Citation: HUANG Tian-Hui, ZHAO Yu-Juan, TIAN Zhao-Fu, LI Xiao-Lan, LIU Qian, ZHAO Dong-Yuan. Adsorption Properties of Ordered Mesoporous Silica for Butyraldehyde[J]. Acta Physico-Chimica Sinica, ;2014, 30(12): 2307-2314. doi: 10.3866/PKU.WHXB201410142 shu

Adsorption Properties of Ordered Mesoporous Silica for Butyraldehyde

1.
1. Technology Centre, China Tobacco Guangxi Industrial Incorporation, Nanning 530001, P. R. China;
2. Department of Chemistry, Fudan University, Shanghai 200433, P. R. China

Received Date: 8 July 2014
Available Online: 14 October 2014
Fund Project: 真龙-复旦功能材料化学联合实验室项目(20120208Y)资助 (20120208Y)

Ordered mesoporous silica materials SBA-15, MCM-41, SBA-16, KIT-6 with different pore sizes and properties were prepared. Several SBA-15 materials were synthesized with different pore diameters by changing the hydrothermal temperature. The materials produced were characterized using small-angle X-ray scattering (SAXS), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and nitrogen adsorption/desorption. The adsorption isotherms of organic aldehyde were measured, using butyraldehyde as a model molecule. The results were compared with those for the adsorption capacity of Y-zeolite; they showed that the specific surface area originating from the mesopores was proportional to the amount of butyraldehyde adsorption. The adsorption isotherms agreed with Langmuir mode for monolayer adsorption. Mesoporous silica MCM-41 with the highest mesopore specific surface area showed the highest adsorbed amount of butyraldehyde (484 mg·g^-1). The SBA-15 sample was selected for the fabrication of cigarette filters, and the results showed that SBA-15 significantly reduced the amount of Croton aldehyde released in cigarette smoke.
- Mesoporous silica,
- Synthesis,
- Adsorption,
- Butyraldehyde,
- Croton aldehyde,
- Cigarette smoke
References
1. [1]
  
