Citation: TANG Jia-Yong, CAO Pei-Qi, FU Yan-Bao, LI Peng-Hui, MA Xiao-Hua. Synthesis of a Mesoporous Manganese Dioxide-Graphene Composite by a Simple Template-Free Strategy for High-Performance Supercapacitors[J]. Acta Physico-Chimica Sinica, ;2014, 30(10): 1876-1882. doi: 10.3866/PKU.WHXB201407172 shu

Synthesis of a Mesoporous Manganese Dioxide-Graphene Composite by a Simple Template-Free Strategy for High-Performance Supercapacitors

1.
1. Department of Materials Science, Fudan University, P. R. Shanghai 200433, P. R. China;
2. Environmental and Energy Technologies Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720, USA

Received Date: 6 May 2014
Available Online: 17 July 2014
Fund Project:

Amanganese dioxide (MnO₂)-graphene composite material with a unique structure consisting of MnO₂ surrounded by graphene sheets was prepared by a simple hydrothermal and thermal decomposition method. The morphology and structure of the obtained materials were examined by scanning electron microscopy, transition electron microscopy, Raman spectroscopy, X-ray diffraction, and N₂ adsorption-desorption. Electrochemical properties were evaluated by cyclic voltammetry, galvanostatic charge- discharge and electrochemical impedance spectroscopy. The specific surface area increased from 109 to 168 m²·g^-1 for the composite containing 15% (w) graphene. The specific capacitance also increased from 294 to 454 F·g^-1 at a current density of 0.2 A·g^-1 in an aqueous electrolyte supercapacitor. Moreover, after 2000 cycles of a galvanostatic charge-discharge test, the hybrid electrode still had excellent cycle stability (92% retention rate).
- Manganese oxide,
- Graphene,
- Composite,
- Supercapacitor,
- Hydrothermal method,
- Energy storage
1. [1]
  
