Citation: XIAO Bo, LIU Shou-Qing. Photocatalytic Oxidation of Ammonia via an Activated Carbon-Nickel Ferrite Hybrid Catalyst under Visible Light Irradiation[J]. Acta Physico-Chimica Sinica, ;2014, 30(9): 1697-1705. doi: 10.3866/PKU.WHXB201407111 shu

Photocatalytic Oxidation of Ammonia via an Activated Carbon-Nickel Ferrite Hybrid Catalyst under Visible Light Irradiation

XIAO Bo ,
LIU Shou-Qing

1.
Jiangsu Key Laboratory of Environmental Functional Materials, School of Chemistry, Biology and Material Engineering, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu Province, P. R. China

Received Date: 18 April 2014
Available Online: 11 July 2014
Fund Project:

The nickel atoms in a metal ferrite lattice inhibit photocatalytic activity with hydrogen peroxide. However, activated carbon bonded on nickel ferrite (AC-NiFe₂O₄) induces photocatalytic activity of nickel ferrite with hydrogen peroxide, enabling photo-Fenton catalytic oxidation of ammonia under visible-light irradiation in the presence of hydrogen peroxide. The AC-NiFe₂O₄ catalyst was characterized using X-ray diffraction, transmission electron microscopy, Fourier-transform infrared spectroscopy, and a vibrating sample magnetometer at room temperature. The photocatalytic tests showed that the ammonia degradation efficiency approached 91.0% in the presence of the AC-NiFe₂O₄ catalyst, whereas the efficiency was only 24.0% without the catalyst under similar conditions over 10 h. Another test showed that the single NiFe₂O₄ catalyst achieved a degradation efficiency of only 30.0% under similar conditions, indicating that activated carbon can accelerate the rate of ammonia oxidation. Exploration of the oxidation mechanism showed that the oxidation pathway involves an HONH₂ intermediate, forming nitrite ions. Kinetic studies showed that the oxidation of ammonia follows a pseudo-first order kinetic law, with a rate constant of 3.538×10^-3 min^-1. The catalyst was used in eight runs, and shown to be stable, recoverable, separable, and reusable, suggesting that it has potential applications in the disposal of ammonia.
- Nickel ferrite,
- Activated carbon,
- Hybrid,
- Photo-Fenton catalyst,
- Ammonia oxidation
1. [1]
  
