Citation: ZHANG Lan, WEI Ji-Ying, ZHAO Xuan, LI Fu-Zhi, JIANG Feng. Preparation, Characterization and Sr(Ⅱ) Adsorption Performance of Self-Doped Antimony Oxide[J]. Acta Physico-Chimica Sinica, ;2014, 30(10): 1923-1931. doi: 10.3866/PKU.WHXB201408201 shu

Preparation, Characterization and Sr(Ⅱ) Adsorption Performance of Self-Doped Antimony Oxide

1.
Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, P. R. China

Received Date: 26 May 2014
Available Online: 20 August 2014
Fund Project:

⁹⁰Sr is an important radionuclide that needs to be removed from radioactive waste water (RWW) in nuclear power plants (NPP) prior to its discharge into the environment. Hydrous antimony oxide is a type of selective adsorbent for Sr(Ⅱ) ions, especially in acid solution. In this paper, a series of self-doped hydrous antimony oxides Sb(Ⅲ)/Sb₂O₅ were prepared by a two-step process in an absolute alcohol solvent, using antimony trichloride as a stable and low-toxic antimony source and H₂O2 solution as an oxidant. UV radiation was used to enhance the oxidation rate of Sb(Ⅲ). The as-prepared samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared (FTIR) spectroscopy analyses, and the effect of the preparation conditions on the composition and structure of the products are discussed. Batch adsorption experiments were performed to study the relationship between the Sb(Ⅲ)/Sb(total) ratio in the oxide adsorbent and the Sr(Ⅱ) adsorption activity. Moreover, the influence of the initial pH of the waste water was investigated. The results showed that Sb(Ⅲ) ions can coexist with Sb(V) and form the solid solution of Sb(Ⅲ)/Sb₂O₅ with cubic pyrochlore structure. Materials with different Sb(Ⅲ)/Sb(total) ratios can be obtained by choosing different alcohols as the solvent and a suitable mixing method of the reactants, as well as by changing the reaction temperature during the oxidation process. Among the as- prepared Sb(Ⅲ)/Sb₂O₅ adsorbents, the sample with a Sb(Ⅲ)/Sb(total) ratio of 49.8% showed the best Sr(Ⅱ) adsorption performance, and the distribution coefficients of Sr(Ⅱ) was about 6.6×107 mL·g^-1. This hydrous antimony oxide showed favorable performance in the wide pH value of pH=3-13. In addition, Sr(Ⅱ) adsorption on the as-prepared material fitted the Langmuir model very well under the conditions studied.
- Middle and low radioactive water,
- Adsorption of strontium ion,
- Inorganic ion-exchange adsorbent,
- Hydrous antimony oxide
References
1. [1]
  
