Citation: LIU Huan, ZANG Na, ZHAO Fang-Yao, LIU Kun, LI Yue, RUAN Wen-Juan. Synthesis and Nonlinear Optical Properties of Porphyrin-Salen Type Homo- and Hetero-Binuclear Metal Complexes[J]. Acta Physico-Chimica Sinica, ;2014, 30(10): 1801-1809. doi: 10.3866/PKU.WHXB201407171 shu

Synthesis and Nonlinear Optical Properties of Porphyrin-Salen Type Homo- and Hetero-Binuclear Metal Complexes

1.
Department of Chemistry, Nankai University, Tianjin 300071, P. R. China

Received Date: 21 April 2014
Available Online: 17 July 2014
Fund Project:

Two new porphyrin-Salen type ligands 5-(3-amino-4-(3,5-di-tert-butylsalicylidene)aminophenyl)- 10,15,20-triphenylporphyrin (1) and 5- (N,N'- di(3,5- di- tert- butylsalicylidene)-3,4-diaminophenyl)-10,15,20- triphenylporphyrin (2), their homo- and hetero- binuclear metal complexes and their mononuclear metal complexes were synthesized and characterized by ¹H nuclear magnetic resonance (¹H NMR) spectroscopy, electrospray ionization mass spectrometry (ESI-MS), elemental analysis, Fourier transform infrared (FTIR) spectroscopy, and ultraviolet visible (UV-Vis) spectroscopy. The third-order nonlinear optical properties of these ligands and complexes were investigated by Z scan techniques. Experimental results indicated that ligands 1 and 2 have a close strong reverse-saturable absorption and self-defocusing effect. The polarization induced by the coordinated metal ions affects the nonlinear refractive indexes of these ligands.
- Porphyrin- Salen type ligand,
- Homo- and hetero- binuclear metal complexes,
- Spectrum property,
- Third-order nonlinear optical property,
- Z scan
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