Citation: JIAO Zhi-Feng, DONG Li-Li, GUO Xiao-Ning, JIN Guo-Qiang, GUO Xiang-Yun, WANG Xiao-Min. Methane Catalytic Combustion over Ni/SiC, Fe/SiC and Co/SiC Modified by Zr_0.5Ce_0.5O₂ Solid Solution[J]. Acta Physico-Chimica Sinica, ;2014, 30(10): 1941-1946. doi: 10.3866/PKU.WHXB201408181 shu

Methane Catalytic Combustion over Ni/SiC, Fe/SiC and Co/SiC Modified by Zr_0.5Ce_0.5O₂ Solid Solution

1.
1. College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, P. R. China;
2. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China

Received Date: 14 May 2014
Available Online: 18 August 2014
Fund Project:

We used Zr_0.5Ce_0.5O₂ solid solution modified high specific surface area SiC as the catalyst support and synthesized Ni/Ce_0.5Zr_0.5O₂/SiC, Fe/Ce_0.5Zr_0.5O₂/SiC, and Co/Ce_0.5Zr_0.5O₂/SiC catalysts by a two-step impregnation method. The catalytic activity and stability were investigated in the catalytic combustion deoxidation of coal-bed gas. The as-prepared catalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma- mass spectroscopy (ICP- MS), high- resolution transmission electron microscope (HRTEM), Brunner-Emmet-Teller (BET) measurements, thermal gravimetric analysis (TGA), and temperature-programmed reduction of H₂ (H₂-TPR). The results suggest that partial diffusion of Ni, Fe, and Co to the Ce_0.5Zr_0.5O₂ lattice leads to the formation of defects in the catalyst bulk phase. Ce_0.5Zr_0.5O₂ increased the redox process between metals and their oxides, improving the oxygen storage, mobility capacity, and the activation of CH₄. In addition, the excellent resistance of both SiC and Ce_0.5Zr_0.5O₂ solid solution to carbon deposition effectively inhibited coke formation on the catalysts during the combustion of rich methane atmosphere. Hence, these catalysts have od catalytic combustion deoxidation activity and stability. Co/ Ce_0.5Zr_0.5O₂/SiC catalyst had the best activity among the three catalysts: CH₄ was activated at 320 ℃ and O2 was completely removed at 410 ℃.
- High surface area SiC,
- Transition metal catalyst,
- Zr_0.5Ce_0.5O₂ solid solution,
- Methane catalytic combustion,
- Deoxidation of coal-bed gas
1. [1]
  