  (1) Lehto, J.; Harjula, R. Radiochim. Acta 1999, 86 (1-2), 65. (2) Vesterbacka, P.; Hamalainen, K. Radiochim. Acta 2005, 93 (5), 291. (3) Kuronen, M.; Harjula, R. Radiochim. Acta 2005, 93 (2), 119. (4) Koivula, R.; Harjula, R. Sep. Sci. Technol. 2003, 38 (15), 3795. doi: 10.1081/SS-120024231
2. [2]
  (5) Harjula, R.; Lehtoa, J.; Paajanena, A.; Tusab, E.; Yarnell, P. React. Funct. Polym. 2004, 60, 85. doi: 10.1016/j.reactfunctpolym.2004.02.014
3. [3]
  (6) Möller, T.; Harjula, R.; Lehto, J. Sep. Sci. Technol. 2002, 28 (1), 13. (7) Liu, H. D.; Li, F. Z.; Zhao, X.; Yun, G. C. Nucl. Technol. 2009, 165, 200. (8) Tel, H.; Alta, Y.; Eral, M.; Sert, E.; Etinkaya, B.; Nan, S. Chem. Eng. J. 2010, 161 (1-2), 151. (9) Gürbo?a, G.; Tel, H. J. Hazard. Mater. 2005, 120 (1-3), 135. doi: 10.1016/j.jhazmat.2004.12.037
4. [4]
  (10) ?nan, S.; Alta?, Y. Chem. Eng. J. 2011, 168 (3), 1263. (11) Guan,W.; Pan, J.; Ou, H.;Wang, X.; Zou, X.; Hu,W.; Li, C.; Wu, X. Chem. Eng. J. 2011, 167 (1), 215. doi: 10.1016/j.cej.2010.12.025
5. [5]
  (12) Thoro od, G. J.; Kennedy, B. J.; Avdeev, M.; Peterson, V. K.; Hanna, J. V.; Luca, V. J. Phys. Chem. Solids 2011, 72 (6), 692. (13) Möller, T.; Clearfield, A.; Harjula, R. Microporous Mesoporous Mat. 2002, 54 (1-2), 187. doi: 10.1016/S1387-1811(02)00320-7
6. [6]
  (14) Cakir, P.; Inan, S.; Altas, Y. J. Hazard. Mater. 2014, 271, 108. doi: 10.1016/j.jhazmat.2014.02.014
7. [7]
  (15) Möller, T.; Harjula, R.; Pillinger, M.; Dyer, A.; Newton, J.; Tusa, E.; Amin, S.;Webb, M.; Araya, A. J. Mater. Chem. 2001, 11 (5), 1526. (16) Möller, T.; Harjula, R.; Kelokaski, P.; Vaaramaa, K.; Karhu, P.; Lehto, J. J. Mater. Chem. 2003, 13 (3), 535. (17) Ali, I. M. Chem. Eng. J. 2009, 155 (3), 580. doi: 10.1016/j.cej.2009.07.050
8. [8]
  (18) Abe, M.; Ito, t. Bull. Chem. Soc. Jpn. 1968, 41, 2366. doi: 10.1246/bcsj.41.2366
9. [9]
  (19) Zhang,W.; Li, P.; Xu, H.; Sun, R.; Qing, P.; Zhang, Y. J. Hazard. Mater. 2014, 268, 273. doi: 10.1016/j.jhazmat.2014.01.016
10. [10]
  (20) Gurgul, J.; Rinke, M. T.; Schellenberg, I.; Pöttgen, R. Solid State Sci. 2013, 17, 122. doi: 10.1016/j.solidstatesciences.2012.11.014
11. [11]
  (21) Han, G. Z.; Zhang, C.; Gao, J. G.; Qian, P. Acta Phys. -Chim. Sin. 2011, 27 (6), 1361. [韩光占, 张超, 高吉刚, 钱萍. 物理化学学报, 2011, 27 (6), 1361.] doi: 10.3866/PKU.WHXB20110612
12. [12]
  (22) Yang, F. Chinese Journal of Aeronautics 2007, 20 (2), 181. doi: 10.1016/S1000-9361(07)60030-2
13. [13]
  (23) Zheng, G. Q.; Zhi, B.; Chen, J. Z. The Chinese Journal of Nonferrous Metals 2006, 16 (9), 1628. [郑国渠, 支波, 陈进中. 中国有色金属学报, 2006, 16 (9), 1628.] (24) Sangvanich, T.; Sukwarotwat, V.;Wiacek, R. J.; Grudzien, R. M.; Fryxell, G. E.; Addleman, R. S.; Timchalk, C.; Yantasee,W. J. Hazard. Mater. 2010, 182 (1-3), 225. doi: 10.1016/j.jhazmat.2010.06.019
14. [14]
  (25) Park, Y.; Lee, Y.; Shin,W. S.; Choi, S. Chem. Eng. J. 2010, 162(2), 685. doi: 10.1016/j.cej.2010.06.026
15. [15]
  (26) Rahman, R. O. A.; Ibrahim, H. A.; Hanafy, M.; Monem, N. M. A. Chem. Eng. J. 2010, 157 (1), 100. doi: 10.1016/j.cej.2009.10.057
16. [16]
  (27) Smi?iklas, I.; Dimovi?, S.; Ple?aš, I. Appl. Clay Sci. 2007, 35 (1-2), 139. doi: 10.1016/j.clay.2006.08.004
17. [17]
  (28) Tan, S.; Chen, X.; Ye, Y.; Sun, J.; Dai, L.; Ding, Q. J. Hazard. Mater. 2010, 179 (1-3), 559. doi: 10.1016/j.jhazmat.2010.03.040
18. [18]
  (29) Inan, S.; Nostar, E. Sep. Sci. Technol. 2013, 48 (9), 1364. doi: 10.1080/01496395.2012.732980
19. [19]
  (30) Appel, C.; Ma, L. Q.; Dean Rhue, R.; Kennelley, E. Geoderma 2003, 113 (1-2), 77. doi: 10.1016/S0016-7061(02)00316-6
1. [1]
  
