Citation:
SUN Xian-Zhong, HUANG Bo, ZHANG Xiong, ZHANG Da-Cheng, ZHANG Hai-Tao, MA Yan-Wei. Experimental Investigation of Electrochemical Impedance Spectroscopy of Electrical Double Layer Capacitor[J]. Acta Physico-Chimica Sinica,
;2014, 30(11): 2071-2076.
doi:
10.3866/PKU.WHXB201408292
-
Electrochemical impedance spectroscopy (EIS) is a very useful technique for studying electrochemical behavior. The ideal Nyquist plot of electrochemical impedance spectroscopy for an electrical double-layer capacitor (EDLC) consists of a 45° line in the high-middle frequency region and a vertical line in the low frequency region, which can be explained by the transmission line model with pore size distribution. However, a semicircle loop in the high frequency region has been found in many studies. Hence, in this study, an equivalent model is proposed, in which the semicircle loop is ascribed to the contact resistance and contact capacitance between particles of activate materials, and between the activated carbon (AC) electrode and current collector. The effects of the charging process, conductivities of the active material and electrolyte, content of conductive additive and binder, porous separator, mass loading, and exerted pressure to the electrode on the EIS spectra of EDLCs were experimentally investigated. Among these effects, the most significant factors were the charging cut-off voltage, conductivity of activated carbon, content of conductive additive, and exerted pressure.
-
-
-
[1]
(1) Musiani, M.; Orazem, M.; Tribollet, B.; Vivier, V. Electrochim. Acta 2011, 56, 8014. doi: 10.1016/j.electacta.2010.12.004
-
[2]
(2) Taberna, P.; Simon, P.; Fauvarque, J. F. J. Electrochem. Soc. 2003, 150, A292.
-
[3]
(3) Aurbach, D.; Markovsky, B.;Weissman, I.; Levi, E.; Ein-Eli, Y. Electrochim. Acta 1999, 45, 67. doi: 10.1016/S0013-4686(99)00194-2
-
[4]
(4) de Levie, R. Electrochim. Acta 1963, 8, 751. doi: 10.1016/0013-4686(63)80042-0
-
[5]
(5) Song, H. K.; Jung, Y. H.; Lee, K. H.; Dao, L. H. Electrochim. Acta 1999, 44, 3513. doi: 10.1016/S0013-4686(99)00121-8
-
[6]
(6) Song, H. K.; Sung, J. H.; Jung, Y. H.; Lee, K. H.; Dao, L. H.; Kim, M. H.; Kim, H. N. J. Electrochem. Soc. 2004, 151, E102.
-
[7]
(7) Sun, X. Z.; Zhang, X.; Zhang, H. T.; Zhang, D. C.; Ma, Y.W. J. Solid State Electrochem. 2012, 16, 2597. doi: 10.1007/s10008-012-1678-7
-
[8]
(8) Sun, X. Z.; Zhang, X.; Zhang, H. T.; Huang, B.; Ma, Y.W. J. Solid State Electrochem. 2013, 17, 2035. doi: 10.1007/s10008-013-2051-1
-
[9]
(9) Sun, X. Z.; Zhang, X.; Huang, B.; Ma, Y.W. Acta Phys. -Chim. Sin. 2014, 30, 485. [孙现众, 张熊, 黄博, 马衍伟. 物理化学学报, 2014, 30, 485.] doi: 10.3866/PKU.WHXB201401131
-
[10]
(10) Lewandowski, A.; Olejniczak, A.; Galinski, M.; Stepniak, I. J. Power Sources 2010, 195, 5814. doi: 10.1016/j.jpowsour.2010.03.082
-
[11]
(11) Qu, Q. T.;Wang, B.; Yang, L. C.; Shi, Y.; Tian, S.;Wu, Y. P. Electrochem. Commun. 2008, 10, 1652. doi: 10.1016/j.elecom.2008.08.020
-
[12]
(12) Ruch, P.W.; Cericola, D.; Foelske-Schmitz, A.; Kötz, R.; Wokaun, A. Electrochim. Acta 2010, 55, 4412. doi: 10.1016/j.electacta.2010.02.064
-
[13]
(13) Kossyrev, P. J. Power Sources 2012, 201, 347. doi: 10.1016/j.jpowsour.2011.10.106
-
[14]
(14) Dsoke, S.; Tian, X.; Taubert, C.; Schluter, S.;Wohlfahrt-Mehrens, M. J. Power Sources 2013, 238, 422. doi: 10.1016/j.jpowsour.2013.04.031
-
[15]
(15) Zhong, H. X.; Zhao, C. B.; Luo, H.; Zhang, L. Z. Acta Phys. -Chim. Sin. 2012, 28, 2641. [仲皓想, 赵春宝, 骆浩, 张灵志. 物理化学学报, 2012, 28, 2641.] doi: 10.3866/PKU.WHXB201207181
-
[16]
(16) Zuo, X. X.; Li, Q.; Liu, J. S.; Xiao, X.; Fan, C. J.; Nan, J. M. Acta Chim. Sin. 2012, 70, 367. [左晓希, 李奇, 刘建生, 肖信, 范成杰, 南俊民. 化学学报, 2012, 70, 367.]
