Citation: LU Xiao-Lin, ZHOU Jie, LI Bo-Lin. Nonlinear Optical Responses of Thiol Chains in Different Confined States[J]. Acta Physico-Chimica Sinica, ;2014, 30(12): 2342-2348. doi: 10.3866/PKU.WHXB201410172 shu

Nonlinear Optical Responses of Thiol Chains in Different Confined States

LU Xiao-Lin ^1,2, ,
ZHOU Jie ² ,
LI Bo-Lin ¹

1.
1. State Key Laboratory of Bioelectronics, School of Biological Science & Medical Engineering, Southeast University, Nanjing 210096, P. R. China;
2. Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Education Ministry, Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. China

Received Date: 23 September 2014
Available Online: 17 October 2014
Fund Project: 国家自然科学基金(51173169, 21004054) (51173169, 21004054) 教育部留学归国人员科研启动基金, 浙江省留学人员科技活动项目择优资助项目和江苏高校优势学科建设工程项目(PAPD 1107037001)资助 (PAPD 1107037001)

The molecular vibrational signals of n-dodecanethiol (DDT) were detected in different confined states using sum frequency generation (SFG) vibrational spectroscopy. Samples with three different confined states were used, including a self-assembled monolayer (SAM) of DDTmolecules on a ld (Au) substrate, DDT surface-functionalized Au nanoparticles on a silica substrate, and surface-functionalized Au nanoparticles dispersed in a toluene solution. The vibrational spectra of the DDT molecules were successfully captured for all three samples, and the spectral differences provided evidence of the different confined structures. On the Au substrate, the DDT molecules orderly packed together; on the silica substrate, the DDT molecules attached to the Au nanoparticle surfaces were somehow flexible; and at the air-toluene interface, the DDT molecules attached to the Au nanoparticle surfaces were highly disordered. The spectral analysis indicated that the molecular vibrational signals generated from the Au nanoparticle surfaces were enhanced because of the localized enhanced fields near the Au nanoparticle surfaces, with the enhancement factors of 10²-10³ over the SAM of DDT molecules on the Au substrate, depending on the selected polarization combination.
- Sum frequency generation vibrational spectroscopy,
- Au nanoparticle,
- n-Dodecanethiol,
- Self-assembled monolayer,
- Air-liquid interface
1. [1]
  