  (1) Pak, A. M.; Vozdvizhenskii, V. F.; Turganbaeva, S. M.; Levintova, T. D.; Konuspaev, S. R. React. Kinet. Catal. Lett. 1983, 23, 1. doi: 10.1007/BF02065653
2. [2]
  (2) Haubrich, J.; Loffreda, D.; Delbecq, F.; Sautet, P.; Jugnet, Y.; Becker, C.;Wandelt, K. J. Phys. Chem. C 2010, 114 (2), 1073. doi: 10.1021/jp908353p
3. [3]
  (3) Phillips, T. K.; Bhinde, T.; Clark, S. M.; Lee, S. Y. J. Phys. Chem. C 2010, 114 (13), 6027. doi: 10.1021/jp911069t
4. [4]
  (4) Yang, H. S.;Weinstock, B. A.; Hirsche, B. L.; Hirsche, B. L., II; Griffiths, P. R. Langmuir 2005, 21 (9), 3921. doi: 10.1021/la048365a
5. [5]
  (5) Wan, Y.; Zhao, D. Y. Chem. Rev. 2007, 107 (7), 2821. doi: 10.1021/cr068020s
6. [6]
  (6) Zhang, Y. M.; Qiao, Z. A.; Li, Y. T.; Liu, Y. L.; Huo, Q. S. J. Mater. Chem. 2011, 21 (43), 17283. doi: 10.1039/c1jm12259b
7. [7]
  (7) Wu, Z. X.; Zhao, D. Y. Chem. Commun. 2011, 47 (12), 3332. doi: 10.1039/c0cc04909c
8. [8]
  (8) Zhou, C. F.;Wang, Y. M.; Cao, Y.; Zhuang, T. T.; Huang,W.; Chun, Y.; Zhu, J. H. J. Mater. Chem. 2006, 16 (16), 1520. doi: 10.1039/b514317a
9. [9]
  (9) Wei, F.; Gu, F. N.; Zhou, Y.; Gao, L.; Yang, J.; Zhu, J. H. Solid State Sci. 2009, 11 (2), 402. doi: 10.1016/j.solidstatesciences.2008.07.001
10. [10]
  (10) Lin,W. G.;Wei, F.; Gu, F. N.; Dong, X.; Gao, L.; Zhuang, T. T.; Yue, M. B.; Zhu, J. H. J. Colloid Interface Sci. 2010, 348 (2), 621. doi: 10.1016/j.jcis.2010.05.012
11. [11]
  (11) Cao, Y.; Yun, Z. Y.; Yang, J.; Dong, X.; Zhou, C. F.; Zhuang, T. T.; Yu, Q.; Liu, H. D.; Zhu, J. H. Microporous Mesoporous Mat. 2007, 103, 352. doi: 10.1016/j.micromeso.2007.01.058
12. [12]
  (12) Zhou, C. F.; Zhu, J. H. Chemosphere 2005, 58 (1), 109. doi: 10.1016/j.chemosphere.2004.08.056
13. [13]
  (13) Liu, A. M.; Hidajat, K.; Kawi, S.; Zhao, D. Y. Chem. Commun. 2000, No. 13, 1145.
14. [14]
  (14) Algarra, M.; Jimenez, M. V.; Jimenez, J.; Jimenez-Lopez, A.; Jimenez-Jimenez, J. Chemosphere 2005, 59 (6), 779. doi: 10.1016/j.chemosphere.2004.11.023
15. [15]
  (15) Benitez, M.; Das, D.; Ferreira, R.; Pischel, U.; Garcia, H. Chem. Mater. 2006, 18 (23), 5597. doi: 10.1021/cm061287n
16. [16]
  (16) Jiang, Y. J.; Gao, Q. M.; Yu, H. G.; Chen, Y. R.; Deng, F. Microporous Mesoporous Mat. 2007, 103, 316. doi: 10.1016/j.micromeso.2007.02.024
17. [17]
  (17) Heidari, A.; Younesi, H.; Mehraban, Z. Chem. Eng. J. 2009, 153 (1-3), 70. doi: 10.1016/j.cej.2009.06.016
18. [18]
  (18) Gargiulo, N.; Peluso, A.; Paolo, A.; Pepe, F.; Caputo, D. J. Chem. Eng. Data 2014, 59 (3), 896. doi: 10.1021/je401075p
19. [19]
  (19) Shi, J. J.; Liu, Y. M.; Chen, J.; Zhang, Y.; Shi, Y. Acta Phys. -Chim. Sin. 2010, 26 (11), 3023. [史晶金, 刘亚敏, 陈杰, 张瑜, 施耀. 物理化学学报, 2010, 26 (11), 3023.] doi: 10.3866/PKU.WHXB20101109
20. [20]
  (20) Zhao, H. M.; Lin, D.; Yang, G.; Chun, Y.; Xu, X. H. Acta Phys. -Chim. Sin. 2012, 28 (4), 985. [赵会民, 林丹, 杨刚, 淳远, 须沁华. 物理化学学报, 2012, 28 (4), 985.] doi: 10.3866/PKU.WHXB201202071
21. [21]
  (21) Hao, N.; Yang, Y. X.;Wang, H. T.;Webley, P. A.; Zhao, D. Y. J. Colloid Interface Sci. 2010, 346 (2), 429. doi: 10.1016/j.jcis.2010.01.074
22. [22]
  (22) Wu, Z. X.; Yang, Y. X.; Tu, B.;Webley, P. A.; Zhao, D. Y. Adsorption 2009, 15 (2), 123. doi: 10.1007/s10450-009-9159-8
23. [23]
  (23) Yuan, J. F.; Li, J. S.; Gu, J.;Wang, F.; Sun, X. Y.; Han,W. Q.; Wang, L. J. Acta Phys. -Chim. Sin. 2010, 26 (6), 1711. [袁金芳, 李健生, 顾娟, 王放, 孙秀云, 韩卫清, 王连军. 物理化学学报, 2010, 26 (6), 1711.] doi: 10.3866/PKU.WHXB20100624
24. [24]
  (24) Ma, Z. F.; Bai, J.;Wang, Y. C.; Jiang, X. ACS Appl. Mater. Interfaces 2014, 6 (4), 2431. doi: 10.1021/am404860q
25. [25]
  (25) Sun, Z. K.; Deng, Y. H.;Wei, J.; Gu, D.; Zhao, D. Y. Chem. Mater. 2011, 23 (8), 2176. doi: 10.1021/cm103704s
26. [26]
  (26) Fan, J.; Yu, C. Z.; Gao, T.; Lei, J.; Tian, B. Z.;Wang, L. M.; Luo, Q.; Tu, B.; Zhou,W. Z.; Zhao, D. Y. Angew. Chem. Int. Edit. 2003, 42 (27), 3146. doi: 10.1002/anie.200351027
27. [27]
  (27) Wang, L. P.; Ren, F. L.;Wu, M. J.; He, Z. H.; Lian,W. L.; Hu, N. N. Chem. Rev. Appl. 2008, 28 (2), 796. [王丽苹, 任凤莲, 吴名剑, 何智慧, 练文柳, 胡念念. 分析实验室, 2008, 28 (2), 796.]
28. [28]
  (28) Xie, S. L.;Wang, K.; Ni, Z. M.; Zhu, R. Z.; Zhu, X.W.; Ren, Z. Y.;Wei,W. Z. Technol. Dev. Chem. Ind. 2009, 38 (11), 15. [谢山岭, 王凯, 倪朝敏, 朱瑞芝, 朱雄伟, 任卓英, 魏万之. 化工技术与开发, 2009, 38 (11), 15.]
1. [1]
  
