Citation: HUANG Zhi-Peng, GUO Lin-Yu, GUO Chao, ZHAO Meng-Meng, WANG Xue-Hua, JIN Zhao, LUO Jin-Hua, WANG Xin, FENG Ji-Jun. Synthesis of Fluorinated Polyanionic Lithium Ion Insertion/Extraction Material LiVPO₄F/C by Carbon Thermal Reduction Assisted Sol-Gel Method[J]. Acta Physico-Chimica Sinica, ;2015, 31(4): 700-706. doi: 10.3866/PKU.WHXB201501261 shu

Synthesis of Fluorinated Polyanionic Lithium Ion Insertion/Extraction Material LiVPO₄F/C by Carbon Thermal Reduction Assisted Sol-Gel Method

1.
1 School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, P. R. China;
2 School of Chemistry and Biological Engineering, Qilu Institute of Technology, Zhangqiu 250200, Shandong Province, P. R. China

Received Date: 19 November 2014
Available Online: 26 January 2015
Fund Project: 国家自然科学基金(51102114) (51102114) 济南市科技发展计划(201401234) (201401234)国家级大学生创新创业训练计划(201310427010)资助项目 (201310427010)

LiVPO₄F/C, as a cathode material of lithium- ion batteries, was prepared by carbon thermal reduction assisted sol-gel method. X-ray diffraction (XRD), scanning electron microscopy (SEM), galvanostatic charge-discharge cycles, cyclic voltammogram (CV), and electrochemical impedance spectroscopy (EIS) were employed to investigate the effects of sintering time and temperature on the structure and corresponding electrochemical performance of as prepared materials. At a sintering time of 4 h, pure phase LiVPO₄F/C material was obtained when the temperature is settled at 450 ℃. The as-produced LiVPO₄F/C exhibited discharge capacities of 193.2, 175.6, and 173.7 mAh·g^-1 at 0.1C, 0.5C, and 1.0C rates, respectively. Li₃V₂(PO₄)₃ impurities are formed and increased with increasing calcination temperature. When sintered at 650 ℃ Li₃V₂(PO₄)₃ is turn out to be the main phase. On the other hand, optimal duration time at high temperature could also inhibit the decomposition of LiVPO₄F and decrease the formation of Li₃V₂(PO₄)₃ impurities, improving electrochemical performance. Optimal conditions were found at a residence time of 3 h when the precursor is sintered at 550 ℃.
- Lithium-ion battery,
- Cathode material,
- Sol-gel,
- Carbon thermal reduction,
- LiVPO₄F/C
1. [1]
  