-
[17]
(17) Conway, B. E. Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications; Kluwer Academic/Plenum Publishers: New York, 1999.
-
[18]
(18) Nian, Y. R.; Teng, H. J. Electroanal. Chem. 2003, 540, 119. doi: 10.1016/S0022-0728(02)01299-8
-
[19]
(19) Huang, C.W.; Hsu, C. H.; Kuo, P. L.; Hsieh, C. T.; Teng, H. Carbon 2011, 49, 895. doi: 10.1016/j.carbon.2010.10.053
-
[20]
(20) Huang, C.W.; Chuang, C. M.; Ting, J. M.; Teng, H. J. Power Sources 2008, 183, 406. doi: 10.1016/j.jpowsour.2008.04.075
-
[21]
(21) Takeuchi, M.; Koike, K.; Mogami, A.; Maruyama, T. Electric Double-layer Capacitor and Carbon Material Therefor. US Patent Application. 20020039275A1, 2002-04-04.
-
[22]
(22) Cericola, D.; Ruch, P.W.; Foelske-Schmitz, A.;Weingarth, D.; Kötz, R. Int. J. Electrochem. Sci. 2011, 6, 988.
-
[23]
(23) Azaïs, P.; Duclaux, L.; Florian, P.; Massiot, D.; Lillo-Rodenas, M. A.; Linares-Solano, A.; Peres, J. P.; Jehoulet, C.; Béguin, F. J. Power Sources 2007, 171, 1046. doi: 10.1016/j.jpowsour.2007.07.001
-
[24]
(24) Ruch, P.W.; Cericola, D.; Foelske, A.; Kötz, R.;Wokaun, A. Electrochim. Acta 2010, 55, 2352. doi: 10.1016/j.electacta.2009.11.098
-
[25]
(25) Chen, Y.; Zhang, X.; Yu, P.; Ma, Y.W. Chem. Commun. 2009, 4527.
-
[26]
(26) Xu, B.; Yue, S. F.; Sui, Z. Y.; Zhang, X. T.; Hou, S. S.; Cao, G. P.; Yang, Y. S. Energ. Environ. Sci. 2011, 4, 2826. doi: 10.1039/c1ee01198g
-
[27]
(27) Kötz, R.; Ruch, P.W.; Cericola, D. J. Power Sources 2010, 195, 923. doi: 10.1016/j.jpowsour.2009.08.045
-
[28]
(28) Bittner, A. M.; Zhu, M.; Yang, Y.;Waibel, H. F.; Konuma, M.; Starke, U.;Weber, C. J. J. Power Sources 2012, 203, 262. doi: 10.1016/j.jpowsour.2011.10.083
-
[29]
(29) Portet, C.; Taberna, P.; Simon, P.; Laberty-Robert, C. Electrochim. Acta 2004, 49, 905. doi: 10.1016/j.electacta.2003.09.043
-
[30]
(30) Huang, X. J. Power Sources 2014, 256, 96. doi: 10.1016/j.jpowsour.2014.01.080
-
[31]
(31) Sheeja, D.; Tay, B.; Leong, K.; Lee, C. Diam. Relat. Mater. 2002, 11, 1643. doi: 10.1016/S0925-9635(02)00109-7
-
[1]
-
-
-
[1]
Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
-
[2]
Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe2O4@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
-
[3]
Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
-
[4]
Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
-
[5]
Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)2. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
-
[6]
Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
-
[7]
Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
-
[8]
Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 100014-. doi: 10.3866/PKU.WHXB202309047
-
[9]
Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa0.5Sr0.5Fe1.6Ni0.4O5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
-
[10]
Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
-
[11]
Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yusuke Yamauchi , Saad Melhi , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006
-
[12]
Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO3)3 double-coating modification on the electrochemical properties of Li[Ni0.8Co0.15Al0.05]O2. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
-
[13]
Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
-
[14]
Shuhui Li , Xucen Wang , Yingming Pan . Exploring the Role of Electrochemical Technologies in Everyday Life. University Chemistry, 2025, 40(3): 302-307. doi: 10.12461/PKU.DXHX202406059
-
[15]
Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, 2025, 40(3): 318-327. doi: 10.12461/PKU.DXHX202406089
-
[16]
Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
-
[17]
Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
-
[18]
Cen Zhou , Biqiong Hong , Yiting Chen . Application of Electrochemical Techniques in Supramolecular Chemistry. University Chemistry, 2025, 40(3): 308-317. doi: 10.12461/PKU.DXHX202406086
-
[19]
Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
-
[20]
Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
-
[1]
Metrics
- PDF Downloads(650)
- Abstract views(854)
- HTML views(34)