  (1) Pak, A. M.; Vozdvizhenskii, V. F.; Turganbaeva, S. M.; Levintova, T. D.; Konuspaev, S. R. React. Kinet. Catal. Lett. 1983, 23, 1. doi: 10.1007/BF02065653
2. [2]
  (2) Haubrich, J.; Loffreda, D.; Delbecq, F.; Sautet, P.; Jugnet, Y.; Becker, C.;Wandelt, K. J. Phys. Chem. C 2010, 114 (2), 1073. doi: 10.1021/jp908353p
3. [3]
  (3) Phillips, T. K.; Bhinde, T.; Clark, S. M.; Lee, S. Y. J. Phys. Chem. C 2010, 114 (13), 6027. doi: 10.1021/jp911069t
4. [4]
  (4) Yang, H. S.;Weinstock, B. A.; Hirsche, B. L.; Hirsche, B. L., II; Griffiths, P. R. Langmuir 2005, 21 (9), 3921. doi: 10.1021/la048365a
5. [5]
  (5) Wan, Y.; Zhao, D. Y. Chem. Rev. 2007, 107 (7), 2821. doi: 10.1021/cr068020s
6. [6]
  (6) Zhang, Y. M.; Qiao, Z. A.; Li, Y. T.; Liu, Y. L.; Huo, Q. S. J. Mater. Chem. 2011, 21 (43), 17283. doi: 10.1039/c1jm12259b
7. [7]
  (7) Wu, Z. X.; Zhao, D. Y. Chem. Commun. 2011, 47 (12), 3332. doi: 10.1039/c0cc04909c
8. [8]
  (8) Zhou, C. F.;Wang, Y. M.; Cao, Y.; Zhuang, T. T.; Huang,W.; Chun, Y.; Zhu, J. H. J. Mater. Chem. 2006, 16 (16), 1520. doi: 10.1039/b514317a
9. [9]
  (9) Wei, F.; Gu, F. N.; Zhou, Y.; Gao, L.; Yang, J.; Zhu, J. H. Solid State Sci. 2009, 11 (2), 402. doi: 10.1016/j.solidstatesciences.2008.07.001
10. [10]
  (10) Lin,W. G.;Wei, F.; Gu, F. N.; Dong, X.; Gao, L.; Zhuang, T. T.; Yue, M. B.; Zhu, J. H. J. Colloid Interface Sci. 2010, 348 (2), 621. doi: 10.1016/j.jcis.2010.05.012
11. [11]
  (11) Cao, Y.; Yun, Z. Y.; Yang, J.; Dong, X.; Zhou, C. F.; Zhuang, T. T.; Yu, Q.; Liu, H. D.; Zhu, J. H. Microporous Mesoporous Mat. 2007, 103, 352. doi: 10.1016/j.micromeso.2007.01.058
12. [12]
  (12) Zhou, C. F.; Zhu, J. H. Chemosphere 2005, 58 (1), 109. doi: 10.1016/j.chemosphere.2004.08.056
13. [13]
  (13) Liu, A. M.; Hidajat, K.; Kawi, S.; Zhao, D. Y. Chem. Commun. 2000, No. 13, 1145.
14. [14]
  (14) Algarra, M.; Jimenez, M. V.; Jimenez, J.; Jimenez-Lopez, A.; Jimenez-Jimenez, J. Chemosphere 2005, 59 (6), 779. doi: 10.1016/j.chemosphere.2004.11.023
15. [15]
  (15) Benitez, M.; Das, D.; Ferreira, R.; Pischel, U.; Garcia, H. Chem. Mater. 2006, 18 (23), 5597. doi: 10.1021/cm061287n
16. [16]
  (16) Jiang, Y. J.; Gao, Q. M.; Yu, H. G.; Chen, Y. R.; Deng, F. Microporous Mesoporous Mat. 2007, 103, 316. doi: 10.1016/j.micromeso.2007.02.024
17. [17]
  (17) Heidari, A.; Younesi, H.; Mehraban, Z. Chem. Eng. J. 2009, 153 (1-3), 70. doi: 10.1016/j.cej.2009.06.016
18. [18]
  (18) Gargiulo, N.; Peluso, A.; Paolo, A.; Pepe, F.; Caputo, D. J. Chem. Eng. Data 2014, 59 (3), 896. doi: 10.1021/je401075p
19. [19]
  (19) Shi, J. J.; Liu, Y. M.; Chen, J.; Zhang, Y.; Shi, Y. Acta Phys. -Chim. Sin. 2010, 26 (11), 3023. [史晶金, 刘亚敏, 陈杰, 张瑜, 施耀. 物理化学学报, 2010, 26 (11), 3023.] doi: 10.3866/PKU.WHXB20101109
20. [20]
  (20) Zhao, H. M.; Lin, D.; Yang, G.; Chun, Y.; Xu, X. H. Acta Phys. -Chim. Sin. 2012, 28 (4), 985. [赵会民, 林丹, 杨刚, 淳远, 须沁华. 物理化学学报, 2012, 28 (4), 985.] doi: 10.3866/PKU.WHXB201202071
21. [21]
