Citation: WANG Jia-Sheng, HAN Shu-Min, LI Yuan, SHEN Na, ZHANG Wei. Hydriding/Dehydriding Properties of an MgH₂+20%(w) MgTiO₃ Composite[J]. Acta Physico-Chimica Sinica, ;2014, 30(12): 2323-2327. doi: 10.3866/PKU.WHXB201410081 shu

Hydriding/Dehydriding Properties of an MgH₂+20%(w) MgTiO₃ Composite

WANG Jia-Sheng ¹ ,
HAN Shu-Min ^1,2, ,
LI Yuan ¹ ,
SHEN Na ¹ ,
ZHANG Wei ¹

1.
1. Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004, Hebei Province, P. R. China;
2. State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, Hebei Province, P. R. China

Received Date: 14 July 2014
Available Online: 9 October 2014
Fund Project: 国家自然科学基金(50971112, 51001043) (50971112, 51001043)河北省高等学校科学技术研究重点项目(ZD2014004)资助 (ZD2014004)

With the aim of decreasing the dehydriding temperature and improving the hydriding/dehydriding kinetic properties of MgH₂, we prepared MgH₂+20%(w) MgTiO₃ composite via ball-milling, and investigated the hydrogen storage properties of the composite. X- ray diffraction (XRD) results showed that the MgTiO₃ decomposed into Mg₂TiO₄ and TiO₂ during the ball-milling. These two resulting compounds remained stable during the hydriding/dehydriding processes, working as catalysts for the hydriding/dehydriding. Temperatureprogrammed- desorption (TPD) and hydriding/dehydriding kinetics tests showed that doping MgH₂ with MgTiO₃ lowered the onset dehydrogenation temperature of MgH₂ from 389 to 249 ℃, as well as increasing the hydrogen absorption amount from 0.977%(w) to 2.902%(w) at 150 ℃, and increasing the desorption amount from 2.319% (w) to 3.653%(w) at 350 ℃. The MgTiO₃ additive decreased the dehydriding activation energy of MgH₂ from 116 to 95.7 kJ·mol^-1. The thermodynamic and kinetic performance of the MgH₂+20%(w) MgTiO₃ composite was significantly improved compared with pristine MgH₂, which was attributed to the high catalytic activity of the (insitu formed) TiO₂ and Mg₂TiO₄ during the ball-milling and dehydriding processes.
- Hydrogen storage property,
- MgH₂,
- MgTiO₃,
- Catalytic activity,
- Activation energy
1. [1]
  