  (1) Mahmoudi, M.; Azadmanesh, K.; Shokr zar, M. A.; Journeay, W. S.; Laurent, S. Chem. Rev. 2011, 111, 3407. doi: 10.1021/cr1003166
2. [2]
  (2) Zijlstra, P.; Orrit, M. Rep. Prog. Phys. 2011, 74, 106401. doi: 10.1088/0034-4885/74/10/106401
3. [3]
  (3) Stratakis, M.; Garcia, H. Chem. Rev. 2012, 112, 4469. doi: 10.1021/cr3000785
4. [4]
  (4) Shen, Y. R. The Principles of Nonlinear Optics;Wiley: New York, 1984; pp 67-85.
5. [5]
  (5) Shen, Y. R. Nature 1989, 337, 519. doi: 10.1038/337519a0
6. [6]
  (6) Shen, Y. R. Annu. Rev. Phys. Chem. 1989, 40, 327. doi: 10.1146/annurev.pc.40.100189.001551
7. [7]
  (7) Hirose, C.; Akamatsu, N.; Domen, K. Appl. Spectrosc. 1992, 46, 1051. doi: 10.1366/0003702924124385
8. [8]
  (8) Eisenthal, K. B. Chem. Rev. 1996, 96, 1343. doi: 10.1021/cr9502211
9. [9]
  (9) Conboy, J. C.; Messmer, M. C.;Walker, R. A.; Richmond, G. L. Prog. Colloid Polym. Sci. 1997, 103, 10. doi: 10.1007/3-798-51084-9
10. [10]
  (10) Buck, M.; Himmelhaus, M. J. Vac. Sci. Technol. A 2001, 19, 2717.
11. [11]
  (11) Chen, Z.; Shen, Y. R.; Somorjai, G. A. Annu. Rev. Phys. Chem. 2002, 53, 437. doi: 10.1146/annurev.physchem. 53.091801.115126
12. [12]
  (12) Richmond, G. L. Chem. Rev. 2002, 102, 2693. doi: 10.1021/cr0006876
13. [13]
  (13) Wang, H. F.; Gan,W.; Lu, R.; Rao, Y. ;Wu, B. H. Int. Rev. Phys. Chem. 2005, 24, 191. doi: 10.1080/01442350500225894
14. [14]
  (14) Vidal, F.; Tadjeddine, A. Rep. Prog. Phys. 2005, 68, 1095. doi: 10.1088/0034-4885/68/5/R03
15. [15]
  (15) Shen, Y. R.; Ostroverkhov, V. Chem. Rev. 2006, 106, 1140. doi: 10.1021/cr040377d
16. [16]
  (16) Allen, H. C.; Casillas-Ituarte, N. N.; Sierra-Hernández, M. R.; Chen, X.; Tang, C. Y. Phys. Chem. Chem. Phys. 2009, 11, 5538. doi: 10.1039/b901209e
17. [17]
  (17) Roke, S. ChemPhysChem 2009, 10, 1380. doi: 10.1002/cphc.v10:9/10
18. [18]
  (18) Chen, Z. Prog. Polym. Sci. 2010, 35, 1376. doi: 10.1016/j.progpolymsci.2010.07.003
19. [19]
  (19) Lu, X.; Chen, Z.; Xue, G.;Wang, X. Front. Chem. China 2010, 5, 435. doi: 10.1007/s11458-010-0220-7
20. [20]
  (20) Chen, Z. Acta Phys. -Chim. Sin. 2012, 28, 504. [陈战. 物理化学学报, 2012, 28, 504. ] doi: 10.3866/PKU.WHXB201201091
21. [21]
  (21) Yan, E. C. Y.; Fu, L.;Wang, Z.; Liu,W. Chem. Rev. 2014, 114, 8471. doi: 10.1021/cr4006044
22. [22]
  (22) Weeramanm C.; Yatawara, A. K.; Bordenyuk, A. N.; Benderskii, A. V. J. Am. Chem. Soc. 2006, 128, 14244. doi: 10.1021/ja065756y
23. [23]
  (23) Bordenyuk, A. N.;Weeramanm C.; Yatawara, A. K.; Jayathilake, H. D.; Stiopkin, I.; Liu, Y.; Benderskii, A. V. J. Phys. Chem. C 2007, 111, 8925.
24. [24]
  (24) Tourillon, G.; Dreesen, L.; Volcke, C.; Sartenaer, Y.; Thiry, P. A.; Peremans, A. Nanotechnology 2007, 18, 415301. doi: 10.1088/0957-4484/18/41/415301
25. [25]
  (25) Humbert, C.; Pluchery, O.; Lacaze, E.; Tadjeddine, A.; Busson, B. Phys. Chem. Chem. Phys. 2012, 14, 280. doi: 10.1039/c1cp21091b
26. [26]
  (26) Himmelhaus, M.; Eisert, F.; Buck, M.; Grunze, M. J. Phys. Chem. B 2000, 104, 576. doi: 10.1021/jp992073e
27. [27]
  (27) Nishi, N.; Hobara, D.; Yammoto, M.; Kakiuchi, T. J. Chem. Phys. 2003, 118, 1904. doi: 10.1063/1.1531098
28. [28]
  (28) Zhang, H.; Romero, C.; Baldelli, S. J. Phys. Chem. B 2005, 109, 15520. doi: 10.1021/jp052807p
29. [29]
  (29) Busson, B.; Tadjeddine, A. J. Phys. Chem. C 2009, 113, 21895. doi: 10.1021/jp908240d
30. [30]
  (30) Braun, R.; Casson, B. D.; Bain, C. D.; van der Ham, E.W. M.; Vrehen, Q. H. F.; Eliel, E. R.; Briggs, A. M.; Davies, P. B. J. Chem. Phys. 1999, 110, 4634. doi: 10.1063/1.478345
31. [31]
  (31) Zhu, X. D.; Suhr, H.; Shen, Y. R. Phys. Rev. B 1987, 35, 3047. doi: 10.1103/PhysRevB.35.3047
32. [32]
  (32) Zhuang, X.; Miranda, P. B.; Kim, D.; Shen, Y. R. Phys. Rev. B 1999, 59, 12632. doi: 10.1103/PhysRevB.59.12632
33. [33]
  (33) Opdahl, A.; Somorjai, G. A. Langmuir 2002, 18, 9409. doi: 10.1021/la020537l
34. [34]
  (34) Varsanyi, G. Vibrational Spectra of Benzene Derivatives; New York: Academic Press, 1969; pp 283-299.
1. [1]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
2. [2]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
3. [3]
  Huihui LIU , Baichuan ZHAO , Chuanhui WANG , Zhi WANG , Congyun ZHANG . Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059
4. [4]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
5. [5]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
6. [6]
  Huanhuan XIE , Yingnan SONG , Lei LI . Two-dimensional single-layer BiOI nanosheets: Lattice thermal conductivity and phonon transport mechanism. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 702-708. doi: 10.11862/CJIC.20240281
7. [7]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
8. [8]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
9. [9]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
10. [10]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
11. [11]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
12. [12]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
13. [13]
  Cuicui Yang , Bo Shang , Xiaohua Chen , Weiquan Tian . Understanding the Wave-Particle Duality and Quantization of Confined Particles Starting from Classic Mechanics. University Chemistry, 2025, 40(3): 408-414. doi: 10.12461/PKU.DXHX202407066
14. [14]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
15. [15]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
16. [16]
  Hong RAO , Yang HU , Yicong MA , Chunxin LÜ , Wei ZHONG , Lihua DU . Synthesis and in vitro anticancer activity of phenanthroline-functionalized nitrogen heterocyclic carbene homo- and heterobimetallic silver/gold complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2429-2437. doi: 10.11862/CJIC.20240275
17. [17]
  Yutong Dong , Huiling Xu , Yucheng Zhao , Zexin Zhang , Ying Wang . The Hidden World of Surface Tension and Droplets. University Chemistry, 2024, 39(6): 357-365. doi: 10.3866/PKU.DXHX202312022
18. [18]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
19. [19]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
20. [20]
  Yongjie ZHANG , Bintong HUANG , Yueming ZHAI . Research progress of formation mechanism and characterization techniques of protein corona on the surface of nanoparticles. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2318-2334. doi: 10.11862/CJIC.20240247

Get Citation

PDF

XML

Metrics

PDF Downloads(311)
Abstract views(570)
HTML views(19)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142