Citation: ZHANG Chuan-Xiang, ZHANG Xiao-Xue, TAO Hai-Jun. Synthesis and Electrochemical Properties of MoS₂/Graphene Composites with Petal-Shaped Microspheres[J]. Acta Physico-Chimica Sinica, ;2014, 30(10): 1963-1969. doi: 10.3866/PKU.WHXB201408043 shu

Synthesis and Electrochemical Properties of MoS₂/Graphene Composites with Petal-Shaped Microspheres

1.
1. College of Materials Engineering, Nanjing Institute of Technology, Nanjing 211167, P. R. China;
2. Jiangsu Key Laboratory of Advanced Sturctural Materials and Application Technolygy, Nanjing 211167, P. R. China;
3. College of Materials Science and Technology, Nanjing University of Aeronautics & Astronautics, Nanjing 211106, P. R. China

Received Date: 28 May 2014
Available Online: 4 August 2014
Fund Project:

MoS₂/graphene composites were synthesized using L-cysteine and sodium molybdate as the sources of sulfur and molybdenum, and L-cysteine was found to be beneficial for two-dimensional layered structure formation. Polyvinylpyrrolidone (PVP)-assisted hydrothermal synthesis gave petal-shaped MoS₂/ reduction of graphene oxide (R ) composite electrode materials (PVP-MoS₂/R ). X-ray diffraction and transmission electron microscopy confirmed that MoS₂ changed to a less ordered layer structure from the multilayer stacking structure after moderate addition of PVP. Scanning electron microscopy showed that the moderate PVP-assisted MoS₂/R material had a petal-shaped microsphere morphology with od dispersion. The ordered stacking structure with less layers and od dispersion of the composite materials shorten the embedded in/out path of lithium ions in MoS₂, which obviously improved their capacity, cycle stability, and rate performance as lithium ion battery anode materials.
- Petal shaped microsphere,
- PVP-MoS₂/R ,
- Capacity,
- Cycle stability,
- Rate performance
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Electrochemical Properties of MoS2/Graphene Composites with Petal-Shaped Microspheres

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Electrochemical Properties of MoS₂/Graphene Composites with Petal-Shaped Microspheres