Citation: QI Qiang, HUANG Mengbing, ZHANG Hai-Bin, SHI Li-Qun. Investigation of Helium Diffusion Behavior in Ti₃SiC₂ by ³He (d, p) ⁴He Nuclear Reaction[J]. Acta Physico-Chimica Sinica, ;2015, 31(S1): 54-58. doi: 10.3866/PKU.WHXB2014Ac15 shu

Investigation of Helium Diffusion Behavior in Ti₃SiC₂ by ³He (d, p) ⁴He Nuclear Reaction

1.
1 Applied Ion Beam Physics Laboratory, Institute of Modern Physics, Fudan University, Shanghai 200433, P. R. China;
2.
2 Ion Beam Laboratory, State University of New York (SUNY) at Albany & SUNY College of Nanoscale Science and Engineering, Albany 12203, New York, U. S. A.;
3.
3 Institute of Nuclear Physics and Chemistry, Chinese Academy of Engineering Physics, Mianyang 610003, Sichuan Province, P. R. China;
4.
4 Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031, P. R. China

Corresponding author: SHI Li-Qun,

In fusion and fission energy devices, the first wall/cladding structure materials are in a harsh environment. The effect of hydrogen and helium produced by transmutation on the structural materials is one of the critical problems for future nuclear reactors. Ti₃SiC₂ is a high performance ceramic material that combines the advantages of ceramics and metals, and it has excellent resistance to irradiation damage. In this work, the helium diffusion constants and concentration profiles in Ti₃SiC₂ from 400 to 1100 ℃ were obtained using the resonant ³He (d, p) ⁴He nuclear reaction, and the helium diffusion behavior is also discussed. The concentration profiles were found to change because of the interaction between helium evolution and stress in the material.
- Ti₃SiC₂ MAX phase,
- Helium diffusion behavior,
- ³He (d, p) ⁴He nuclear reaction,
- Helium bubble,
- Irradiation damage
1. [1]
  (1) Oo, Z.; Low, I. M.; O'Connor, B. H. Physica B 2006, 385-386, 499.
2. [2]
  (2) Barsoum, M.W. Prog. Solid State Chem. 2000, 28, 201. doi: 10.1016/S0079-6786(00)00006-6
3. [3]
  (3) Gilbert, C. J.; Bloyer, D. R.; Barsoum, M.W.; El-Raghy, T.; Tomsia, A. P.; Ritchie, R. O. Scripta Mater. 2000, 42, 761. doi: 10.1016/S1359-6462(99)00427-3
4. [4]
  (4) Barsoum, M.W.; El-Raghy, T.; Rawn, C. J.; Porter, W. D.; Wang, H.; Payzant, E. A.; Hubbard, C. R. J. Phys. Chem. Solids 1999, 60, 429. doi: 10.1016/S0022-3697(98)00313-8
5. [5]
  (5) Gao, N. F.; Miyamoto, Y.; Zhang, D. Mater. Lett. 2002, 55, 61. doi: 10.1016/S0167-577X(01)00620-6
6. [6]
  (6) El-Raghy, T.; Barsoum, M.W.; Zavaliangos, A.; Kalidindi, S. R. J. Am. Ceram. Soc. 1999, 82, 2855.
7. [7]
  (7) Whittle, K. R.; Blackford, M. G.; Aughterson, R. D.; Moricca, S.; Lumpkin, G. R.; Riley, D. P.; Zaluzec, N. J. Acta Mater. 2010, 58, 4362. doi: 10.1016/j.actamat.2010.04.029
8. [8]
  (8) Barsoum, M.W.; El-Raghy T. Am. Sci. 2001, 89, 334. doi: 10.1511/2001.28.736
9. [9]
  (9) Kooi, B. J.; Poppen, R. J.; Carvalho, N. J. M.; De Hosson, J. T. M.; Barsoum, M.W. Acta Mater. 2003, 51, 2859.
10. [10]
  (10) Costantini, J. M.; Trocellier, P.; Haussy, J.; Grob, J. J. Nucl. Instrum. Meth. B 2002, 195, 400. doi: 10.1016/S0168-583X(02)01137-0
11. [11]
  (11) Costantini, J. M.; Grob, J. J.; Haussy, J.; Trocellier, P.; Trouslard, P. J. Nucl. Mater. 2003, 321, 281. doi: 10.1016/S0022-3115(03)00280-0
12. [12]
  (12) Zielinski, F.; Costantini, J. M.; Haussy, J.; Durbin, F. J. Nucl. Mater. 2003, 312, 141. doi: 10.1016/S0022-3115(02)01589-1
13. [13]
  (13) Dominique, G.; Patrick, T.; Yves, S. J. Nucl. Mater. 2002, 303, 115. doi: 10.1016/S0022-3115(02)00822-X
14. [14]
  (14) Paszti, F. Nucl. Instrum. Meth. B 1992, 66, 83. doi: 10.1016/0168-583X(92)96143-M
15. [15]
  (15) Qi, Q.; Cheng, G. J.; Shi, L. Q.; O'Connor, D. J.; King, B. V.; Kisi, E. H. Acta Mater. 2014, 66, 317. doi: 10.1016/j.actamat.2013.11.019
16. [16]
  (16) Ziegler, J. F.; Biersack, J. P. The Stopping and Range of Ions in Matter (SRIM), SRIM 2010; http://www.srim.org.
17. [17]
  (17) Mayer, J.W.; Rimini, E. Ion Beam Handbook for Material Analysis; Academic: New York, 1977.
18. [18]
  (18) Biersack, J. P.; Haggmark, L. G. Nucl. Instrum. Meth. B 1980, 174, 257. doi: 10.1016/0029-554X(80)90440-1
19. [19]
  (19) Ryssel, H.; Ruge, I. Ion Implantation;Wiley: Chichester, 1986.
20. [20]
  (20) Philibert, J. Diffusion and Matter Transport in Solids; Philibert, J. Ed.; de Physique: Paris, 1985.
21. [21]
  (21) Reed, D. J. Radiat. Effects 1977, 31, 129.
22. [22]
  (22) Lewis, M. B.; Farell, K. Nucl. Instrum. Meth. B 1986, 16, 163. doi: 10.1016/0168-583X(86)90008-X
23. [23]
  (23) Donnelly, S. E.; Evans, J. H. Eds. Fundamentals of Inert Gases in Solids; Plenum: New York, 1991.
24. [24]
  (24) Vassen, R.; Trinkaus, H.; Jung, P. Phys. Rev. B 1991, 44, 4206. doi: 10.1103/PhysRevB.44.4206
25. [25]
  (25) Jia, L. X.; Wang, Y. X.; Ou, X. D.; Shi, L.Q.; Ding, W. Mater. Lett. 2012, 83, 23. doi: 10.1016/j.matlet.2012.05.093
26. [26]
  (26) Middleburgh, S. C.; Lumpkin, G. R.; Riley, D. P. J. Am. Ceram. Soc. 2013, 96, 3196.
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Investigation of Helium Diffusion Behavior in Ti₃SiC₂ by ³He (d, p) ⁴He Nuclear Reaction