Citation: HUANG Tian-Hui, ZHAO Yu-Juan, TIAN Zhao-Fu, LI Xiao-Lan, LIU Qian, ZHAO Dong-Yuan. Adsorption Properties of Ordered Mesoporous Silica for Butyraldehyde[J]. Acta Physico-Chimica Sinica, ;2014, 30(12): 2307-2314. doi: 10.3866/PKU.WHXB201410142 shu

Adsorption Properties of Ordered Mesoporous Silica for Butyraldehyde

1.
1. Technology Centre, China Tobacco Guangxi Industrial Incorporation, Nanning 530001, P. R. China;
2. Department of Chemistry, Fudan University, Shanghai 200433, P. R. China

Received Date: 8 July 2014
Available Online: 14 October 2014
Fund Project: 真龙-复旦功能材料化学联合实验室项目(20120208Y)资助 (20120208Y)

Ordered mesoporous silica materials SBA-15, MCM-41, SBA-16, KIT-6 with different pore sizes and properties were prepared. Several SBA-15 materials were synthesized with different pore diameters by changing the hydrothermal temperature. The materials produced were characterized using small-angle X-ray scattering (SAXS), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and nitrogen adsorption/desorption. The adsorption isotherms of organic aldehyde were measured, using butyraldehyde as a model molecule. The results were compared with those for the adsorption capacity of Y-zeolite; they showed that the specific surface area originating from the mesopores was proportional to the amount of butyraldehyde adsorption. The adsorption isotherms agreed with Langmuir mode for monolayer adsorption. Mesoporous silica MCM-41 with the highest mesopore specific surface area showed the highest adsorbed amount of butyraldehyde (484 mg·g^-1). The SBA-15 sample was selected for the fabrication of cigarette filters, and the results showed that SBA-15 significantly reduced the amount of Croton aldehyde released in cigarette smoke.
- Mesoporous silica,
- Synthesis,
- Adsorption,
- Butyraldehyde,
- Croton aldehyde,
- Cigarette smoke
1. [1]
  
