Citation: HUANG Tian-Hui, ZHAO Yu-Juan, TIAN Zhao-Fu, LI Xiao-Lan, LIU Qian, ZHAO Dong-Yuan. Adsorption Properties of Ordered Mesoporous Silica for Butyraldehyde[J]. Acta Physico-Chimica Sinica, ;2014, 30(12): 2307-2314. doi: 10.3866/PKU.WHXB201410142 shu

Adsorption Properties of Ordered Mesoporous Silica for Butyraldehyde

1.
1. Technology Centre, China Tobacco Guangxi Industrial Incorporation, Nanning 530001, P. R. China;
2. Department of Chemistry, Fudan University, Shanghai 200433, P. R. China

Received Date: 8 July 2014
Available Online: 14 October 2014
Fund Project: 真龙-复旦功能材料化学联合实验室项目(20120208Y)资助 (20120208Y)

Ordered mesoporous silica materials SBA-15, MCM-41, SBA-16, KIT-6 with different pore sizes and properties were prepared. Several SBA-15 materials were synthesized with different pore diameters by changing the hydrothermal temperature. The materials produced were characterized using small-angle X-ray scattering (SAXS), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and nitrogen adsorption/desorption. The adsorption isotherms of organic aldehyde were measured, using butyraldehyde as a model molecule. The results were compared with those for the adsorption capacity of Y-zeolite; they showed that the specific surface area originating from the mesopores was proportional to the amount of butyraldehyde adsorption. The adsorption isotherms agreed with Langmuir mode for monolayer adsorption. Mesoporous silica MCM-41 with the highest mesopore specific surface area showed the highest adsorbed amount of butyraldehyde (484 mg·g^-1). The SBA-15 sample was selected for the fabrication of cigarette filters, and the results showed that SBA-15 significantly reduced the amount of Croton aldehyde released in cigarette smoke.
- Mesoporous silica,
- Synthesis,
- Adsorption,
- Butyraldehyde,
- Croton aldehyde,
- Cigarette smoke
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