Citation: TANG Jia-Yong, CAO Pei-Qi, FU Yan-Bao, LI Peng-Hui, MA Xiao-Hua. Synthesis of a Mesoporous Manganese Dioxide-Graphene Composite by a Simple Template-Free Strategy for High-Performance Supercapacitors[J]. Acta Physico-Chimica Sinica, ;2014, 30(10): 1876-1882. doi: 10.3866/PKU.WHXB201407172 shu

Synthesis of a Mesoporous Manganese Dioxide-Graphene Composite by a Simple Template-Free Strategy for High-Performance Supercapacitors

1.
1. Department of Materials Science, Fudan University, P. R. Shanghai 200433, P. R. China;
2. Environmental and Energy Technologies Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720, USA

Received Date: 6 May 2014
Available Online: 17 July 2014
Fund Project:

Amanganese dioxide (MnO₂)-graphene composite material with a unique structure consisting of MnO₂ surrounded by graphene sheets was prepared by a simple hydrothermal and thermal decomposition method. The morphology and structure of the obtained materials were examined by scanning electron microscopy, transition electron microscopy, Raman spectroscopy, X-ray diffraction, and N₂ adsorption-desorption. Electrochemical properties were evaluated by cyclic voltammetry, galvanostatic charge- discharge and electrochemical impedance spectroscopy. The specific surface area increased from 109 to 168 m²·g^-1 for the composite containing 15% (w) graphene. The specific capacitance also increased from 294 to 454 F·g^-1 at a current density of 0.2 A·g^-1 in an aqueous electrolyte supercapacitor. Moreover, after 2000 cycles of a galvanostatic charge-discharge test, the hybrid electrode still had excellent cycle stability (92% retention rate).
- Manganese oxide,
- Graphene,
- Composite,
- Supercapacitor,
- Hydrothermal method,
- Energy storage
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