  (1) Chen, Z.; Qin, Y.;Weng, D.; Xiao, Q.; Peng, Y.;Wang, X.; Li, H.;Wei, F.; Lu, Y. Advanced Functional Materials 2009, 19, 3420. doi: 10.1002/adfm.v19:21
2. [2]
  (2) Winter, M.; Brodd, R. J. Chemical Reviews 2004, 104 (10), 4245. doi: 10.1021/cr020730k
3. [3]
  (3) Burke, A. Journal of Power Sources 2000, 91 (1), 37. doi: 10.1016/S0378-7753(00)00485-7
4. [4]
  (4) Wang, G.; Zhang, L.; Zhang, J. Chemical Society Reviews 2012, 41 (2), 797. doi: 10.1039/c1cs15060j
5. [5]
  (5) Yang, Z.; Zhang, J.; Kintner-Meyer, M. C.; Lu, X.; Choi, D.; Lemmon, J. P.; Liu, J. Chemical Reviews 2011, 111 (5), 3577. doi: 10.1021/cr100290v
6. [6]
  (6) Yang, G.; Xu, C.; Li, H. Chem. Commun. 2008, 48, 6537. (7) Qu, D. Journal of Power Sources 2002, 109 (2), 403. doi: 10.1016/S0378-7753(02)00108-8
7. [7]
  (8) Su, P.; Guo, H. L.; Peng, S.; Ning, S. K. Acta Phys. -Chim. Sin. 2012, 28 (11), 2745. [苏鹏, 郭慧林, 彭三, 宁生科. 物理化学学报, 2012, 28 (11), 2745.] doi: 10.3866/PKU.WHXB201208221
8. [8]
  (9) Stoller, M. D.; Park, S.; Zhu, Y.; An, J.; Ruoff, R. S. Nano Letters 2008, 8 (10), 3498. (10) Zhu, J. B.; Xu, Y. L.;Wang, J.;Wang, J. P. Acta Phys. -Chim. Sin. 2012, 28 (2), 378. [朱剑波, 徐友龙, 王杰, 王景平. 物理化学学报, 2012, 28 (2), 378.] doi: 10.3866/PKU.WHXB201112021
9. [9]
  (11) Lu, X.; Dou, H.; Yuan, C.; Yang, S.; Hao, L.; Zhang, F.; Shen, L.; Zhang, L.; Zhang, X. Journal of Power Sources 2012, 197, 319. doi: 10.1016/j.jpowsour.2011.08.112
10. [10]
  (12) Liu, Y.; Yan, D.; Zhuo, R.; Li, S.;Wu, Z.;Wang, J.; Ren, P.; Yan, P.; Geng, Z. Journal of Power Sources 2013, 242, 78. doi: 10.1016/j.jpowsour.2013.05.062
11. [11]
  (13) Wang, Y.; Hu, Z.;Wu, H. Materials Chemistry and Physics 2011, 126 (3), 580. doi: 10.1016/j.matchemphys.2011.01.022
12. [12]
  (14) Liu, J.; Jiang, J.; Cheng, C.; Li, H.; Zhang, J.; ng, H.; Fan, H. J. Advanced Materials 2011, 23 (18), 2076. doi: 10.1002/adma.v23.18
13. [13]
  (15) Wei,W.; Cui, X.; Chen,W.; Ivey, D. G. Chemical Society Reviews 2011, 40 (3), 1697. doi: 10.1039/c0cs00127a
14. [14]
  (16) Long, J.W.; Bélanger, D.; Brousse, T.; Sugimoto,W.; Sassin, M. B.; Crosnier, O. Mrs Bull. 2011, 36 (7), 513. (17) Toupin, M.; Brousse, T.; Bélanger, D. Chemistry of Materials 2002, 14 (9), 3946. (18) Kim, J.; Lee, K. H.; Overzet, L. J.; Lee, G. S. Nano Letters 2011, 11 (7), 2611. (19) Li, P. H.; Ma, X. H. Battery Bimonthly 2013, No. 6, 247. [李鹏辉, 马晓华. 电池, 2013, No. 6, 247.] (20) Zhang, X. Y.; Ran, F.; Fan, H. L.; Kong, L. B.; Kang, L. Acta Phys. -Chim. Sin. 2014, 30 (5), 881. [张宣宣, 冉奋, 范会利, 孔令斌, 康龙. 物理化学学报, 2014, 30 (5), 881.] doi: 10.3866/PKU.WHXB201403061
15. [15]
  (21) Geim, A. K. Science 2009, 324 (5934), 1530. (22) Geim, A. K.; Novoselov, K. S. Nature Materials 2007, 6 (3), 183. doi: 10.1038/nmat1849
16. [16]
  (23) Yan, J.; Fan, Z.;Wei, T.; Qian,W.; Zhang, M.;Wei, F. Carbon 2010, 48 (13), 3825. doi: 10.1016/j.carbon.2010.06.047
17. [17]
  (24) Cheng, Q.; Tang, J.; Ma, J.; Zhang, H.; Shinya, N.; Qin, L. Carbon 2011, 49 (9), 2917. doi: 10.1016/j.carbon.2011.02.068
18. [18]
  (25) Yu, G.; Hu, L.; Vosgueritchian, M.;Wang, H.; Xie, X.; McDonough, J. R.; Cui, X.; Cui, Y.; Bao, Z. Nano Letters 2011, 11(7), 2905. doi: 10.1021/nl2013828
19. [19]
  (26) Subramanian, V.; Zhu, H.;Wei, B. Electrochemistry Communications 2006, 8 (5), 827. doi: 10.1016/j.elecom.2006.02.027
20. [20]
  (27) Chen, D.; Ji, G.; Ma, Y.; Lee, J. Y.; Lu, J. ACS Applied Materials & Interfaces 2011, 3 (8), 3078. doi: 10.1021/am200592r
21. [21]
