Citation: YANG Peng, TAN Fu-Rui, ZHANG Jing, JIN He-Hua, LI Hong-Bo, LIU Chun-Hua, LI Qing-Wen. Effects of Pore-Size Range and Composition of Polysaccharide Gels on Flow Behaviors and Selective Sorting of Single-Walled Carbon Nanotubes[J]. Acta Physico-Chimica Sinica, ;2014, 30(9): 1764-1770. doi: 10.3866/PKU.WHXB201407032 shu

Effects of Pore-Size Range and Composition of Polysaccharide Gels on Flow Behaviors and Selective Sorting of Single-Walled Carbon Nanotubes

1.
1. School of Chemical Engineering, Hefei University of Technology, Hefei 230009, P. R. China;
2. Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Science, Suzhou 215123, Jiangsu Province, P. R. China

Received Date: 5 May 2014
Available Online: 3 July 2014
Fund Project:

We used gel-column chromatography to show the effects of the pore-size range and chemical composition of porous polysaccharide gels on the flow characteristics and metal/semiconductor (m/s) separation of dispersed single-walled carbon nanotubes (SWCNTs). Comparative studies of the flow behaviors of dispersed SWCNTs in a series of Sephacryl gels with different pore sizes showed that a small pore-size range increased the interaction strength of SWCNTs with gels, leading to rapid flow of thicker metallic (m-)SWCNTs through gel beads, and the selective entrapment of thinner semiconducting (s-)SWCNTs. We also found that the effect of the gel composition was more important than that of the gel porosity on the sorting of SWCNTs. When the amine group in the dextran-based Sephacryl gel was replaced by agarose, e.g., Superdex 200 or Sepharose 2B gel, the interaction with the dispersed SWCNTs was enhanced, resulting in slowing down of both the m- and s- SWCNTs throughout the gel, and obvious deterioration in the selectivity for, and purity of, the s-SWCNTs. In contrast, Sephadex G100 gel, which has one dextran group functionalized by hydrophobic epoxypropane, yielded very weak interactions with SWCNTs, leading to direct drainage of both types of SWCNT, despite its fine pore size, similar to that of Sephacryl S100. We therefore propose that the gel pore size and composition exerted a synergistic effect in verning the m/s sorting of SWCNTs with high selectivity, purity, and efficiency.
- Single-walled carbon nanotube,
- Separation,
- Pore-size range,
- Composition,
- Polysaccharide gel chromatography
1. [1]
  
