Citation: LI Xiang-Hong, DENG Shu-Duan, XIE Xiao-Guang, DU Guan-Ben. Inhibition Effect of Bamboo Leaf Extract on the Corrosion of Aluminum in HCl Solution[J]. Acta Physico-Chimica Sinica, ;2014, 30(10): 1883-1894. doi: 10.3866/PKU.WHXB201407161 shu

Inhibition Effect of Bamboo Leaf Extract on the Corrosion of Aluminum in HCl Solution

1.
1. Faculty of Science, Southwest Forestry University, Kunming 650224, P. R. China;
2. Yunnan Key Laboratory of Wood Adhesives and Glue Products, Southwest Forestry University, Kunming 650224, P. R. China;
3. School of Chemical Science and Technology, Yunnan University, Kunming 650091, P. R. China

Received Date: 28 April 2014
Available Online: 16 July 2014
Fund Project:

A bamboo leaf inhibitor (designated PSLE) was extracted from Phyllostachys sulphurea (Corr. Riviere) leaves using a series of C₂H₅OH-water solutions (20%-80% (volume fraction)). The solutions were characterized by Fourier transform infrared (FTIR) spectroscopy and ultraviolet- visible (UV-Vis) spectrophotometry. The total flavonoid content of the PSLE was determined. The inhibition effect of PSLE toward the corrosion of aluminum in HCl solution was studied by weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM). Density functional theory (DFT) quantum chemical calculations including solvent effects were used to investigate the adsorption of light by the two major components vientin and isovientin. The results show that PSLE is a od inhibitor and the adsorption of PSLE on the aluminum surface obeys the Langmuir adsorption isotherm. The inhibition efficiency increases with PSLE concentration while it decreases with temperature and HCl concentration. A od correlation exists between the total flavonoid content and the inhibition performance. This implies that the flavonoids are the major contributor to inhibition activity. PSLE behaves as a cathodic inhibitor. The EIS spectra are characterized by one large capacitive loop at high frequencies followed by a large inductive loop at low frequency values. The impedance value increases with increasing inhibitor concentration. SEM results confirm that the corrosion of aluminum is retarded remarkably by PSLE. The quantum calculation results indicate that the adsorption center of either vientin or isovientin is mainly a flavonoid backbone structure (FBS).
- Aluminium,
- Hydrochloric acid,
- Bamboo leaf extract,
- Corrosion inhibition,
- Adsorption,
- Quantum chemical calculation
1. [1]
  
