Citation: ZHANG Jie, ZHANG Jiang-Hao, ZHANG Chang-Bin, HE Hong. Complete Catalytic Oxidation of Ethanol over MnO₂ with Different Crystal Phase Structures[J]. Acta Physico-Chimica Sinica, ;2015, 31(2): 353-359. doi: 10.3866/PKU.WHXB201412081 shu

Complete Catalytic Oxidation of Ethanol over MnO₂ with Different Crystal Phase Structures

1.
State Key Joint Laboratory of Environmental Simulation and Pollution Control, Center for Air Pollution Control Technology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, P. R. China

Received Date: 3 November 2014
Available Online: 8 December 2014
Fund Project: 国家自然科学基金(21422706) (21422706)国家高技术研究发展计划项目(863) (2012AA062702)资助 (863) (2012AA062702)

α-MnO₂, β-MnO₂, γ-MnO₂, and δ-MnO₂ catalysts were synthesized by hydrothermal methods, and their catalytic performances towards the oxidation of ethanol were evaluated in detail. The as-synthesized MnO₂ catalysts were characterized by N₂ adsorption- desorption measurements, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and H₂ temperature-programmed reduction (H₂-TPR). The α-MnO₂ catalyst showed the best activity of the catalysts tested for the combustion of ethanol and the trend in the activity of different MnO₂ catalysts towards the oxidation of ethanol was of the order α-MnO₂>δ-MnO₂>γ-MnO₂>β-MnO₂. The effect of the crystal phase structure on the activity of the MnO₂ catalysts was investigated. The XRD results showed that there were differences in the crystallinities of the α-, β-, γ-, δ-MnO₂ catalysts, but these differences did not have a significant effect on their catalytic performances towards the oxidation of ethanol. The BET surface areas of the α-, β-, γ-, δ-MnO₂ catalysts exhibited similar tendencies to their ethanol oxidation activities, although the results of standardization calculations showed that the surface area was not the main factor affecting their catalytical activities. The XPS results showed that the lattice oxygen concentration played an important role in defining the catalytic performance of the MnO₂. The α-MnO₂ catalyst showed the best reducibility of all of the MnO₂ catalysts tested, as determined by H₂-TPR. The excellent performance of α-MnO₂ was attributed to its higher lattice oxygen concentration and reducibility, which were identified as the main factors affecting the activity of the MnO₂ towards the complete oxidation of ethanol.
- MnO₂ catalyst,
- Low temperature catalytic oxidation,
- Ethanol complete oxidation,
- Volatile organic compound,
- Lattice oxygen
1. [1]
  
