Citation: LU Xiao-Lin, ZHOU Jie, LI Bo-Lin. Nonlinear Optical Responses of Thiol Chains in Different Confined States[J]. Acta Physico-Chimica Sinica, ;2014, 30(12): 2342-2348. doi: 10.3866/PKU.WHXB201410172 shu

Nonlinear Optical Responses of Thiol Chains in Different Confined States

LU Xiao-Lin ^1,2, ,
ZHOU Jie ² ,
LI Bo-Lin ¹

1.
1. State Key Laboratory of Bioelectronics, School of Biological Science & Medical Engineering, Southeast University, Nanjing 210096, P. R. China;
2. Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Education Ministry, Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. China

Received Date: 23 September 2014
Available Online: 17 October 2014
Fund Project: 国家自然科学基金(51173169, 21004054) (51173169, 21004054) 教育部留学归国人员科研启动基金, 浙江省留学人员科技活动项目择优资助项目和江苏高校优势学科建设工程项目(PAPD 1107037001)资助 (PAPD 1107037001)

The molecular vibrational signals of n-dodecanethiol (DDT) were detected in different confined states using sum frequency generation (SFG) vibrational spectroscopy. Samples with three different confined states were used, including a self-assembled monolayer (SAM) of DDTmolecules on a ld (Au) substrate, DDT surface-functionalized Au nanoparticles on a silica substrate, and surface-functionalized Au nanoparticles dispersed in a toluene solution. The vibrational spectra of the DDT molecules were successfully captured for all three samples, and the spectral differences provided evidence of the different confined structures. On the Au substrate, the DDT molecules orderly packed together; on the silica substrate, the DDT molecules attached to the Au nanoparticle surfaces were somehow flexible; and at the air-toluene interface, the DDT molecules attached to the Au nanoparticle surfaces were highly disordered. The spectral analysis indicated that the molecular vibrational signals generated from the Au nanoparticle surfaces were enhanced because of the localized enhanced fields near the Au nanoparticle surfaces, with the enhancement factors of 10²-10³ over the SAM of DDT molecules on the Au substrate, depending on the selected polarization combination.
- Sum frequency generation vibrational spectroscopy,
- Au nanoparticle,
- n-Dodecanethiol,
- Self-assembled monolayer,
- Air-liquid interface
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