  (1) Saito, R.; Dresslhaus, G.; Dresselhaus, M. S. Physical Review B 2000, 61 (4), 2981. doi: 10.1103/PhysRevB.61.2981
2. [2]
  (2) Ryabenko, A. G.; Dorofeeva, T. V.; Zvereva, G. I. Carbon 2004, 42 (8-9), 1523. doi: 10.1016/j.carbon.2004.02.005
3. [3]
  (3) Hecht, D. S.; Hu, L. B.; Irvin. G. Adv. Mater. 2011, 23 (13), 1482. doi: 10.1002/adma.201003188
4. [4]
  (4) Kong, J.; Franklin, N. R.; Zhou, C.W.; Chapline, M. G.; Peng, S.; Cho, K. J.; Dai, H. J. Science 2000, 287 (5453), 622. doi: 10.1126/science.287.5453.622
5. [5]
  (5) Javey, A.; Guo, J.;Wang, Q.; Lundstrom, M.; Dai, H. J. Nature 2003, 424, 654. doi: 10.1038/nature01797
6. [6]
  (6) Wind, S. J.; Appenzeller, J.; Avouris, P. Phys. Rev. Lett. 2003, 91, 058301. doi: 10.1103/PhysRevLett.91.058301
7. [7]
  (7) Jaisi, D. P.; Saleh, N. B.; Blake, R. E.; Elimelech, M. Environmental Science & Technology 2008, 42, 8317. doi: 10.1021/es801641v
8. [8]
  (8) Jaisi, D. P.; Elimelech, M. Environmental Science & Technology 2009, 43, 9161.
9. [9]
  (9) Li, H. B.; Zhang, J.; Jin, H. H.; Li, Q.W. Acta Phys. -Chim. Sin. 2012, 26 (10), 2447. [李红波, 张静, 金赫华, 李清文. 物理化学学报, 2012, 26 (10), 2447.] doi: 10.3866/PKU.WHXB201209041
10. [10]
  (10) Arnold, K.; Hennrich, F.; Krupke, R.; Lebedkin, S.; Kappes, M. M. Physica Status Solidi B-Basic Solid State Physics 2006, 243, 3073.
11. [11]
  (11) Heller, D. A.; Mayrhofer, R. M.; Baik, S.; Grinkova, Y. V.; Usrey, M. L.; Strano, M. S. Journal of the American Chemical Society 2004, 126, 14567. doi: 10.1021/ja046450z
12. [12]
  (12) Moshammer, K.; Hennrich, F.; Kappes, M. M. Nano Research 2009, 2, 599. doi: 10.1007/s12274-009-9057-0
13. [13]
  (13) Tanaka, T.; Urabe, Y.; Nishide, D.; Kataura, H. Applied Physics Express 2009, 2 (12).
14. [14]
  (14) Liu, H.; Feng, Y.; Tanaka, T.; Urabe, Y.; Kataura, H. Journal of Physical Chemistry C 2010, 114, 9270.
15. [15]
  (15) Liu, H. P.; Nishide, D.; Tanaka, T.; Kataura, H. Nature Communications 2011, 2, 309.
16. [16]
  (16) Gui, H.; Li, H.; Tan, F.; Jin, H.; Zhang, J.; Li, Q. Carbon 2012, 50, 332.
17. [17]
  (17) McCormick, T. J.; Foley, J. P.; Lloyd, D. K. Journal of Chromatography B-Analytical Technologies in the Biomedical and Life Sciences 2003, 785, 1. doi: 10.1016/S1570-0232(02)00756-0
18. [18]
  (18) Zhao, P.; Einarsson, E.; Xiang, R.; Murakami, Y.; Maruyama, S. Journal of Physical Chemistry C 2010, 114, 4831. doi: 10.1021/jp910959s
19. [19]
  (19) Tummala, N. R.; Striolo, A. Physical Review E 2009, 80, 021408.
20. [20]
  (20) Tummala, N. R.; Striolo, A. ACS Nano 2009, 3, 595. doi: 10.1021/nn8007756
21. [21]
  (21) O'Connell, M. J.; Bachilo, S. M.; Huffman, C. B.; Moore, V. C.; Strano, M. S.; Haroz, E. H.; Rialon, K. L.; Boul, P. J.; Noon,W. H.; Kittrell, C.; Ma, J. P.; Hauge, R. H.;Weisman, R. B.; Smalley, R. E. Science 2002, 297, 593. doi: 10.1126/science.1072631
22. [22]
  (22) Vaisman, L.;Wagner, H. D.; Marom, G. Advances in Colloid and Interface Science 2006, 128, 37.
1. [1]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
2. [2]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
3. [3]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
4. [4]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
5. [5]
  Zijuan LI , Xuan LÜ , Jiaojiao CHEN , Haiyang ZHAO , Shuo SUN , Zhiwu ZHANG , Jianlong ZHANG , Yanling MA , Jie LI , Zixian FENG , Jiahui LIU . Synthesis of visual fluorescence emission CdSe nanocrystals based on ligand regulation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 308-320. doi: 10.11862/CJIC.20240138
6. [6]
  Yang Chen , Peng Chen , Yuyang Song , Yuxue Jin , Song Wu . Application of Chemical Transformation Driven Impurity Separation in Experiments Teaching: A Novel Method for Purification of α-Fluorinated Mandelic Acid. University Chemistry, 2024, 39(6): 253-263. doi: 10.3866/PKU.DXHX202310077
7. [7]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
8. [8]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
9. [9]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001
10. [10]
  Wen Shi , Zhangwen Wei , Mei Pan , Chengyong Su . Explorations on the Course Construction of Structural Chemistry Practice and Application Targeting the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 96-100. doi: 10.12461/PKU.DXHX202409036
11. [11]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
12. [12]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
13. [13]
  Yanxin Wang , Hongjuan Wang , Yuren Shi , Yunxia Yang . Application of Python for Visualizing in Structural Chemistry Teaching. University Chemistry, 2024, 39(3): 108-117. doi: 10.3866/PKU.DXHX202306005
14. [14]
  Zhiguang Xu , Xuan Xu , Qiong Luo , Ganquan Wang , Bin Peng . Reform and Practice of Online and Offline Blended Teaching in Structural Chemistry Course. University Chemistry, 2024, 39(6): 195-200. doi: 10.3866/PKU.DXHX202310112
15. [15]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
16. [16]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
17. [17]
  Shui Hu , Houjin Li , Zhenming Zang , Lianyun Li , Rong Lai . Integration of Science and Education Promotes the Construction of Undergraduate-to-Master’s Integration Experimental Courses: A Case Study on the Extraction, Separation and Identification of Artemisinin from Artemisia annua. University Chemistry, 2024, 39(4): 314-321. doi: 10.3866/PKU.DXHX202310063
18. [18]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
19. [19]
  Haoxiang Zhang , Zhihan Zhao , Yongchen Jin , Zhiqiang Niu , Jinlei Tian . Synthesis of an Efficient Absorbent Gel: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(11): 251-258. doi: 10.12461/PKU.DXHX202401084
20. [20]
  Qingfeng Zhang , Shang-E Wei , Hua Hou , Xuan Zhao , Zixuan Yang , Lin Zhuang . Construction and Reform of the Structural Chemistry Curriculum and Textbooks under the Chemistry “101 Plan”: an In-Depth Exploration for Cultivating Top-Notch Innovative Talents. University Chemistry, 2024, 39(10): 38-44. doi: 10.12461/PKU.DXHX202409047

Get Citation

PDF

XML

Metrics

PDF Downloads(453)
Abstract views(629)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142