Citation: LI Jing-Jing, LI Yuan, WANG Ai-Ling, QU Yan-Rong, YUE Bin, ZHOU Dan, CHU Hai-Bin, ZHAO Yong-Liang. Surface Plasmon Resonance Enhanced Luminescence of Europium Complexes with Ag@SiO₂ Core-Shell Structure[J]. Acta Physico-Chimica Sinica, ;2014, 30(12): 2328-2334. doi: 10.3866/PKU.WHXB201409292 shu

Surface Plasmon Resonance Enhanced Luminescence of Europium Complexes with Ag@SiO₂ Core-Shell Structure

1.
College of Chemistry and Chemical Engineering, Inner Mon lia University, Hohhot 010021, P. R. China

Received Date: 31 July 2014
Available Online: 29 September 2014
Fund Project: 国家自然科学基金(21161013) (21161013) 内蒙古自然科学基金(2011MS0202) (2011MS0202)内蒙古重大基础研究开放基金(2010KF03)资助 (2010KF03)

Three types of Ag@SiO₂ nanoparticles with silica shell thicknesses of around 10, 25, and 80 nm were prepared. Europium complexes with benzoate (BA) in different proportions, 1, 10-phenanthroline (phen) and 2, 2'-bipyridine (bpy), were synthesized and characterized. The results suggest that the complexes have the formulas Eu(BA)_nCl_3-n ·2H₂O (n=1, 2, 3), Eu(phen)Cl₃ ·2H₂O, and Eu(bpy)Cl₃ ·2H₂O. The luminescence spectra of the complexes showed that adding Ag@SiO₂ nanoparticles increased the fluorescence intensity. The fluorescence enhancement sequence of the different silica shell thickness Ag@SiO₂ nanoparticles was 25 nm> 80 nm>10 nm, which showed that the local surface plasmon resonance was strongest at the silica shell thickness of about 25 nm. Furthermore, the enhancement effect for the Eu(phen)Cl₃·2H₂O complex was the strongest and that for the benzoic complex Eu(BA)_nCl_3-n·2H₂O was the weakest in these complexes. For the three benzoic complexes, the enhancement effect of Eu(BA)₃·2H₂O was the lowest. The nitrogenous complexes (Eu(phen)Cl₃ and Eu(bpy)Cl₃) could combine withAg@SiO₂ nanoparticles very well, while the interaction of Eu(BA)₃· 2H₂O with Ag@SiO₂ nanoparticles was weaker. Ag@SiO₂ nanoparticles are expected to enhance luminescence of rare earth materials.
- Europium complex,
- Plasmon resonance,
- Ag@SiO₂ nanoparticle,
- Luminescence intensity,
- Core-shell structure
1. [1]
  