  (1) Chaieb, E.; Bouyanzer, A.; Hammouti, B.; Berrabah, M. Acta Phys. -Chim. Sin. 2009, 25, 1254. [Chaieb, E.; Bouyanzer, A.; Hammouti, B.; Berrabah, M. 物理化学学报, 2009, 25, 1254.] doi: 10.3866/PKU.WHXB20090709
2. [2]
  (2) Raja, P. B.; Rahim, A. A.; Osman, H.; Awang, K. Acta Phys. -Chim. Sin. 2010, 26, 2171. [Raja, Pandian Bothi; Rahim, Afidah Abdul; Osman, Hasnah; Awang, Khalijah. 物理化学学报, 2010, 26, 2171.] doi: 10.3866/PKU.WHXB20100646
3. [3]
  (3) El Hosary, A. A.; Saleh R. M.; Shams El Din, A. M. Corrossion Sci. 1972, 12, 897. doi: 10.1016/S0010-938X(72)80098-2
4. [4]
  (4) Avwiri, G. O.; Lgho, F. O. Mater. Lett. 2003, 57, 3705. doi: 10.1016/S0167-577X(03)00167-8
5. [5]
  (5) Oguzie, E. E.; Onuchukwu, A. I.; Okafor, P. C.; Ebenso, E. E. Pig. Resin. Technol. 2006, 35 (2), 63. doi: 10.1108/03699420610652340
6. [6]
  (6) El-Etre, A. Y. Corrosion Sci. 2003, 45, 2485. doi: 10.1016/S0010-938X(03)00066-0
7. [7]
  (7) Oguzie, E. E. Corrosion Sci. 2007, 49, 1527. doi: 10.1016/j.corsci.2006.08.009
8. [8]
  (8) Umoren, S. A.; Obot, I. B.; Ebenso, E. E.; Obi-Egbedi, N. O. Desalination 2009, 247, 561. doi: 10.1016/j.desal.2008.09.005
9. [9]
  (9) Deng, S. D.; Li, X. H. Corrosion Sci. 2012, 64, 253. doi: 10.1016/j.corsci.2012.07.017
10. [10]
  (10) Lu, B. Y.;Wu, X. Q.; Tie, X.W.; Zhang, Y.; Zhang, Y. Food Chem. Toxicol. 2005, 43, 783. doi: 10.1016/j.fct.2005.01.019
11. [11]
  (11) Lu, B. Y.;Wu, X. Q.; Shi, J. Y.; Dong, Y. J.; Zhang, Y. Food Chem. Toxicol. 2006, 44, 1739. doi: 10.1016/j.fct.2006.05.012
12. [12]
  (12) Li, X. H.; Deng, S. D.; Fu, H. Corrosion Sci. 2012, 62, 163. doi: 10.1016/j.corsci.2012.05.008
13. [13]
  (13) Deng, S. D.; Li, X. H.; Fu, H. Chem. Indust. Forest Prod. 2010, 30, 81. [邓书端, 李向红, 付惠. 林产化学与工业, 2010, 30, 81.] (14) Li, X. H.; Deng, S. D. Corrosion Sci. 2012, 65, 299. doi: 10.1016/j.corsci.2012.08.033
14. [14]
  (15) Li, X. H.; Deng, S. D.; Fu, H. Acta Phys. -Chim. Sin. 2011, 27, 2841. [李向红, 邓书端, 付惠. 物理化学学报, 2011, 27, 2841.] doi: 10.3866/PKU.WHXB20112841
15. [15]
  (16) Materials Studio 7.0. Accelrys Inc.: San Die , CA, 2013. (17) Becke, A. D. J. Chem. Phys. 1988, 88, 2547. doi: 10.1063/1.454033
16. [16]
  (18) Lee, C.; Yang,W.; Parr, R. G. Phys. Rev. B 1988, 37, 785. doi: 10.1103/PhysRevB.37.785
17. [17]
  (19) Klamt, A.; Schüürmann, G. J. Chem. Soc. Perkin Trans. 1993, 2, 799. (20) Jing,W. J. Information Develop Economy 2009, 19, 139. (21) Su, C. H.;Wang, F. S.; Ding, Y. L. China Forestry Sci. Tech. 2010, 24, 87. (22) Deng, Q. Y.; Liu, L.; Deng, H. M. Principles of Spectrometric Identification, 2nd ed.; Science Press: Beijing, 2007; p 37. (23) Kuang, H. X. Traditional Chinese Medicine Chemistry; Traditional Chinese Medicine Press: Beijing, 2003; p 155. (24) Fuchs- dec, R.; Dole?ek,V. Colloids Surf. A 2004, 244, 73. doi: 10.1016/j.colsurfa.2004.05.015
18. [18]
  (25) Cano, E.; Polo, J. L.; La Iglesia, A.; Bastidas, J. M. Adsorption 2004, 10, 219. doi: 10.1023/B:ADSO.0000046358.35572.4c
19. [19]
  (26) Zhao, J. M.; Li, J. Acta Phys. -Chim. Sin. 2012, 28, 623. [赵景茂, 李俊. 物理化学学报, 2012, 28, 623.] doi: 10.3866/PKU.WHXB201112293
20. [20]
  (27) Oguzie, E. E.; Unaegbu, C.; Ogukwea, C. N.; Okolue, B. N.; Onuchuku, A. I. Mater. Chem. Phys. 2004, 84, 363. doi: 10.1016/j.matchemphys.2003.11.027
21. [21]
  (28) Deng, S. D.; Li, X. H.; Xie, X. G. Corrosion Sci. 2014, 80, 276. doi: 10.1016/j.corsci.2013.11.041