  (1) Costa, R. C. C.; Lelis, M. F. F.; Oliveira, L. C. A.; Fabris, J. D.; Ardisson, J. D.; Rios, R. R. V. A.; Silva, C. N.; La , R. M. J. Hazard. Mater. B 2006, 129, 171. doi: 10.1016/j.jhazmat.2005.08.028
2. [2]
  (2) Liu, S. Q.; Feng, L. R.; Xu, N.; Chen, Z. G.;Wang, X. M. Chem. Eng. J. 2012, 203, 432. doi: 10.1016/j.cej.2012.07.071
3. [3]
  (3) Fu, Y. S.; Chen, H. Q.; Sun, X. Q.;Wang, X. AIChE J. 2012, 58, 3298. doi: 10.1002/aic.13716
4. [4]
  (4) Pan, X.; Fu, Y.;Wang, L.;Wang, X. Chem. Eng. J. 2012, 149, 195.
5. [5]
  (5) Nguyen, T. D.; Phan, N. H.; Do, M. H.; N , K. T. J. Hazard. Mater. 2011, 185, 653. doi: 10.1016/j.jhazmat.2010.09.068
6. [6]
  (6) Xu, X.;Wang, X. J.; Hu, Z. H.; Liu, Y .F.;Wang, C. C.; Zhao, G. H. Acta Phys. -Chim. Sin. 2010, 26, 79. [徐鑫, 王晓静,胡中华, 刘亚菲, 王晨晨, 赵国华. 物理化学学报, 2010, 26, 79.] doi: 10.3866/PKU.WHXB20100131
7. [7]
  (7) Yang, H. P.; Zhang, Y. C.; Fu, X. F.; Song, S. S.;Wu, J. M. Acta Phys. -Chim. Sin. 2013, 29, 1327. [杨汉培, 张颖超, 傅小飞, 宋双双, 吴俊明. 物理化学学报, 2013, 29, 1327.] doi: 10.3866/PKU.WHXB201303212
8. [8]
  (8) Long, M.; Cong, Y.; Li, X. K.; Cui, Z.W.; Dong, Z. J.; Yuan, G. M. Acta Phys. -Chim. Sin. 2013, 29, 1344. [龙梅, 丛野, 李轩科, 崔正威, 董志军, 袁观明. 物理化学学报, 2013, 29, 1344.] doi: 10.3866/PKU.WHXB201303263
9. [9]
  (9) Xing,W. N.; Ni, L.; Yan, X. S.; Liu, X. L.; Luo, Y. Y.; Lu, Z. Y.; Yan, Y. S.; Huo, P.W. Acta Phys. -Chim. Sin. 2014, 30, 141. [邢伟男, 倪良, 颜学升, 刘馨琳, 罗莹莹, 逯子扬, 闫永胜, 霍鹏伟. 物理化学学报, 2014, 30, 141.] doi: 10.3866/PKU.WHXB201311211
10. [10]
  (10) Ou, H. H.; Hoffmann, M. R.; Liao, C. H.; Hong, J. H.; Lo, S. L. Appl. Catal. B 2010, 99, 74. doi: 10.1016/j.apcatb.2010.06.002
11. [11]
  (11) Bonsen, E. M.; Schroeter, S.; Jacobs, H.; Broekaert, J. A. C. Chemosphere 1997, 35, 1431. doi: 10.1016/S0045-6535(97)00216-6
12. [12]
  (12) Altomare, M.; Chiarello, G. L.; Costa, A.; Guarino, M.; Selli, E.; Chem. Eng. J. 2012, 191, 394. doi: 10.1016/j.cej.2012.03.037
13. [13]
  (13) Kominami, H.; Nishimune, H.; Ohta, Y.; Arakawa, Y.; Inaba, T. Appl. Catal. B 2012, 111, 297.
14. [14]
  (14) Kolinko, P. A.; Kozlov, D. V. Appl. Catal. B 2009, 90, 126. doi: 10.1016/j.apcatb.2009.03.001
15. [15]
  (15) Boulinguiez, B.; Bouzaza, A.; Merabet, S.;Wolbert, D. J. Photochem. Photobiol. A 2008, 200, 254. doi: 10.1016/j.jphotochem.2008.08.005
16. [16]
  (16) Zhu, X.; Nanny, M. A.; Butler, E. C. Water Res. 2008, 42, 2736. doi: 10.1016/j.watres.2008.02.003
17. [17]
  (17) Shavisi, Y.; Sharifnia, S.; Hosseini, S. N.; Khadivi, M. A. J. Ind. Eng. Chem. 2014, 20, 278. doi: 10.1016/j.jiec.2013.03.037
18. [18]
  (18) Dong, Y.; Bai, Z.; Liu, R.; Zhu, T. Atmos. Environ. 2007, 41, 3182. doi: 10.1016/j.atmosenv.2006.08.056
19. [19]
  (19) Geng, Q.; Guo, Q.; Cao, C.; Zhang, Y.;Wang, L. Ind. Eng. Chem. Res. 2008, 47, 4363. doi: 10.1021/ie800274g
20. [20]
  (20) u, H. H.; Liao, C. H.; Liou, Y. H.; Hong, J. H.; Lo, S. L. Environ. Sci. Technol. 2008, 42, 4507. doi: 10.1021/es703211u
21. [21]
  (21) Altomare, M.; Selli, E. Catalysis Today 2013, 209, 127. doi: 10.1016/j.cattod.2012.12.001
22. [22]
  (22) Niedzielski, P.; Kurzyca, I.; Siepak, J. Anal. Chim. Acta 2006, 577, 220. doi: 10.1016/j.aca.2006.06.057
23. [23]
  (23) Lazarevic, Z. ?.; Jovalekic, C.; Recnik, A.; Ivanovski, V. N.; Milutinovic, A.; Romcevic, M.; Pavlovic, M. B.; Cekic, B.; Romcevic, N. ?. Mater. Res. Bull. 2013, 48, 404. doi: 10.1016/j.materresbull.2012.10.061
24. [24]
  (24) Klug, H. P.; Alexander, L. E. X-Ray Diffraction Procedures for Polycrystalline and Amorphous Materials, 2nd ed.;Wiley: New York, 1974.
25. [25]