  (28) Ma, J.; Cheng, Q.; Pavlinek, V.; Saha, P.; Li, C. New Journal of Chemistry 2013, 37, 722. doi: 10.1039/C2NJ40880E
22. [22]
  (29) Tang, X.; Liu, Z.; Zhang, C.; Yang, Z.;Wang, Z. Journal of Power Sources 2009, 193 (2), 939. doi: 10.1016/j.jpowsour.2009.04.037
23. [23]
  (30) Stankovich, S.; Dikin, D. A.; Dommett, G. H.; Kohlhaas, K. M.; Zimney, E. J.; Stach, E. A.; Piner, R. D.; Nguyen, S. T.; Ruoff, R. S. Nature 2006, 442 (7100), 282. doi: 10.1038/nature04969
24. [24]
  (31) ng, Y.; Yang, S.; Liu, Z.; Ma, L.; Vajtai, R.; Ajayan, P. M. Advanced Materials 2013, 25, 3979. doi: 10.1002/adma.201301051
25. [25]
  (32) Wang, D.; Li, F.;Wu, Z.; Ren,W.; Cheng, H. Electrochemistry Communications 2009, 11 (9), 1729. (33) Gao, T.; Glerup, M.; Krumeich, F.; Nesper, R.; Fjellvåg, H.; Norby, P. The Journal of Physical Chemistry C 2008, 112 (34), 13134. doi: 10.1021/jp804924f
26. [26]
  (34) Rao, C. N. R.; Sood, A. K.; Subrahmanyam, K. S.; vindaraj, A. Angewandte Chemie International Edition 2009, 48 (42), 7752. (35) Subramanian, V.; Zhu, H.;Wei, B. Journal of Power Sources 2006, 159 (1), 361. doi: 10.1016/j.jpowsour.2006.04.012
27. [27]
  (36) Mao, L.; Zhang, K.; Chan, H. S. O.;Wu, J. Journal of Materials Chemistry 2012, 22 (1), 80. doi: 10.1039/c1jm12869h
28. [28]
  (37) Lee, H.; Kang, J.; Cho, M. S.; Choi, J.; Lee, Y. Journal of Materials Chemistry 2011, 21 (45), 18215. doi: 10.1039/c1jm13364k
29. [29]
  (38) Zhang, L. L.; Zhou, R.; Zhao, X. S. Journal of Materials Chemistry 2010, 20 (29), 5983. doi: 10.1039/c000417k
30. [30]
  (39) Xu, M.; Kong, L.; Zhou,W.; Li, H. The Journal of Physical Chemistry C 2007, 111 (51), 19141. doi: 10.1021/jp076730b
31. [31]
  (40) Fan, Z.; Yan, J.;Wei, T.; Zhi, L.; Ning, G.; Li, T.;Wei, F. Advanced Functional Materials 2011, 21 (12), 2366. doi: 10.1002/adfm.v21.12
1. [1]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
2. [2]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . 二维材料基超级电容器的容量与倍率性能提升策略. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-. doi: 10.1016/j.actphy.2025.100063
3. [3]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
4. [4]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
5. [5]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
6. [6]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
7. [7]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
8. [8]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
9. [9]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
10. [10]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
11. [11]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
12. [12]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
13. [13]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
14. [14]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
15. [15]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
16. [16]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
17. [17]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
18. [18]
  Jiahao Lu , Xin Ming , Yingjun Liu , Yuanyuan Hao , Peijuan Zhang , Songhan Shi , Yi Mao , Yue Yu , Shengying Cai , Zhen Xu , Chao Gao . 基于稳态电热法的石墨烯膜导热系数的精确可靠测量. Acta Physico-Chimica Sinica, 2025, 41(5): 100045-. doi: 10.1016/j.actphy.2025.100045
19. [19]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
20. [20]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002

Get Citation

PDF

XML

Metrics

PDF Downloads(628)
Abstract views(712)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142