Citation: SUN Tao-Xiang, SHEN Xing-Hai, CHEN Qing-De. Investigation of Selective Extraction of UO₂²⁺ from Aqueous Solution by CMPO and TBP in Ionic Liquids[J]. Acta Physico-Chimica Sinica, ;2015, 31(S1): 32-38. doi: 10.3866/PKU.WHXB2014Ac10 shu

Investigation of Selective Extraction of UO₂²⁺ from Aqueous Solution by CMPO and TBP in Ionic Liquids

1.
Beijing National Laboratory for Molecular Sciences, Radiochemistry and Radiation Chemistry Key Laboratory of Fundamental Science, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Corresponding author: SHEN Xing-Hai,
Fund Project: 国家自然科学基金(20871009) (20871009)

The selective extraction of UO₂²⁺ from aqueous solution in the presence of other metal ions by octylphenyl-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) and tri-n-butyl phosphate (TBP) in ionic liquids (ILs), namely 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imides (C_nmimNTf₂, n=2, 4, 6, 8), were studied. The influences of the nitric acid concentration and the IL alkyl chain length on the distribution ratio and selectivity were examined. Compared with TBP in C4mimNTf2, CMPO in the ILs gave higher distribution ratios and better selectivities. Zr⁴⁺, ReO₄^-, and Cs⁺ were the main competing ions in the separation of UO₂²⁺ from simulated liquid waste (SLM) by the C_nmimNTf₂ systems. ReO₄^- and Cs⁺ were extracted by the ILs themselves. Zr⁴⁺ was extracted by CMPO or TBP in the ILs but not by the ILs themselves. This work gives further information on the use of ILs, and provides a basis for matching extractants with ILs in the processing of spent nuclear fuel.
- Ionic liquid,
- Extraction,
- Separation,
- Selectivity,
- UO₂²⁺
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Investigation of Selective Extraction of UO₂²⁺ from Aqueous Solution by CMPO and TBP in Ionic Liquids