  (1) Amann, M.; Lutz, M. J. Hazard. Mater. 2000, 78, 41. doi: 10.1016/S0304-3894(00)00216-8
2. [2]
  (2) Grosjean, D.; Grosjean, E.; Gertler, A.W. Environ. Sci. Technol. 2001, 35, 45. doi: 10.1021/es001326a
3. [3]
  (3) Jacobson, M. Z. Environ. Sci. Technol. 2007, 41, 4150. doi: 10.1021/es062085v
4. [4]
  (4) Av uropoulos, G.; Oikonomopoulos, E.; Kanistras, D.; Ioannides, T. Appl. Catal. B: Environ. 2006, 65, 62. doi: 10.1016/j.apcatb.2005.12.016
5. [5]
  (5) Cordi, E. M.; Falconer, J. L. J. Catal. 1996, 162, 104. doi: 10.1006/jcat.1996.0264
6. [6]
  (6) Mitsui, T.; Tsutsui, K.; Matsui, T.; Kikuchi, R.; Eguchi, K. Appl. Catal. B: Environ. 2008, 81, 56. doi: 10.1016/j.apcatb.2007.12.006
7. [7]
  (7) Idriss, H.; Seebauer, E. G. J. Mol. Catal. A 2000, 152, 201. doi: 10.1016/S1381-1169(99)00297-6
8. [8]
  (8) Li, H. J.; Tana; Zhang, X. J.; Huang, X. M.; ShenW. J. Catal. Commun. 2011, 12, 1361. doi: 10.1016/j.catcom.2011.05.016
9. [9]
  (9) Ye, Q.; Gao, Q.; Zhang, X. R.; Xu, B. Q. Catal. Commun. 2006, 7, 589. doi: 10.1016/j.catcom.2006.01.023
10. [10]
  (10) Wang, R. H.; Li, J. H. Environ. Sci. Technol. 2010, 44, 4282. doi: 10.1021/es100253c
11. [11]
  (11) Zhao, P.;Wang, C. N.; He, F.; Liu, S. T. RSC Adv. 2014, 4, 45665. doi: 10.1039/C4RA07843H
12. [12]
  (12) Liang, S. H.; Teng, F.; Yao,W. Q.; Zhu, Y. F. Acta Phys. -Chim. Sin. 2008, 24, 205. [梁淑惠, 滕飞, 姚文清, 朱永法. 物理化学学报, 2008, 24, 205.] doi: 10.3866/PKU.WHXB20080205
13. [13]
  (13) Li, J.W.; Zhao, P.; Liu, S. T. Appl. Catal. A: Gen. 2014, 482, 363. doi: 10.1016/j.apcata.2014.06.013
14. [14]
  (14) Tang, X. F.; Li, Y. G.; Huang, X. M.; Xu, Y. D.; Zhu, H. Q.; Wang, J. G.; Shen,W. J. Appl. Catal. B: Environ. 2006, 62, 265. doi: 10.1016/j.apcatb.2005.08.004
15. [15]
  (15) Morales, M. R.; Barbero, B. P.; Cadús, L. E. Appl. Catal. B: Environ. 2007, 74, 1. doi: 10.1016/j.apcatb.2007.01.008
16. [16]
  (16) Njagi, E. C.; Chen, C. H.; Genuino, H.; Galindo, H.; Huang, H.; Suib, S. L. Appl Catal. B: Environ, 2010, 99, 103. doi: 10.1016/j.apcatb.2010.06.006
17. [17]
  (17) Luo, J.; Zhang, Q. H.; Garcia-Martin z, J.; Suib, S. L. J. Am. Chem. Soc. 2008, 130, 3198. doi: 10.1021/ja077706e
18. [18]
  (18) Ye, Q.; Zhao, J. S.; Huo, F. F.;Wang, D.; Cheng, S. Y.; Kang, T. F.; Dai, H. X. Microporous Mesoporous Mat. 2013, 172, 20. doi: 10.1016/j.micromeso.2013.01.007
19. [19]
  (19) Wu, X. Q.; Zong, R. L.; Zhu, Y. F. Acta Phys. -Chim. Sin. 2012, 28, 437. [吴小琴, 宗瑞隆, 朱永法. 物理化学学报, 2012, 28, 437.] doi: 10.3866/PKU.WHXB201112082
20. [20]
  (20) Sui, N.; Duan, Y. Z.; Jiao, X. L.; Chen, D. R. J. Phys. Chem. C 2009, 113, 8560.
21. [21]
  (21) Lin, J.; Cai, F.; Zhang, G. Y.; Yang, L. F.; Yang, J. Y.; Fang,W. P. Acta Phys. -Chim. Sin. 2013, 29, 597. [林健, 蔡钒,张国玉, 杨乐夫, 杨金玉, 方维平. 物理化学学报, 2013, 29, 597.] doi: 10.3866/PKU.WHXB201301041
22. [22]
  (22) Liang, S. H.; Teng, F.; Bulgan, G.; Zong, R. L.; Zhu, Y. F. J. Phys. Chem. C 2008, 112, 5307. doi: 10.1021/jp0774995
23. [23]
  (23) Xu, R.;Wang, X.;Wang, D. S.; Zhou, K. B.; Li, Y. D. J. Catal. 2006, 237, 426. doi: 10.1016/j.jcat.2005.10.026
24. [24]
  (24) Dai, Y.; Li, J. H.; Peng, Y.; Tang, X. F. Acta Phys. -Chim. Sin. 2012, 28, 1771. [戴韵, 李俊华, 彭悦, 唐幸福. 物理化学学报, 2012, 28, 1771.] doi: 10.3866/PKU.WHXB201204175
25. [25]
  (25) Li, J.W.; Song, C.; Liu, S. T. Acta Chim. Sin. 2012, 70, 2347. [李经纬, 宋灿, 刘善堂. 化学学报, 2012, 70, 2347.] doi: 10.6023/A12080562
26. [26]
  (26) Bastos, S. S. T.; Órfão, J. J. M.; Freitas, M. M. A.; Pereira, M. F. R.; Figueiredo, J. L. Appl. Catal. B: Environ. 2009, 93, 30. doi: 10.1016/j.apcatb.2009.09.009
27. [27]
  (27) Morales, M. R.; Barbero, B. P.; Cadús, L. E. Appl. Catal. B: Environ. 2006, 67, 229. doi: 10.1016/j.apcatb.2006.05.006
28. [28]
  (28) Delimaris, D.; Ioannides, T. Appl. Catal. B: Environ. 2008, 84, 303. doi: 10.1016/j.apcatb.2008.04.006
29. [29]
  (29) Fu, X. B.; Feng, J. Y.;Wang, H.; Ng, K. M. Catal. Commun. 2009, 10, 1844. doi: 10.1016/j.catcom.2009.06.013
30. [30]
  (30) Hu, J.; Sun, K. Q.; He, D. P.; Xu, B. Q. Chin. J. Catal. 2007, 28, 1025. [胡敬, 孙科强, 何代平, 徐柏庆. 催化学报, 2007, 28, 1025.] doi: 10.1016/S1872-2067(08)60001-7
31. [31]
  (31) Ye, Q.; Huo, F. F.; Yan, L. N.;Wang, J.; Cheng, S. Y.; Kang, T.F. Acta Phys. -Chim. Sin. 2011, 27, 2872. [叶青, 霍飞飞, 闫立娜, 王娟, 程水源, 康天放. 物理化学学报, 2011, 27, 2872.] doi: 10.3866/PKU.WHXB20112872
32. [32]
  (32) Dai, Y.;Wang, X. Y.; Li, D.; Dai, Q. G. J. Hazard. Mater. 2011, 188, 132. doi: 10.1016/j.jhazmat.2011.01.084
33. [33]
  (33) Liu, J.; Makwana, V.; Cai, J.; Suib, S. L.; Aindow, M. J. Phys. Chem. B 2003, 107, 9185. doi: 10.1021/jp0300593
1. [1]
  .
  CCS Chemistry 综述推荐│绿色氧化新思路：光/电催化助力有机物高效升级
  . CCS Chemistry, 2025, 7(10.31635/ccschem.024.202405369): -.
2. [2]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
3. [3]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
4. [4]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
5. [5]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
6. [6]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
7. [7]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
8. [8]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
9. [9]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
10. [10]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
11. [11]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
12. [12]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
13. [13]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
14. [14]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
15. [15]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
16. [16]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
17. [17]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
18. [18]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
19. [19]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
20. [20]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004

Get Citation

PDF

XML

Metrics

PDF Downloads(428)
Abstract views(772)
HTML views(47)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Complete Catalytic Oxidation of Ethanol over MnO2 with Different Crystal Phase Structures

Metrics

通讯作者: 陈斌, bchen63@163.com

Complete Catalytic Oxidation of Ethanol over MnO₂ with Different Crystal Phase Structures