Citation: WU Yan-Bo, BI Jun, WEI Bin-Bin. Preparation and Supercapacitor Properties of Double-Perovskite La₂CoNiO₆ Inorganic Nanofibers[J]. Acta Physico-Chimica Sinica, ;2015, 31(2): 315-321. doi: 10.3866/PKU.WHXB201412164 shu

Preparation and Supercapacitor Properties of Double-Perovskite La₂CoNiO₆ Inorganic Nanofibers

1.
College of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian 116028, Liaoning Province, P. R. China

Received Date: 5 September 2014
Available Online: 16 December 2014
Fund Project: 国家自然科学基金(21076028)资助项目 (21076028)

A La₂CoNiO₆ inorganic nanofiber supercapacitor electrode material was successfully prepared from a polyvinylpyrrolidone/lanthanum nitrate-cobalt acetate-nickel acetate (PVP/LCN) precursor by electrostatic spinning. Its surface morphology and structure were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). We found that the fibers were connected through rhombohedral La₂CoNiO₆ nanoparticles resulting in a linear spatial network structure. The electrochemical performance of the as-prepared inorganic nanofibers was characterized by cyclic voltammetry (CV), chronopotentiograms (CP), and cycle life tests. The results show that the La₂CoNiO₆ nanofiber electrode material has od capacitor performance. For the three-electrode system the electrode achieved a respectable specific capacitance of 335.0 F·g^-1 at 0.25 A·g^-1. For the symmetrical two-electrode system the electrode achieved a specific capacitance of 129.1 F·g^-1 at the same current density.
- Double-perovskite,
- Electrostatic spinning,
- Inorganic nanofiber,
- Supercapacitor,
- Electrode material
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Supercapacitor Properties of Double-Perovskite La2CoNiO6 Inorganic Nanofibers

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Preparation and Supercapacitor Properties of Double-Perovskite La₂CoNiO₆ Inorganic Nanofibers