22. [22]
  (29) Zhang, Q. B.; Hua, Y. X. Mater. Chem. Phys. 2010, 119, 57. doi: 10.1016/j.matchemphys.2009.07.035
23. [23]
  (30) Martinez, S.; Stern, I. Appl. Surf. Sci. 2002, 199, 83. doi: 10.1016/S0169-4332(02)00546-9
24. [24]
  (31) Behpour, M.; Ghoreishi, S. M.; Soltani, N.; Salavati-Niasari, M. T. Corrosion Sci. 2009, 51, 1073. doi: 10.1016/j.corsci.2009.02.011
25. [25]
  (32) Cai, Q. H.; Shan, Y. K.; Lu, B.; Yuan, X. H. Corrosion 1993, 49, 486. doi: 10.5006/1.3316077
26. [26]
  (33) de Assunção Araújo Pereira, S. S.; Pêgas, M. M.; Fernández, T. L.; Magalhães, M.; Schöntag, T. G.; La , D. C.; de Senna, L. F.; D'Elia, E. Corrosion Sci. 2012, 65, 360. doi: 10.1016/j.corsci.2012.08.038
27. [27]
  (34) Obot, I. B.; Obi-Egbedi, N. O. Corrosion Sci. 2010, 52, 282. doi: 10.1016/j.corsci.2009.09.013
28. [28]
  (35) Shukla, S. K.; Quraishi, M. A. Corrosion Sci. 2010, 52, 314. doi: 10.1016/j.corsci.2009.09.017
29. [29]
  (36) Talati, J. D.; Gandhi, D. K. Corrosion Sci. 1983, 23, 1315. doi: 10.1016/0010-938X(83)90081-1
30. [30]
  (37) Yurt, A.; Ulutas, S.; Dal, H. Appl. Surf. Sci. 2006, 253, 919. doi: 10.1016/j.apsusc.2006.01.026
31. [31]
  (38) Li, X. H.; Deng, S. D.; Fu, H. Corrosion Sci. 2011, 53, 1529. (39) Cao, C. N. Corrosion Electrochemistry Mechanism, 3rd ed.; Chemical Industrial Engineering Press: Beijing, 2008; p 197. (40) Oguzie, E. E.; Okolue, B. N.; Ebenso, E. E.; Onuoha, G. N.; Onuchukwu, A. I. Mater. Chem. Phys. 2004, 87, 394. doi: 10.1016/j.matchemphys.2004.06.003
32. [32]
  (41) Khaled, K. F.; Al-Qahtani, M. M. Mater. Chem. Phys. 2009, 113, 150. doi: 10.1016/j.matchemphys.2008.07.060
33. [33]
  (42) Li, X. H.; Deng, S. D.; Xie, X. G. Corrosion Sci. 2014, 81, 162. doi: 10.1016/j.corsci.2013.12.021
34. [34]
  (43) Garrigues, L.; Pebere, N.; Dabosi, F. Electrochim. Acta 1996, 41, 1209. doi: 10.1016/0013-4686(95)00472-6
35. [35]
  (44) Noor, E. A. Mater. Chem. Phys. 2009, 114, 533. doi: 10.1016/j.matchemphys.2008.09.065
36. [36]
  (45) Bessone, J.; Mayer, C.; Jutter, K.; Lorenz,W. Electrochim. Acta 1983, 28, 171. doi: 10.1016/0013-4686(83)85105-6
37. [37]
  (46) Brett, C. M. A. Corrosion Sci. 1992, 33, 203. doi: 10.1016/0010-938X(92)90145-S
38. [38]
  (47) Burstein, G. T.; Cinderey, R. J. Corrosion Sci. 1992, 32, 1195. (48) Metlkoš -Hukovi?, M.; Babi?, R.; Grubac, Z. J. Appl. Electrochem. 1998, 28, 433. doi: 10.1023/A:1003200808093
39. [39]
  (49) Lebrini, M.; Lagrenée, M.; Vezin, H.; Traisnel, M.; Bentiss, F. Corrosion Sci. 2007, 49, 2254. doi: 10.1016/j.corsci.2006.10.029
40. [40]
  (50) Amin, M. A.; Mohsen, Q.; Hazzai, O. A. Mater. Chem. Phys. 2009, 114, 908. doi: 10.1016/j.matchemphys.2008.10.057
41. [41]
  (51) Lenderink, H. J.W.; Linden, M. V. D.; DeWit, J. H.W. Electrochim. Acta 1993, 38, 1989. doi: 10.1016/0013-4686(93)80329-X
42. [42]
  (52) Kilner, C. A.; Halcrow, M. A. Polyhedron 2006, 25, 235. doi: 10.1016/j.poly.2005.06.034
43. [43]
  (53) Beaufort, L.; Benvenuti, F.; Noels, A. F. I. J. Mol. Catal. AChem. 2006, 260, 210. doi: 10.1016/j.molcata.2006.07.005
44. [44]
  (54) Abd El Rehim, S. S.; Hassan, H. H.; Amin, M. A. Mater. Chem. Phys. 2001, 70, 64. doi: 10.1016/S0254-0584(00)00468-5
45. [45]
  (55) Osório,W. R.; Moutinho, D. J.; Peixoto, L. C.; Ferreira, I. L.; Garcia, A. Electrochim. Acta 2011, 56, 8412. doi: 10.1016/j.electacta.2011.07.028