  (1) Lehto, J.; Harjula, R. Radiochim. Acta 1999, 86 (1-2), 65. (2) Vesterbacka, P.; Hamalainen, K. Radiochim. Acta 2005, 93 (5), 291. (3) Kuronen, M.; Harjula, R. Radiochim. Acta 2005, 93 (2), 119. (4) Koivula, R.; Harjula, R. Sep. Sci. Technol. 2003, 38 (15), 3795. doi: 10.1081/SS-120024231
2. [2]
  (5) Harjula, R.; Lehtoa, J.; Paajanena, A.; Tusab, E.; Yarnell, P. React. Funct. Polym. 2004, 60, 85. doi: 10.1016/j.reactfunctpolym.2004.02.014
3. [3]
  (6) Möller, T.; Harjula, R.; Lehto, J. Sep. Sci. Technol. 2002, 28 (1), 13. (7) Liu, H. D.; Li, F. Z.; Zhao, X.; Yun, G. C. Nucl. Technol. 2009, 165, 200. (8) Tel, H.; Alta, Y.; Eral, M.; Sert, E.; Etinkaya, B.; Nan, S. Chem. Eng. J. 2010, 161 (1-2), 151. (9) Gürbo?a, G.; Tel, H. J. Hazard. Mater. 2005, 120 (1-3), 135. doi: 10.1016/j.jhazmat.2004.12.037
4. [4]
  (10) ?nan, S.; Alta?, Y. Chem. Eng. J. 2011, 168 (3), 1263. (11) Guan,W.; Pan, J.; Ou, H.;Wang, X.; Zou, X.; Hu,W.; Li, C.; Wu, X. Chem. Eng. J. 2011, 167 (1), 215. doi: 10.1016/j.cej.2010.12.025
5. [5]
  (12) Thoro od, G. J.; Kennedy, B. J.; Avdeev, M.; Peterson, V. K.; Hanna, J. V.; Luca, V. J. Phys. Chem. Solids 2011, 72 (6), 692. (13) Möller, T.; Clearfield, A.; Harjula, R. Microporous Mesoporous Mat. 2002, 54 (1-2), 187. doi: 10.1016/S1387-1811(02)00320-7
6. [6]
  (14) Cakir, P.; Inan, S.; Altas, Y. J. Hazard. Mater. 2014, 271, 108. doi: 10.1016/j.jhazmat.2014.02.014
7. [7]
  (15) Möller, T.; Harjula, R.; Pillinger, M.; Dyer, A.; Newton, J.; Tusa, E.; Amin, S.;Webb, M.; Araya, A. J. Mater. Chem. 2001, 11 (5), 1526. (16) Möller, T.; Harjula, R.; Kelokaski, P.; Vaaramaa, K.; Karhu, P.; Lehto, J. J. Mater. Chem. 2003, 13 (3), 535. (17) Ali, I. M. Chem. Eng. J. 2009, 155 (3), 580. doi: 10.1016/j.cej.2009.07.050
8. [8]
  (18) Abe, M.; Ito, t. Bull. Chem. Soc. Jpn. 1968, 41, 2366. doi: 10.1246/bcsj.41.2366
9. [9]
  (19) Zhang,W.; Li, P.; Xu, H.; Sun, R.; Qing, P.; Zhang, Y. J. Hazard. Mater. 2014, 268, 273. doi: 10.1016/j.jhazmat.2014.01.016
10. [10]
  (20) Gurgul, J.; Rinke, M. T.; Schellenberg, I.; Pöttgen, R. Solid State Sci. 2013, 17, 122. doi: 10.1016/j.solidstatesciences.2012.11.014
11. [11]
  (21) Han, G. Z.; Zhang, C.; Gao, J. G.; Qian, P. Acta Phys. -Chim. Sin. 2011, 27 (6), 1361. [韩光占, 张超, 高吉刚, 钱萍. 物理化学学报, 2011, 27 (6), 1361.] doi: 10.3866/PKU.WHXB20110612
12. [12]
  (22) Yang, F. Chinese Journal of Aeronautics 2007, 20 (2), 181. doi: 10.1016/S1000-9361(07)60030-2
13. [13]