  (1) Zuo, C. J.; Qian, Y. J.; Tan, J.; Xu, H. M. Energy 2008, 33, 455. doi: 10.1016/j.energy.2007.07.001
2. [2]
  (2) Clayton, J. L. Int. J. Coal. Geol. 1998, 35, 159. doi: 10.1016/S0166-5162(97)00017-7
3. [3]
  (3) Özgen Karacan, C.; Ruiz, F. A.; Cotè, M.; Phipps, S. Int. J. Coal. Geol. 2011, 86, 121. doi: 10.1016/j.coal.2011.02.009
4. [4]
  (4) Gélin, P.; Primet, M. Appl. Catal. B 2002, 39, 1. doi: 10.1016/S0926-3373(02)00076-0
5. [5]
  (5) Ciuparu, D.; Lyubovsky, M. R.;Altman, E.; Pfefferle, L. D.; Datye, A. Catal. Rev. 2002, 44, 593. doi: 10.1081/CR-120015482
6. [6]
  (6) Xiao, L. H.; Sun, K. P.; Xu, X. L. Acta Phys. -Chim. Sin. 2008, 24, 2108. [肖利华, 孙鲲鹏, 徐贤伦. 物理化学学报, 2008, 24, 2108.] doi: 10.1016/S1872-1508(08)60080-7
7. [7]
  (7) Arai, H.; Machida, M. Catal. Today 1991, 10, 81. doi: 10.1016/0920-5861(91)80076-L
8. [8]
  (8) Lei, Z.; Sun, Y.; Han, M. F.;Wang, Q. B. Acta Phys. -Chim. Sin. 2012, 28, 2129. [雷泽, 孙义, 韩敏芳, 王启宝. 物理化学学报, 2012, 28, 2129.] doi: 10.3866/PKU.WHXB201206153
9. [9]
  (9) Wang, X.; Xie, Y. C. React. Kinet. Catal. Lett. 2000, 70, 43. doi: 10.1023/A:1010398212659
10. [10]
  (10) Li, Y. X.; Guo, Y. H.; Xue, B. Fuel Process. Technol. 2009, 90, 652. doi: 10.1016/j.fuproc.2008.12.002
11. [11]
  (11) Guo, X. N.; Zhi, G. J.; Yan, X. Y.; Jin, G. Q.; Guo, X. Y.; Brault, P. Catal. Commun. 2011, 12, 870. doi: 10.1016/j.catcom.2011.02.007
12. [12]
  (12) Birot,A.; Epron, F.; Descorme, C.; Duprez, D. Appl. Catal. B 2008, 79, 17. doi: 10.1016/j.apcatb.2007.10.002
13. [13]
  (13) Liu, Z. C.; Lu, G. Z.; Guo, Y.;Wang, Y. Q.; Guo, Y. L. Catal. Sci. Technol. 2011, 1, 1006. doi: 10.1039/c1cy00140j
14. [14]
  (14) Guo, X. N.; Brault, P.; Zhi, G. J.; Caillard, A.; Jin, G. Q.; Coutanceau, C.; Baranton, S.; Guo, X. Y. J. Phys. Chem. C 2011, 115, 11240. doi: 10.1021/jp203351p
15. [15]
  (15) Ledoux, M. J.; Pham-Huu, C. CatTech 2001, 5, 226. doi: 10.1023/A:1014092930183
16. [16]
  (16) Guo, X. Y.; Jin, G. Q. J. Mater. Sci. 2005, 40, 1301. doi: 10.1007/s10853-005-6957-6
17. [17]
  (17) Jin, G. Q.; Guo, X. Y. Microporous Mesoporous Mat. 2003, 60, 207. (18) de Leitenburg, C.; Trovarelli, A.; Llorca, J.; Cavani, F.; Bini, G. Appl. Catal. A: Gen. 1996, 139, 161. doi: 10.1016/0926-860X(95)00334-7
18. [18]
  (19) Balducci, G.; Fornasiero, P.; Di Monte, R.; Kaspar, J.; Meriani, S.; Graziani, M. Catal. Lett. 1995, 33, 193. doi: 10.1007/BF00817058
19. [19]
  (20) Vlaic, G.; Di Monte, R.; Fornasiero, P.; Fonda, E.; Kaapar, J.; Graziani, M. J. Catal. 1999, 182, 378. doi: 10.1006/jcat.1998.2335
20. [20]
  (21) Fornasiero, P.; Dimonte, R.; Rao, G. R.; Kaspar, J.; Meriani, S.; Trovarelli, A.; Graziani, M. J. Catal. 1995, 151, 168. doi: 10.1006/jcat.1995.1019
21. [21]
  (22) Chen, Y. D.; Liao, C.W.; Cao, H. Y.; Liu, Z. M.;Wang, J. L.; ng, M. C.; Chen, Y. Q. Chin. J. Catal. 2010, 31, 562. [陈永东, 廖传文, 曹红岩, 刘志敏, 王健礼, 龚茂初, 陈耀强. 催化学报, 2010, 31, 562.] (23) Chen, X. Y.; Tadd, A. R.; Schwank, J.W. J. Catal. 2007, 251, 374. doi: 10.1016/j.jcat.2007.07.031
22. [22]
  (24) Yue, B. H.; Zhou, R. X.;Wang, Y. J.; Zheng, X. M. Appl. Surf. Sci. 2006, 252, 5820. (25) Liu, H. T.; Li, S. Q.; Zhang, S. B.;Wang, J. M.; Zhou, G. J.; Chen, L.;Wang, X. L. Catal. Commun. 2008, 9, 51. doi: 10.1016/j.catcom.2007.05.002
23. [23]
  (26) van Steen, E.; Sewell, G. S.; Makhothe, R. A.; Micklethwaite, C.; Manstein, H.; de Lange, M.; Oconnor, C. T. J. Catal. 1996, 162, 220. doi: 10.1006/jcat.1996.0279
24. [24]
  (27) Reddy, E. P.; Davydov, L.; Smirniotis, P. G. J. Phys. Chem. B 2002, 106, 3394. (28) Tanksale, A.; Beltramini, J. N.; Dumesic, J. A.; Lu, G. Q. J. Catal. 2008, 258, 366. doi: 10.1016/j.jcat.2008.06.024
1. [1]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
2. [2]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
3. [3]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
4. [4]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
5. [5]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
6. [6]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
7. [7]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
8. [8]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
9. [9]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
10. [10]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
11. [11]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
12. [12]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
13. [13]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
14. [14]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
15. [15]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
16. [16]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
17. [17]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
18. [18]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
19. [19]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
20. [20]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349

Get Citation

PDF

XML

Metrics

PDF Downloads(462)
Abstract views(638)
HTML views(35)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Methane Catalytic Combustion over Ni/SiC, Fe/SiC and Co/SiC Modified by Zr0.5Ce0.5O2 Solid Solution

Metrics

通讯作者: 陈斌, bchen63@163.com

Methane Catalytic Combustion over Ni/SiC, Fe/SiC and Co/SiC Modified by Zr_0.5Ce_0.5O₂ Solid Solution