  (25) Mouallem-Bahout, M.; Bertrand, S.; PeHa, O. J. Solid State Chem. 2005, 178, 1080. doi: 10.1016/j.jssc.2005.01.009
26. [26]
  (26) Hoigne, J.; Bader, H. Environ. Sci. Technol. 1978, 12, 79. doi: 10.1021/es60137a005
27. [27]
  (27) Liao, Q.; Sun, J.; Gao, L. Colloids Surf. A 2009, 345, 95. doi: 10.1016/j.colsurfa.2009.04.037
28. [28]
  (28) Romero, A.; Santos, A.; Vicente, F. J. Hazard. Mater. 2009, 162, 785. doi: 10.1016/j.jhazmat.2008.05.123
29. [29]
  (29) Ramirez, J. H.; Maldonado-Hódar, F. J.; Pérez-Cadenas, A. F.; Moreno-Castilla, C.; Costa, C. A.; Madeira, L. M. Appl. Catal. B 2007, 75, 312. doi: 10.1016/j.apcatb.2007.05.003
30. [30]
  (30) Lam, S.W.; Chiang, K.; Lim, T. M.; Amal, R.; Low, G. K. C. J. Catal. 2005, 234, 292. doi: 10.1016/j.jcat.2005.06.014
31. [31]
  (31) Bacardit, J.; Sto1tzner, J.; Chamarro, E. Eng. Chem. Res. 2007, 46, 7615. doi: 10.1021/ie070154o
32. [32]
  (32) Machulek, A., Jr.; Moraes, J. E. F.; Carolina, Vautier-Gion .; Silverio, C. A.; Friedrich, L. C.; Nascimento, C. A. O.; nzalez, M. C.; Quina, F. H. Environ. Sci. Technol. 2007, 41, 8459. doi: 10.1021/es071884q
33. [33]
  (33) Li, M.; Feng, C.; Zhang, Z.; Zhao, R.; Lei, X.; Chen, R.; Sugiura, N. Electrochim. Acta 2009, 55, 159. doi: 10.1016/j.electacta.2009.08.027
34. [34]
  (34) Zhu, X.; Castleberry, S. R.; Nanny, M. A.; Butler, E. C. Environ. Sci. Technol. 2005, 39, 3784. doi: 10.1021/es0485715
35. [35]
  (35) Lee, J.; Park, H.; Choi,W. Environ. Sci. Technol. 2002, 36, 5462. doi: 10.1021/es025930s
36. [36]
  (36) Velasco, L. F.; Fonseca, I. M.; Parra, J. B.; Lima, J.; Ania, C. O. Carbon 2012, 50, 249. doi: 10.1016/j.carbon.2011.08.042
37. [37]
  (37) Leary, R.;Westwood, A. Carbon 2011, 49, 741. doi: 10.1016/j.carbon.2010.10.010
38. [38]
  (38) Liu, S. Q.; Xiao, B.; Feng, L. R.; Zhou, S. S.; Chen, Z. G.; Liu, C. B.; Chen, F.;Wu, Z. Y.; Xu N.; Oh,W. C.; Meng, Z. D. Carbon 2013, 64, 197. doi: 10.1016/j.carbon.2013.07.052
39. [39]
  (39) Guo, S.; Zhang, G. K.; Guo, Y. D.; Yu, J. C. Carbon 2013, 60, 437. doi: 10.1016/j.carbon.2013.04.058
1. [1]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
2. [2]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
3. [3]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
4. [4]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
5. [5]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
6. [6]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
7. [7]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
8. [8]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
9. [9]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
10. [10]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
11. [11]
  Fei Liu , Dong-Yang Zhao , Kai Sun , Ting-Ting Yu , Xin Wang . Comprehensive Experimental Design for Photochemical Synthesis, Analysis, and Characterization of Seleno-Containing Medium-Sized N-Heterocycles. University Chemistry, 2024, 39(3): 369-375. doi: 10.3866/PKU.DXHX202309047
12. [12]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
13. [13]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
14. [14]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
15. [15]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
16. [16]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
17. [17]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
18. [18]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
19. [19]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
20. [20]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

Get Citation

PDF

XML

Metrics

PDF Downloads(445)
Abstract views(702)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142