 2013, 29 (3), 546. [徐桂银, 丁兵, 聂平, 骆宏钧, 张校刚. 物理化学学报, 2013, 29 (3), 546.] doi: 10.3866/PKU.WHXB201301081
5. [5]
  (5) Che, Q.; Zhang, F.; Zhang, X. G.; Lu, X. J.; Ding, B.; Zhu, J. J. Acta Physico-Chimica Sinica 2012, 28 (4), 837. [车倩, 张方, 张校刚, 卢向军, 丁兵, 朱佳佳. 物理化学学报, 2012, 28 (4), 837.] doi: 10.3866/PKU.WHXB201202074
6. [6]
  (6) Guo, P. Z.; Ji, Q. Q.; Zhang, L. L.; Zhao, S. Y.; Zhao, X. S. Acta Phys. -Chim. Sin. 2011, 27 (12), 2836.] [郭培志, 季倩倩, 张丽莉, 赵善玉, 赵修松. 物理化学学报, 2011, 27 (12), 2836.] doi: 10.3866/PKU.WHXB20112836
7. [7]
  (7) Liu, P.; Verbrugge, M.; Soukiazian, S. Journal of Power Sources 2006, 156 (2), 712. doi: 10.1016/j.jpowsour.2005.05.055
8. [8]
  (8) Chen, L.; Yuan, C.; Dou, H.; Gao, B.; Chen, S.; Zhang, X. Electrochimica Acta 2009, 54 (8), 2335. doi: 10.1016/j.electacta.2008.10.071
9. [9]
  (9) Sun, Y.; Shi, G. Journal of Polymer Science Part B: Polymer Physics 2013, 51 (4), 231. doi: 10.1002/polb.23226
10. [10]
  (10) Zhao, Y.; Hu, C.; Hu, Y.; Cheng, H.; Shi, G.; Qu, L. Angew. Chem. Int. Edit. 2012, 124 (45), 11533. doi: 10.1002/ange.201206554
11. [11]
  (11) Qie, L.; Chen, W. M.; Wang, Z. H.; Shao, Q. G.; Li, X.; Yuan, L. X.; Hu, X. L.; Zhang, W. X.; Huang, Y. H. Adv. Mater. 2012, 24 (15), 2047. doi: 10.1002/adma.201104634
12. [12]
  (12) Tanaka, S.; Nakatani, N.; Doi, A.; Miyake, Y. Carbon 2011, 49 (10), 3184. doi: 10.1016/j.carbon.2011.03.042
13. [13]
  (13) Chen, X. Y.; Chen, C.; Zhang, Z. J.; Xie, D. H.; Deng, X. Industrial & Engineering Chemistry Research 2013, 52 (30), 10181. doi: 10.1021/ie400862h
14. [14]
  (14) Han, J.; Xu, G.; Ding, B.; Pan, J.; Dou, H.; MacFarlane, D. R. Journal of Materials Chemistry A 2014, 2 (15), 5352. doi: 10.1039/C3TA15271E
15. [15]
  (15) Zhang, W.; Yang, F. K.; Pan, Z.; Zhang, J.; Zhao, B. Macromolecular Rapid Communications 2014, 35 (3), 350. doi: 10.1002/marc.201300761
16. [16]
  (16) Ai, K. L.; Liu, Y. L.; Ruan, C. P.; Lu, L. H.; Lu, G. Q. Adv. Mater. 2013, 25 (7), 998. doi: 10.1002/adma.201203923
17. [17]
  (17) Peterson, M. B.; Le-Masurier, S. P.; Lim, K.; Hook, J. M.; Martens, P.; Granville, A. M. Macromolecular Rapid Communications 2014, 35 (3), 291. doi: 10.1002/marc.201300746
18. [18]
  (18) Gao, S.; Fan, H.; Chen, Y.; Li, L.; Bando, Y.; lberg, D. Nano Energy 2013, 2 (6), 1261. doi: 10.1016/j.nanoen.2013.06.005
19. [19]
  (19) Sevilla, M.; Valle-Vigón, P.; Fuertes, A. B. Advanced Functional Materials 2011, 21 (14), 2781. doi: 10.1002/adfm.201100291
20. [20]
  (20) Xu, G.; Ding, B.; Nie, P.; Shen, L.; Wang, J.; Zhang, X. Chemistry-A European Journal 2013, 19 (37), 12306. doi: 10.1002/chem.201301352
21. [21]
  (21) Xu, F.; Cai, R.; Zeng, Q.; Zou, C.; Wu, D.; Li, F.; Lu, X.; Liang, Y.; Fu, R. Journal of Materials Chemistry 2011, 21 (6), 1970. doi: 10.1039/C0JM02044C
22. [22]
  (22) Zhou, C.; Zhang, Y.; Li, Y.; Liu, J. Nano Letters 2013, 13 (5), 2078. doi: 10.1021/nl400378j.
23. [23]
  (23) Wang, D.W.; Li, F.; Yin, L. C.; Lu, X.; Chen, Z. G.; Gentle, I. R.; Lu, G. Q.; Cheng, H. M. Chemistry-A European Journal 2012, 18 (17), 5345. doi: 10.1002/chem.201102806
24. [24]
  (24) Liu, D.; Zhang, X.; Sun, Z.; You, T. Nanoscale 2013, 5 (20), 9528. doi: 10.1039/C3NR03229A
25. [25]
  (25) Hu, C.; Xiao, Y.; Zhao, Y.; Chen, N.; Zhang, Z.; Cao, M.; Qu, L. Nanoscale 2013, 5 (7), 2726. doi: 10.1039/C3NR34002C
26. [26]
  (26) Han, J.; Xu, G.; Dou, H.; MacFarlane, D. R. Chemistry-A European Journal 2015, 21 (6), 2310. doi: 10.1002/chem.201404975
1. [1]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
2. [2]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
3. [3]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
4. [4]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
5. [5]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
6. [6]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
7. [7]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
8. [8]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
9. [9]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
10. [10]
  Yu ZHANG , Fangfang ZHAO , Cong PAN , Peng WANG , Liangming WEI . Application of double-side modified separator with hollow carbon material in high-performance Li-S battery. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412
11. [11]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
12. [12]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
13. [13]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
14. [14]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
15. [15]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
16. [16]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
17. [17]
  Ziheng Zhuang , Xiao Xu , Kin Shing Chan . Superdrugs for Superbugs. University Chemistry, 2024, 39(9): 128-133. doi: 10.3866/PKU.DXHX202309040
18. [18]
  Lei Shu , Zimin Duan , Yushen Kang , Zijian Zhao , Hong Wang , Lihua Zhu , Hui Xiong , Nan Wang . An Exploration of the CO₂-Involved Carbon Cycle World. University Chemistry, 2024, 39(5): 144-153. doi: 10.3866/PKU.DXHX202309084
19. [19]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
20. [20]
  Lei Shu , Zhengqing Hao , Kai Yan , Hong Wang , Lihua Zhu , Fang Chen , Nan Wang . Development of a Double-Carbon Related Experiment: Preparation, Characterization and Carbon-Capture Ability of Eggshell-Derived CaO. University Chemistry, 2024, 39(4): 149-156. doi: 10.3866/PKU.DXHX202310134

Get Citation

PDF

XML

Metrics

PDF Downloads(332)
Abstract views(600)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142