  (1) Lan, Z. Q.; Xiao, X.; Su, X.; Chen, J. S.; Guo, J. Acta Phys. -Chim. Sin. 2012, 28 (8), 1877. [蓝志强, 肖潇, 苏鑫, 陈捷狮, 郭进. 物理化学学报, 2012, 28 (8), 1877.] doi: 10.3866/PKU.WHXB201205281
2. [2]
  (2) Wang, H.; Zhang, J.; Liu, J.W.; Ouyang, L. Z.; Zhu, M. Int. J. Hydrog. Energy 2013, 38 (25), 10932. doi: 10.1016/j.ijhydene.2013.02.075
3. [3]
  (3) Floriano, R.; Leiva, D. R.; Deledda, S.; Hauback, B. C.; Botta, W. J. Int. J. Hydrog. Energy 2014, 39 (9), 4404.
4. [4]
  (4) Shimada, M.; Higuchi, E.; Inoue, H. J. Alloy. Compd. 2013, 580, S153.
5. [5]
  (5) Kurko, S.; Milanovi?, I.; Novakovi?, J. G.; Ivanovi?, N.; Novakovi?, N. Int. J. Hydrog. Energy 2014, 39 (2), 862.
6. [6]
  (6) Song,W. J.; Li, J. S.; Zhang, T. B.; Hou, X. J.; Kou, H. C.; Xue, X.; Hu, R. Trans. Nonferrous Met. Soc. China 2013, 23 (12),3677. doi: 10.1016/S1003-6326(13)62916-7
7. [7]
  (7) Mamula, B. P.; Novakovi?, J. G.; Radisavljevi?, I.; Ivanovi?, N.; Novakovi?, N. Int. J. Hydrog. Energy 2014, 39 (11), 5874. doi: 10.1016/j.ijhydene.2014.01.172
8. [8]
  (8) Du, X. M.; Li,W. H.; Huang, Y.;Wu, E. D. Acta Phys. -Chim. Sin. 2011, 27 (12), 2793. [杜晓明, 李武会, 黄勇, 吴尔冬. 物理化学学报, 2011, 27 (12), 2793.] doi: 10.3866/PKU.WHXB20112793
9. [9]
  (9) Jongh, P. E.;Wagemans, R.W.; Eggenhuisen, T. M.; Dauvillier, B. S.; Radstake, P. B.; Meeldijk, J. D.; Geus, J.W.; Jong, K. P.Chem. Mater. 2007, 19, 6052. doi: 10.1021/cm702205v
10. [10]
  (10) Li, J. H.; Liu, B. Z.; Han, S. M.; Hu, L.; Zhu, X. L.;Wang, M. Z. Acta Phys. -Chim. Sin. 2011, 27 (2), 403. [李金华, 刘宝忠, 韩树民, 扈琳, 朱惜林, 王明智. 物理化学学报, 2011, 27 (2), 403.] doi: 10.3866/PKU.WHXB20110206
11. [11]
  (11) Kwon, S. N.; Baek, S. H.; Mumm, D. R.; Hong, S. H.; Song, M. Y.; Youp, S. M. Int. J. Hydrog. Energy 2013, 33 (17), 4586.
12. [12]
  (12) Fan, Y. P.; Peng, X. Y.; Liu, B. Z.; Su, T. C.; Bala, H. J. Rare Earths 2014, 32 (5), 434. doi: 10.1016/S1002-0721(14)60090-9
13. [13]
  (13) Song, M. Y.; Kwak, Y. J.; Lee, S. H.; Park, H. R.; Kim, B. G. Met. Mater. Int. 2013, 19, 879. doi: 10.1007/s12540-013-4033-3
14. [14]
  (14) Floriano, R.; Leiva, D. R.; Deledda, S.; Hauback, B. C.; Botta, W. J. Int. J. Hydrog. Energy 2013, 38 (36), 16193.
15. [15]
  (15) Liu, G.; Qiu, F.; Li, J.;Wang, Y.; Li, L.; Yan, C.; Jiao, L.; Yuan, H. Int. J. Hydrog. Energy 2012, 37 (22), 17111. doi: 10.1016/j.ijhydene.2012.07.106
16. [16]
  (16) Lototskyy, M.; Sibanyoni, J. M.; Denys, R. V.;Williams, M.; Pollet, B. G.; Yartys, V. A. Carbon 2013, 57, 146. doi: 10.1016/j.carbon.2013.01.058
17. [17]
  (17) Miloševi?, S.; Milanovi?, I.; Mamula, B. P.; ?uki?, A.; Rajnovi?, D.; Pasquini, L.; Novakovi?, J. G. Int. J. Hydrog. Energy 2013, 38 (27), 12223. doi: 10.1016/j.ijhydene. 2013.06.083
18. [18]
  (18) Sabitu, S. T.; udy, A. J. Int. J. Hydrog. Energy 2012, 37 (17), 12301. doi: 10.1016/j.ijhydene.2012.06.039
19. [19]
  (19) Shahi, R. R.; Bhatnagar, A.; Pandey, S. K.; Dixit, V.; Srivastava, O. N. Int. J. Hydrog. Energy 2014, 39 (26), 14255. doi: 10.1016/j.ijhydene.2014.03.183
20. [20]
  (20) Ren, C.; Fang, Z. Z.; Zhou, C.; Lu, J.; Ren, Y.; Zhang, X.; Luo, X. Int. J. Hydrog. Energy 2014, 39 (11), 5868. doi: 10.1016/j.ijhydene.2014.01.152
21. [21]
  (21) Croston, D. L.; Grant, D. M.;Walker, G. S. J. Alloy. Compd. 2010, 492, 251. doi: 10.1016/j.jallcom.2009.10.199
22. [22]
  (22) Bariccoa, M.; Rahmana, M.W.; Livraghia, S.; Castelleroa, A.; Enzob, S.; Giamello, E. J. Alloy. Compd. 2012, 536, S216.
23. [23]
  (23) Wang, H.; Zhang, J.; Liu, J.W.; Ouyang, L. Z.; Zhu, M. J. Alloy. Compd. 2013, 580, S197.
24. [24]
  (24) Pitt, M. P.; Paskevicius, M.;Webb, C. J.; Sheppard, D. A.; Buckley, C. E.; Gray, E. M. Int. J. Hydrog. Energy 2012, 37 (5), 4227. doi: 10.1016/j.ijhydene.2011.11.114
25. [25]
  (25) Lin, H. J.; Ouyang, L. Z.;Wang, H.; Zhao, D. Q.;Wang,W. H.; Sun, D. L.; Zhu, M. Int. J. Hydrog. Energy 2012, 37 (19), 14329. doi: 10.1016/j.ijhydene.2012.07.073
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Hydriding/Dehydriding Properties of an MgH2+20%(w) MgTiO3 Composite

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Hydriding/Dehydriding Properties of an MgH₂+20%(w) MgTiO₃ Composite