Citation: DU Hai-Ying, WANG Jing, QIAO Qiao, SUN Yan-Hui, SHAO Qiang, LI Xiao-Gan. Synthesis and Characterization of ZnO/PPy Hetero-Nanocomposites and Their Gas Sensing Properties[J]. Acta Physico-Chimica Sinica, ;2015, 31(4): 800-806. doi: 10.3866/PKU.WHXB201501283 shu

Synthesis and Characterization of ZnO/PPy Hetero-Nanocomposites and Their Gas Sensing Properties

DU Hai-Ying ^1,2 ,
WANG Jing ^1, ,
QIAO Qiao ¹ ,
SUN Yan-Hui ^1,2 ,
SHAO Qiang ² ,
LI Xiao-Gan ¹

1.
1 School of Electronic Science and Technology, Dalian University of Technology, Dalian 116023, Liaoning Province, P. R. China;
2 College of Electromechanical & Information Engineering, Dalian Nationalities University, Dalian 116600, Liaoning Province, P. R. China

Received Date: 12 December 2014
Available Online: 28 January 2015
Fund Project: 国家自然科学基金(61176068, 61131004, 61474012)资助项目 (61176068, 61131004, 61474012)

Pyrrole (Py) was oxidized by ferric(III) chloride solution in water for the synthesis of polypyrrole (PPy) nanoparticles on the substrate slide by in-situ polymerization at room temperature. Zinc oxide nanorods grew on the PPy nanoparticles when in a water bath at 90 ℃. ZnO/PPy hetero-nanocomposites were obtained by a hydrothermal method and characterized using X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). Gas sensors were fabricated based on the ZnO/PPy hetero-nanocomposites to detect ammonia at room temperature. The gas sensing properties of these hetero-nanocomposites were measured in the concentration range of 10×10^-6-150×10^-6 (volume fraction). The relationship of the sensitivity of the sensors to the ammonia concentration showed linearity. The gas sensor based on ZnO/PPy heteronanocomposites showed od selectivity to ammonia when in the presence of interfering gases such as methanol, acetone, and toluene. The formation mechanism of the ZnO/PPy hetero-nanocomposites was briefly analyzed.
- In-situ polymerization,
- Hetero-nanocomposite,
- Gas sensor,
- Gas sensing property,
- Formation mechanism
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