46. [46]
  (56) Lagrenée, M.; Mernari, B.; Bouanis, M.; Traisnel, M.; Bentiss, F. Corrosion Sci. 2002, 44, 573. doi: 10.1016/S0010-938X(01)00075-0
47. [47]
  (57) Lorenz,W. J.; Mansfeld, F. Corrosion Sci. 1981, 21, 647. doi: 10.1016/0010-938X(81)90015-9
48. [48]
  (58) Tang, H. G.; Zheng,W. D.; Chen, Z. D. Chin. Agri. Sci. Bull. 2005, 21, 114. (59) Li, H. Y.; Sun, J. Y.; Zhang, J. M.; Shou, D. Chin. Traditional Patent Medi. 2004, 26, 208. (60) Li, X. H.; Deng, S. D.; Fu, H.; Xie, X. G. Corrosion Sci. 2014, 78, 29. doi: 10.1016/j.corsci.2013.08.025
49. [49]
  (61) Gao, Z. Q.; Xu, Q.; Song, Z. R.;Wang, L. Chem. World 2008, 49, 439. (62) Fukui, K. Angewandte Chemie International Edition in English 1982, 21, 801. (63) Li, X. H.; Xie, X. G. Acta Phys. -Chim. Sin. 2013, 29, 2221. [李向红, 谢小光. 物理化学学报, 2013, 29, 2221.] doi: 10.3866/PKU.WHXB201307301
1. [1]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
2. [2]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
3. [3]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
4. [4]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
5. [5]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
6. [6]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
7. [7]
  Jia Zhou . Constructing Potential Energy Surface of Water Molecule by Quantum Chemistry and Machine Learning: Introduction to a Comprehensive Computational Chemistry Experiment. University Chemistry, 2024, 39(3): 351-358. doi: 10.3866/PKU.DXHX202309060
8. [8]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
9. [9]
  Dongju Zhang , Rongxiu Zhu . Construction of Ideological and Political Education in Quantum Chemistry Course: Several Teaching Cases to Reveal the Universal Connection of Things. University Chemistry, 2024, 39(7): 272-277. doi: 10.3866/PKU.DXHX202311032
10. [10]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
11. [11]
  Zhaoyue Lü , Zhehao Chen , Yi Ni , Duanbin Luo , Xianfeng Hong . Multi-Level Teaching Design and Practice Exploration of Raman Spectroscopy Experiment. University Chemistry, 2024, 39(11): 304-312. doi: 10.12461/PKU.DXHX202402047
12. [12]
  Tongyu Zheng , Teng Li , Xiaoyu Han , Yupei Chai , Kexin Zhao , Quan Liu , Xiaohui Ji . A DIY pH Detection Agent Using Persimmon Extract for Acid-Base Discoloration Popularization Experiment. University Chemistry, 2024, 39(5): 27-36. doi: 10.3866/PKU.DXHX202309107
13. [13]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
14. [14]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
15. [15]
  Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
16. [16]
  Tao Cao , Fang Fang , Nianguang Li , Yinan Zhang , Qichen Zhan . Green Synthesis of p-Hydroxybenzonitrile Catalyzed by Spinach Extracts under Red-Light Irradiation: Research and Exploration of Innovative Experiments for Pharmacy Undergraduates. University Chemistry, 2024, 39(5): 63-69. doi: 10.3866/PKU.DXHX202309098
17. [17]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
18. [18]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
19. [19]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
20. [20]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187

Get Citation

PDF

XML

Metrics

PDF Downloads(414)
Abstract views(663)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142