  (1) Whittingham, M. S. Chem. Rev. 2004, 104, 4271. doi: 10.1021/cr020731c
2. [2]
  (2) Tarascon, J. M.; Armand, M. Nature 2001, 414, 359. doi: 10.1038/35104644
3. [3]
  (3) Ai, D. J.; Liu, K. Y.; Lu, Z. G.; Zou, M. M.; Zeng, D. Q.; Ma, J. Electrochim. Acta 2011, 56, 2823. doi: 10.1016/j.electacta.2010.12.063
4. [4]
  (4) Padhi, A. K.; Najundaswamy, K. S.; odenough, J. B. J. Electrochem. Soc. 1997, 144, 1188. doi: 10.1149/1.1837571
5. [5]
  (5) Chang, C. X.; Xiang, J. F.; Shi, X. X.; Han, X. Y.; Yuan, L. J.; Sun, J. T. Electrochim. Acta 2008, 54, 623. doi: 10.1016/j.electacta.2008.07.038
6. [6]
  (6) Reimers, J. N.; Dahn, J. R. J. Electrochemi. Soc. 1992, 139, 2091. doi: 10.1149/1.2221184
7. [7]
  (7) Wu, L.; Zhong, S. K.; Liu, J. Q.; Lv, F.; Wan, K. Mater. Lett. 2012, 89, 32. doi: 10.1016/j.matlet.2012.08.076
8. [8]
  (8) Feng, J. J.; Huang, Z. P.; Guo, C.; Chernova, N. A.; Upreti, S.; Whittingham, M. S. ACS Appl. Mater. Interfaces 2013, 5, 10227. doi: 10.1021/am4029526
9. [9]
  (9) Li, Z.; Chernova, N. A.; Feng, J. J.; Upreti, S.; Omenya, F.; Whittingham, M. S. J. Electrochem. Soc. 2012, 159, A116.
10. [10]
  (10) Barker, J.; Saidi, M. Y.; Swoyer, J. L. Lithium Metal Fluorophosphate Materials and Preparation Thereof. US 6387568 B1, 2002.
11. [11]
  (11) Barker, J.; Saidi, M. Y.; Swoyer, J. L. J. Electrochem. Soc. 2003, 150 (10), A1394.
12. [12]
  (12) Zhong, S. K.; Chen, W.; Liu, C. J. Trans. Nonferrous Met. Soc. China 2010, 20, s275.
13. [13]
  (13) Lee, K.; Myung, S.; Yashiro, H.; Sun, Y. Electrochim. Acta 2008, 53, 3065. doi: 10.1016/j.electacta.2007.11.042
14. [14]
  (14) Wang, L.; Huang, Y.; Jiang, R.; Jia, D. Electrochim. Acta 2007, 52, 6778. doi: 10.1016/j.electacta.2007.04.104
15. [15]
  (15) Feng, J. J.; Liu, X. Z.; Zhang, X. M.; Jiang, J. Z.; Zhao, J.; Wang, M. J. Electrochem. Soc. 2009, 156, A768.
16. [16]
  (16) Liu, L.; Tian, F. H.; Wang, X. Y.; Zhou, M. Acta Phys. -Chim. Sin. 2011, 27, 2600. [刘黎, 田方华, 王先友, 周萌. 物理化学学报, 2011, 27, 2600.] doi: 10.3866/PKU.WHXB20111126
17. [17]
  (17) Ellis, B. L.; Ramesh, T. N.; Davis, L. J. M.; ward, G. R.; Nazar, L. F. Chem. Mater. 2011, 23, 5138. doi: 10.1021/cm201773n
18. [18]
  (18) Barker, J.; ver, R. K. B.; Burns, P.; Bryan, A.; Saidi, M. Y.; Swoyer, J. L. J. Power Sources 2005, 146, 516. doi: 10.1016/j.jpowsour.2005.03.126
19. [19]
  (19) Wang, J. X.; Wang, Z. X.; Shen, L.; Li, X. H.; Guo, H. J.; Tang, W. J.; Zhu, Z. G. Trans. Nonferrous Met. Soc. China 2013, 23, 1718. doi: 10.1016/S1003-6326(13)62653-9
20. [20]
  (20) Xiao, P. F.; Lai, M. O.; Lu, L. Solid State Ionics 2013, 242, 10. doi: 10.1016/j.ssi.2013.04.002
21. [21]
  (21) Li, Y. Z.; Zhou, Z.; Gao, X. P.; Yan, J. J. Power Sources 2006, 160, 633. doi: 10.1016/j.jpowsour.2006.01.067
22. [22]
  (22) Xiong, Z. Q.; Zhang, G. Q.; Xiong, J. Q.; Yang, X. Q.; Zhang, Y. Y. Mater. Lett. 2013, 111, 214. doi: 10.1016/j.matlet.2013.08.086
23. [23]
  (23) Piao, Y.; Lin, Lin, C. K.; Qin, Y.; Zhou, D. H.; Ren, Y.; Bloom, I.; Wei, Y. J.; Chen, G.; Chen, Z. H. J. Power Sources 2015, 273, 1250. doi: 10.1016/j.jpowsour.2013.11.127
24. [24]
  (24) Sun, X. F.; Xu, Y. L.; Chen, G. G.; Ding, P.; Zheng, X. Y. Solid State Ionics 2014, 268, 236. doi: 10.1016/j.ssi.2014.08.008
25. [25]
  (25) Wang, Y. L.; Zhao, H. X.; Ji, Y. F.; Wang, L. H.; Wei, Z. Solid State Ionics 2014, 268, 169. doi: 10.1016/j.ssi.2014.10.031
26. [26]
  (26) Huang, H.; Yin, S. C.; Kerr, T.; Taylor, N.; Nazar, L. F. Adv. Mater. 2002, 14, 1525. doi: 10.1002/1521-4095(20021104)14: 21<1525::AID-ADMA1525>3.0.CO;2-3
27. [27]
  (27) Wei, Y.; Wang, L. J.; Yan, J.; Sha, O.; Tang, Z. Y.; Ma, L. Acta Phys. -Chim. Sin. 2011, 27, 2587. [魏怡, 王利娟, 闫继, 沙鸥, 唐致远, 马莉. 物理化学学报, 2011, 27, 2587.] doi: 10.3866/PKU.WHXB20111124
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
3. [3]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
4. [4]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
5. [5]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
6. [6]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
7. [7]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
8. [8]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
9. [9]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
10. [10]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
11. [11]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
12. [12]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
13. [13]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
14. [14]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
15. [15]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
16. [16]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
17. [17]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
18. [18]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
19. [19]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
20. [20]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312

Get Citation

PDF

XML

Metrics

PDF Downloads(326)
Abstract views(927)
HTML views(106)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Fluorinated Polyanionic Lithium Ion Insertion/Extraction Material LiVPO4F/C by Carbon Thermal Reduction Assisted Sol-Gel Method

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis of Fluorinated Polyanionic Lithium Ion Insertion/Extraction Material LiVPO₄F/C by Carbon Thermal Reduction Assisted Sol-Gel Method