Citation: CHEN Chan-Juan, HU Zhong-Ai, HU Ying-Ying, LI Li, YANG Yu-Ying, AN Ning, LI Zhi-Min, WU Hong-Ying. SnO₂/Graphite Nanosheet Composite Electrodes and Their Application in Supercapacitors[J]. Acta Physico-Chimica Sinica, ;2014, 30(12): 2256-2262. doi: 10.3866/PKU.WHXB201409302 shu

SnO₂/Graphite Nanosheet Composite Electrodes and Their Application in Supercapacitors

1.
Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, P. R. China

Received Date: 9 June 2014
Available Online: 30 September 2014
Fund Project: 国家自然科学基金(20963009, 21163017) (20963009, 21163017)高等学校博士学科点专项科研基金(20126203110001)资助项目 (20126203110001)

Electrochemical exfoliation of graphite rods under the action of an electric field force led to the formation of two-dimensional (2D) graphite nanosheet arrays (GNSAs) perpendicular to the surface of the graphite substrate and parallel to each other in arrangement. Subsequently, SnO₂/graphite nanosheet array (SnO₂/GNSA) composite electrodes were prepared by the cathodic reduction electrodeposition method. The morphology, composition, and microstructure of the samples were characterized using field emission scanning electron microscopy (FESEM), powder X-ray diffraction (XRD), and Fourier transform infrared (FT-IR) spectroscopy, respectively. Electrochemical measurements showed that the composite electrodes achieved specific capacitance values as high as 4105 F·m^-2 in the potential window up to 1.4 V with a scan rate of 5 mV·s^-1 in 0.5 mol·L^-1 LiNO₃ solution. Asymmetric supercapacitor fabricated with the as-prepared SnO₂/GNSAs exhibited excellent capacitive performance with energy density of 0.41 Wh·m^-2 in the potential window up to 1.8 V and retention of 81% after 5000 cycles.
- Supercapacitor,
- Graphite nanosheet array,
- SnO₂,
- Composite electrode,
- Electrochemical performance
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沈阳化工大学材料科学与工程学院沈阳 110142

SnO2/Graphite Nanosheet Composite Electrodes and Their Application in Supercapacitors

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通讯作者: 陈斌, bchen63@163.com

SnO₂/Graphite Nanosheet Composite Electrodes and Their Application in Supercapacitors