  (23) Zheng, G. Q.; Zhi, B.; Chen, J. Z. The Chinese Journal of Nonferrous Metals 2006, 16 (9), 1628. [郑国渠, 支波, 陈进中. 中国有色金属学报, 2006, 16 (9), 1628.] (24) Sangvanich, T.; Sukwarotwat, V.;Wiacek, R. J.; Grudzien, R. M.; Fryxell, G. E.; Addleman, R. S.; Timchalk, C.; Yantasee,W. J. Hazard. Mater. 2010, 182 (1-3), 225. doi: 10.1016/j.jhazmat.2010.06.019
14. [14]
  (25) Park, Y.; Lee, Y.; Shin,W. S.; Choi, S. Chem. Eng. J. 2010, 162(2), 685. doi: 10.1016/j.cej.2010.06.026
15. [15]
  (26) Rahman, R. O. A.; Ibrahim, H. A.; Hanafy, M.; Monem, N. M. A. Chem. Eng. J. 2010, 157 (1), 100. doi: 10.1016/j.cej.2009.10.057
16. [16]
  (27) Smi?iklas, I.; Dimovi?, S.; Ple?aš, I. Appl. Clay Sci. 2007, 35 (1-2), 139. doi: 10.1016/j.clay.2006.08.004
17. [17]
  (28) Tan, S.; Chen, X.; Ye, Y.; Sun, J.; Dai, L.; Ding, Q. J. Hazard. Mater. 2010, 179 (1-3), 559. doi: 10.1016/j.jhazmat.2010.03.040
18. [18]
  (29) Inan, S.; Nostar, E. Sep. Sci. Technol. 2013, 48 (9), 1364. doi: 10.1080/01496395.2012.732980
19. [19]
  (30) Appel, C.; Ma, L. Q.; Dean Rhue, R.; Kennelley, E. Geoderma 2003, 113 (1-2), 77. doi: 10.1016/S0016-7061(02)00316-6
1. [1]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
2. [2]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
3. [3]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
4. [4]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
5. [5]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
6. [6]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
7. [7]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
8. [8]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
9. [9]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
10. [10]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
11. [11]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
12. [12]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
13. [13]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
14. [14]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
15. [15]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
16. [16]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
17. [17]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
18. [18]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
19. [19]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
20. [20]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408

Get Citation

PDF

XML

Metrics

PDF Downloads(271)
Abstract views(489)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation, Characterization and Sr(Ⅱ) Adsorption Performance of Self-Doped Antimony Oxide

References

Metrics

通讯作者: 陈斌, bchen63@163.com