  (1) Moskovits, M. Rev. Mod. Phys. 1985, 57 (3), 783. doi: 10.1103/RevModPhys.57.783
2. [2]
  (2) Xiao, Q. L.; Meng, J. X.; Xie, L. J.; Zhang, R. Acta Phys. -Chim. Sin. 2011, 27, 2427. [肖全兰, 孟建新, 谢丽娟, 张蕤. 物理化学学报, 2011, 27, 2427.] doi: 10.3866/PKU.WHXB20110928
3. [3]
  (3) Worlinsky, J. L.; Basu, S. J. Phys. Chem. B 2009, 113, 865. doi: 10.1021/jp8100464
4. [4]
  (4) Geddes, C. D.; Cao, H.; Gryczynski, I.; Gryczynsk, Z.; Fang, J. Y.; Lakowicz, J. R. J. Phys. Chem. A 2003, 107, 3443. doi: 10.1021/jp022040q
5. [5]
  (5) Cui, J. H.; Hu, C. F.; Yang, Y. H.;Wu, Y. J.; Yang, L. F.;Wang, Y. L.; Liu, Y. L.; Jiang, Z. Y. J. Mater. Chem. 2012, 22, 8121. doi: 10.1039/c2jm16441h
6. [6]
  (6) Kong, H.; Jiang, J. Langmuir 2008, 24, 2051. doi: 10.1021/la703085e
7. [7]
  (7) Liu, Y. L.; Song, F.; Liu, J. D.; Zhang, J.; Yu, Y.; Zhao, H. Y. Chem. Phys. Lett. 2013, 565, 98. doi: 10.1016/j.cplett.2013.02.050
8. [8]
  (8) Wang, Y. H.;Wang, T.; Zhou, J. Acta Phys. -Chim. Sin. 2014, 30 (1), 28. [王悦辉, 王婷, 周济. 物理化学学报, 2014, 30 (1), 28.] doi: 10.3866/PKU.WHXB201311011
9. [9]
  (9) Darugar, Q.; Qian,W.; El-Sayed, M. A. J. Phys. Chem. B 2006, 110, 143. doi: 10.1021/jp0545445
10. [10]
  (10) Ding, Y. L.; Zhang, X. D.; Gao, H. B. J. Lumin. 2014, 147, 72. doi: 10.1016/j.jlumin.2013.10.062
11. [11]
  (11) Shera, E. B.; Seitzinger, N. K.; Davis, L. M.; Keller, R. A.; Soper, S. A. Chem. Phys. Lett. 1990, 174, 553. doi: 10.1016/0009-2614(90)85485-U
12. [12]
  (12) Sudheendra, L.; Ortalan, V.; Dey, S.; Browning, N. D.; Kennedy, I. M. Chem. Mater. 2011, 23 (11), 2987. doi: 10.1021/cm2006814
13. [13]
  (13) Wei, H. Y.; Cleary, Z.; Park, S.; Senevirathne, K.; Eilers, H. J. Alloy. Compd. 2010, 500 (1), 96. doi: 10.1016/j.jallcom.2010.03.220
14. [14]
  (14) Liu, F.; Aldea, G.; Nunzi, J. M. J. Lumin. 2010, 130 (1),56. doi: 10.1016/j.jlumin.2009.07.017
15. [15]
  (15) Lakowicz, J. R. Anal. Biochem. 2004, 324, 153. doi: 10.1016/j. ab.2003.09.039
16. [16]
  (16) Liebermann, T.; Knoll,W. Colloids Surf. A 2000, 171, 115. doi: 10.1016/S0927-7757(99)00550-6
17. [17]
  (17) Weiss, S. Science 1999, 283, 1676. doi: 10.1126/science. 283.5408.1676
18. [18]
  (18) Tsuji, A.; Koshimoto, H.; Sato, Y.; Hirano, M.; Sei-lida, Y.; Kondo, S.; Ishibashi, K. Biophys. J. 2000, 78, 3260. doi: 10.1016/S0006-3495(00)76862-7
19. [19]
  (19) Knoll,W.; Yu, F.; Neumann, T.; Schiller, S.; Naumann, R. Phys. Chem. Chem. Phys. 2003, 5, 5169. doi: 10.1039/b310317j
20. [20]
  (20) Schietinger, S.; Aichele, T.;Wang, H. Q.; Nann, T.; Benson, O. Nano Lett. 2010, 10 (1), 134. doi: 10.1021/nl903046r
21. [21]
  (21) D′A stino, S.; Pompa, P. P.; Chiuri, R.; Phaneuf, R. J.; Britti, D. G.; Rinaldi, R.; Cin lani, R.; Della, S. F. Optics Letters 2009, 34, 2381. doi: 10.1364/OL.34.002381
22. [22]