  (21) Hao, N.; Yang, Y. X.;Wang, H. T.;Webley, P. A.; Zhao, D. Y. J. Colloid Interface Sci. 2010, 346 (2), 429. doi: 10.1016/j.jcis.2010.01.074
22. [22]
  (22) Wu, Z. X.; Yang, Y. X.; Tu, B.;Webley, P. A.; Zhao, D. Y. Adsorption 2009, 15 (2), 123. doi: 10.1007/s10450-009-9159-8
23. [23]
  (23) Yuan, J. F.; Li, J. S.; Gu, J.;Wang, F.; Sun, X. Y.; Han,W. Q.; Wang, L. J. Acta Phys. -Chim. Sin. 2010, 26 (6), 1711. [袁金芳, 李健生, 顾娟, 王放, 孙秀云, 韩卫清, 王连军. 物理化学学报, 2010, 26 (6), 1711.] doi: 10.3866/PKU.WHXB20100624
24. [24]
  (24) Ma, Z. F.; Bai, J.;Wang, Y. C.; Jiang, X. ACS Appl. Mater. Interfaces 2014, 6 (4), 2431. doi: 10.1021/am404860q
25. [25]
  (25) Sun, Z. K.; Deng, Y. H.;Wei, J.; Gu, D.; Zhao, D. Y. Chem. Mater. 2011, 23 (8), 2176. doi: 10.1021/cm103704s
26. [26]
  (26) Fan, J.; Yu, C. Z.; Gao, T.; Lei, J.; Tian, B. Z.;Wang, L. M.; Luo, Q.; Tu, B.; Zhou,W. Z.; Zhao, D. Y. Angew. Chem. Int. Edit. 2003, 42 (27), 3146. doi: 10.1002/anie.200351027
27. [27]
  (27) Wang, L. P.; Ren, F. L.;Wu, M. J.; He, Z. H.; Lian,W. L.; Hu, N. N. Chem. Rev. Appl. 2008, 28 (2), 796. [王丽苹, 任凤莲, 吴名剑, 何智慧, 练文柳, 胡念念. 分析实验室, 2008, 28 (2), 796.]
28. [28]
  (28) Xie, S. L.;Wang, K.; Ni, Z. M.; Zhu, R. Z.; Zhu, X.W.; Ren, Z. Y.;Wei,W. Z. Technol. Dev. Chem. Ind. 2009, 38 (11), 15. [谢山岭, 王凯, 倪朝敏, 朱瑞芝, 朱雄伟, 任卓英, 魏万之. 化工技术与开发, 2009, 38 (11), 15.]
1. [1]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
2. [2]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
5. [5]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
6. [6]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
7. [7]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
8. [8]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
9. [9]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
10. [10]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
11. [11]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
12. [12]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
13. [13]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
14. [14]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
15. [15]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
16. [16]
  Yanyang Li , Zongpei Zhang , Kai Li , Shuangquan Zang . Ideological and Political Design for the Comprehensive Experiment of the Synthesis and Aggregation-Induced Emission (AIE) Performance Study of Salicylaldehyde Schiff-Base. University Chemistry, 2024, 39(2): 105-109. doi: 10.3866/PKU.DXHX202307020
17. [17]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
18. [18]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
19. [19]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
20. [20]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093

Get Citation

PDF

XML

Metrics

PDF Downloads(465)
Abstract views(1162)
HTML views(38)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Adsorption Properties of Ordered Mesoporous Silica for Butyraldehyde

References

Metrics

通讯作者: 陈斌, bchen63@163.com