  (1) Pak, A. M.; Vozdvizhenskii, V. F.; Turganbaeva, S. M.; Levintova, T. D.; Konuspaev, S. R. React. Kinet. Catal. Lett. 1983, 23, 1. doi: 10.1007/BF02065653
2. [2]
  (2) Haubrich, J.; Loffreda, D.; Delbecq, F.; Sautet, P.; Jugnet, Y.; Becker, C.;Wandelt, K. J. Phys. Chem. C 2010, 114 (2), 1073. doi: 10.1021/jp908353p
3. [3]
  (3) Phillips, T. K.; Bhinde, T.; Clark, S. M.; Lee, S. Y. J. Phys. Chem. C 2010, 114 (13), 6027. doi: 10.1021/jp911069t
4. [4]
  (4) Yang, H. S.;Weinstock, B. A.; Hirsche, B. L.; Hirsche, B. L., II; Griffiths, P. R. Langmuir 2005, 21 (9), 3921. doi: 10.1021/la048365a
5. [5]
  (5) Wan, Y.; Zhao, D. Y. Chem. Rev. 2007, 107 (7), 2821. doi: 10.1021/cr068020s
6. [6]
  (6) Zhang, Y. M.; Qiao, Z. A.; Li, Y. T.; Liu, Y. L.; Huo, Q. S. J. Mater. Chem. 2011, 21 (43), 17283. doi: 10.1039/c1jm12259b
7. [7]
  (7) Wu, Z. X.; Zhao, D. Y. Chem. Commun. 2011, 47 (12), 3332. doi: 10.1039/c0cc04909c
8. [8]
  (8) Zhou, C. F.;Wang, Y. M.; Cao, Y.; Zhuang, T. T.; Huang,W.; Chun, Y.; Zhu, J. H. J. Mater. Chem. 2006, 16 (16), 1520. doi: 10.1039/b514317a
9. [9]
  (9) Wei, F.; Gu, F. N.; Zhou, Y.; Gao, L.; Yang, J.; Zhu, J. H. Solid State Sci. 2009, 11 (2), 402. doi: 10.1016/j.solidstatesciences.2008.07.001
10. [10]
  (10) Lin,W. G.;Wei, F.; Gu, F. N.; Dong, X.; Gao, L.; Zhuang, T. T.; Yue, M. B.; Zhu, J. H. J. Colloid Interface Sci. 2010, 348 (2), 621. doi: 10.1016/j.jcis.2010.05.012
11. [11]
  (11) Cao, Y.; Yun, Z. Y.; Yang, J.; Dong, X.; Zhou, C. F.; Zhuang, T. T.; Yu, Q.; Liu, H. D.; Zhu, J. H. Microporous Mesoporous Mat. 2007, 103, 352. doi: 10.1016/j.micromeso.2007.01.058
12. [12]
  (12) Zhou, C. F.; Zhu, J. H. Chemosphere 2005, 58 (1), 109. doi: 10.1016/j.chemosphere.2004.08.056
13. [13]
  (13) Liu, A. M.; Hidajat, K.; Kawi, S.; Zhao, D. Y. Chem. Commun. 2000, No. 13, 1145.
14. [14]
  (14) Algarra, M.; Jimenez, M. V.; Jimenez, J.; Jimenez-Lopez, A.; Jimenez-Jimenez, J. Chemosphere 2005, 59 (6), 779. doi: 10.1016/j.chemosphere.2004.11.023
15. [15]
  (15) Benitez, M.; Das, D.; Ferreira, R.; Pischel, U.; Garcia, H. Chem. Mater. 2006, 18 (23), 5597. doi: 10.1021/cm061287n
16. [16]
  (16) Jiang, Y. J.; Gao, Q. M.; Yu, H. G.; Chen, Y. R.; Deng, F. Microporous Mesoporous Mat. 2007, 103, 316. doi: 10.1016/j.micromeso.2007.02.024
17. [17]
  (17) Heidari, A.; Younesi, H.; Mehraban, Z. Chem. Eng. J. 2009, 153 (1-3), 70. doi: 10.1016/j.cej.2009.06.016
18. [18]
  (18) Gargiulo, N.; Peluso, A.; Paolo, A.; Pepe, F.; Caputo, D. J. Chem. Eng. Data 2014, 59 (3), 896. doi: 10.1021/je401075p
19. [19]
  (19) Shi, J. J.; Liu, Y. M.; Chen, J.; Zhang, Y.; Shi, Y. Acta Phys. -Chim. Sin. 2010, 26 (11), 3023. [史晶金, 刘亚敏, 陈杰, 张瑜, 施耀. 物理化学学报, 2010, 26 (11), 3023.] doi: 10.3866/PKU.WHXB20101109
20. [20]
  (20) Zhao, H. M.; Lin, D.; Yang, G.; Chun, Y.; Xu, X. H. Acta Phys. -Chim. Sin. 2012, 28 (4), 985. [赵会民, 林丹, 杨刚, 淳远, 须沁华. 物理化学学报, 2012, 28 (4), 985.] doi: 10.3866/PKU.WHXB201202071
21. [21]
  (21) Hao, N.; Yang, Y. X.;Wang, H. T.;Webley, P. A.; Zhao, D. Y. J. Colloid Interface Sci. 2010, 346 (2), 429. doi: 10.1016/j.jcis.2010.01.074
22. [22]
  (22) Wu, Z. X.; Yang, Y. X.; Tu, B.;Webley, P. A.; Zhao, D. Y. Adsorption 2009, 15 (2), 123. doi: 10.1007/s10450-009-9159-8
23. [23]
  (23) Yuan, J. F.; Li, J. S.; Gu, J.;Wang, F.; Sun, X. Y.; Han,W. Q.; Wang, L. J. Acta Phys. -Chim. Sin. 2010, 26 (6), 1711. [袁金芳, 李健生, 顾娟, 王放, 孙秀云, 韩卫清, 王连军. 物理化学学报, 2010, 26 (6), 1711.] doi: 10.3866/PKU.WHXB20100624
24. [24]
  (24) Ma, Z. F.; Bai, J.;Wang, Y. C.; Jiang, X. ACS Appl. Mater. Interfaces 2014, 6 (4), 2431. doi: 10.1021/am404860q
25. [25]
  (25) Sun, Z. K.; Deng, Y. H.;Wei, J.; Gu, D.; Zhao, D. Y. Chem. Mater. 2011, 23 (8), 2176. doi: 10.1021/cm103704s
26. [26]
  (26) Fan, J.; Yu, C. Z.; Gao, T.; Lei, J.; Tian, B. Z.;Wang, L. M.; Luo, Q.; Tu, B.; Zhou,W. Z.; Zhao, D. Y. Angew. Chem. Int. Edit. 2003, 42 (27), 3146. doi: 10.1002/anie.200351027
27. [27]
  (27) Wang, L. P.; Ren, F. L.;Wu, M. J.; He, Z. H.; Lian,W. L.; Hu, N. N. Chem. Rev. Appl. 2008, 28 (2), 796. [王丽苹, 任凤莲, 吴名剑, 何智慧, 练文柳, 胡念念. 分析实验室, 2008, 28 (2), 796.]
28. [28]
  (28) Xie, S. L.;Wang, K.; Ni, Z. M.; Zhu, R. Z.; Zhu, X.W.; Ren, Z. Y.;Wei,W. Z. Technol. Dev. Chem. Ind. 2009, 38 (11), 15. [谢山岭, 王凯, 倪朝敏, 朱瑞芝, 朱雄伟, 任卓英, 魏万之. 化工技术与开发, 2009, 38 (11), 15.]
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