  (22) Aslan, K.;Wu, M.; Lakowicz, J. R.; Geddes, C. D. J. Am. Chem. Soc. 2007, 129, 1524. doi: 10.1021/ja0680820
23. [23]
  (23) Kamruzzaman, M.; Alam, A.; Lee, S. H.; Suh, Y. S.; Kim, Y. H.; Kim, G. M.; Kim, S. H. Acta Metall. 2011, 174, 353. doi: 10.1007/s00604-011-0633-0
24. [24]
  (24) Chowdhury, M. H.; Pong, J.; Gray, S. K.; Lakowicz, J. R. J. Phys. Chem. C 2008, 112, 11236. doi: 10.1021/jp802414k
25. [25]
  (25) Malicka, J.; Gryczynski, I.; Kusba, J.; Lakowicz, J. R. Biopolymers 2003, 70, 595. doi: 10.1002/bip.10507
26. [26]
  (26) Ventura, M. G.; Parola, A. J.; Matos, A. P. J. Non-Cryst. Solids 2011, 357, 1342. doi: 10.1016/j.jnoncrysol.2010.12.013
27. [27]
  (27) Kobayashi, Y.; Katakami, H.; Mine, E.; Nagao, D.; Konno, M.; Liz-Marzan, L. M. J. Coll. Inter. Sci. 2005, 283 (2), 392. doi: 10.1016/j.jcis.2004.08.184
28. [28]
  (28) Guo, L.; Guan, A.; Lin, X.; Zhang, C.; Chen, G. Talanta 2010, 82, 1696. doi: 10.1016/j.talanta.2010.07.051
29. [29]
  (29) Ni,W.; Zhang, Z.; Chen, H.; Li, L.;Wang, J. J. Am. Chem. Soc. 2008, 130, 6692. doi: 10.1021/ja8012374
30. [30]
  (30) Yang, Z.; Ni,W.; Kou, X.; Zhang, S.; Sun, Z.; Sun, L.;Wang, J.; Yan, C. J. Phys. Chem. C 2008, 112, 18895. doi: 10.1021/jp8069699
31. [31]
  (31) Pillai, S. S.; Kamat, P. V. J. Phys. Chem. B 2004, 108, 945. doi: 10.1021/jp037018r
32. [32]
  (32) Sun, H. J.; Fu, X. T.; Chu, H. B.; Du, Y.; Lin, X. M.; Li, X.; Zhao, Y. L. J. Photochem. Photobiol. A 2011, 219, 243. doi: 10.1016/j.jphotochem.2011.02.026
33. [33]
  (33) Yan, B.; Zhang, H. J.;Wang, S. B.; Ni, J. Z. J. Photochem. Photobiol. A 1998, 116, 209. doi: 10.1016/S1010-6030(98)00307-4
34. [34]
  (34) Grosby, G. A.; Whan, R. E.; Alire, R. M. J. Chem. Phys. 1961, 34, 743. doi: 10.1063/1.1731670
35. [35]
  (35) Steemers, F. J.; Verboom,W.; Reinhoudt, D. N.; Vandertol, E. B.; Verhoeven, J.W. J. Am. Chem. Soc. 1995, 117, 9408. doi: 10.1021/ja00142a004
36. [36]
  (36) Latva, M.; Takalo, H.; Mukkala, V. M.; Matachescu, C.; RodriguezUbis, J. C.; Kankare, J. J. Lumin. 1997, 75, 149. doi: 10.1016/S0022-2313(97)00113-0
37. [37]
  (37) Geddes, C. D.; Lakowicz, J. R. J. Fluoresc. 2002, 12, 121. doi: 10.1023/A:1016875709579
38. [38]
  (38) Wu, M.; Lakowicz, J. R.; Geddes, C. D. J. Fluoresc. 2005, 15, 53. doi: 10.1007/s10895-005-0213-y
39. [39]
  (39) Qu, Y. R.; Lin, X. M.;Wang, A. L.;Wang, Z. X.; Kang, J.; Chu, H. B.; Zhao, Y. L. J. Lumin. 2014, 154, 402. doi: 10.1016/j.jlumin.2014.05.013
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沈阳化工大学材料科学与工程学院沈阳 110142

Surface Plasmon Resonance Enhanced Luminescence of Europium Complexes with Ag@SiO2 Core-Shell Structure

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通讯作者: 陈斌, bchen63@163.com

Surface Plasmon Resonance Enhanced Luminescence of Europium Complexes with Ag@SiO₂ Core-Shell Structure