Citation: WANG Li-Guo, ZHANG Xiao-Dan, WANG Feng-You, WANG Ning, JIANG Yuan-Jian, HAO Qiu-Yan, XU Sheng-Zhi, WEI Chang-Chun, ZHAO Ying. Influence of Different Pyramidal Structural Morphologies of Crystalline Silicon Wafers for Surface Passivation and Heterojunction Solar Cells[J]. Acta Physico-Chimica Sinica, ;2014, 30(9): 1758-1763. doi: 10.3866/PKU.WHXB201406301 shu

Influence of Different Pyramidal Structural Morphologies of Crystalline Silicon Wafers for Surface Passivation and Heterojunction Solar Cells

1.
1. Institute of Information Functional Materials, Hebei University of Technology, Tianjin 300130, P. R. China;
2. Key Laboratory of Photo-Electronics Thin Film Devices and Technique of Tianjin, Key Laboratory of Photo-Electronic Information Science and Technology of Ministry of Education, Institute of Photo-Electronics Thin Film Devices and Technique, Nankai University, Tianjin 300071, P. R. China

Received Date: 4 June 2014
Available Online: 30 June 2014
Fund Project:

Silicon heterojunction (SHJ) solar cells consisting of a hydrogenated amorphous silicon (a-Si:H) film deposited on a crystalline silicon wafer have attracted considerable attention from the photovoltaic industry, because of their high efficiencies, high stabilities, low cost, and low-temperature fabrication. Texturing of silicon surfaces is an effective method for improving the efficiency of silicon solar cells. In this work, textured silicon substrates consisting of three different pyramidal structures were obtained using tetramethylammonium hydroxide (TMAH) solution, and used to fabricate SHJ solar cells. We investigated the influence of different pyramidal structural morphologies on the optical properties and electronic performances, to identify the optimum structure for SHJ solar cells. We obtained a standard silicon substrate with four-sided pyramidal structures using 2% (w) TMAH and 10% (w) isopropyl alcohol (IPA). In comparison with other pyramidal structures, the standard four-sided pyramidal-structured silicon substrate had the lowest reflectance, leading to an increased short-circuit current density (J_sc), and its morphology is suitable for surface passivation and SHJ solar cells.
- Texturing,
- Surface morphology of pyramids,
- Reflectance,
- Effective carrier lifetime,
- Passivation,
- Heterojunction solar cell
1. [1]
  
  (1) Baker-Finch, S. C.; McIntosh, K. R. Prog. Photovoltaics Res. Appl. 2011, 19, 406. doi: 10.1002/pip.1050
2. [2]
  (2) Terheiden, B.; Fath, P. Highly Efficient Double Side Mechanically Textured Novel Silicon Solar Cell Concepts, In Photovoltaic Energy Conversion; Proceedings of 3rdWorld Conference on IEEE, Osaka, Japan, May 11-18, 2003; pp 1443-1446.
3. [3]
  (3) Marrero, N.; nzález-Díaz, B.; Guerrero-Lemus, R.; Borchert, D. Sol. Energy Mater. Sol. Cells 2007, 91, 1943. doi: 10.1016/j.solmat.2007.08.001
4. [4]
  (4) Gan padhyay, U.; Kim, K.; Dhungel, S.; Manna, U.; Basu, P.; Banerjee, M.; Saha, H.; Yi, J. Sol. Energy Mater. Sol. Cells 2006, 90, 3557. doi: 10.1016/j.solmat.2006.06.044
5. [5]
  (5) Welcome to PV-Tech. http://www.pv-tech.org/news/back contact_hit_solar_cell _from_panasonic_pushes_efficiency_record_to_25.6 (accessed May 27, 2014)
6. [6]
  (6) Angermann, H.; Rappich, J. R.; Klimm, C. Cent. Eur. J. Phys. 2009, 7, 363. doi: 10.2478/s11534-009-0055-3
7. [7]
  (7) Angermann, H.; Henrion,W.; Rebien, M.; Röseler, A. Sol. Energy Mater. Sol. Cells 2004, 83, 331. doi: 10.1016/j.solmat.2004.01.031
8. [8]
  (8) Song, Y.; Park, M.; Guliants, E.; Anderson,W. Sol. Energy Mater. Sol. Cells 2000, 64, 225. doi: 10.1016/S0927-0248(00)00222-1
9. [9]
  (9) Mueller, T.;Wong, J.; Aberle, A. G. Energy Procedia 2012, 15, 97. doi: 10.1016/j.egypro.2012.02.012
10. [10]
  (10) Schüttauf, J.W. A.; DerWerf, C. H. M. V.; Van Sark,W. G. J. H. M.; Rath, J. K.; Schropp, R. E. I. Thin Solid Films 2011, 519, 4476. doi: 10.1016/j.tsf.2011.01.319
11. [11]
  (11) Sridharan, S.; Bhat, N.; Bhat, K. Appl. Phys. Lett. 2013, 102, 021604. doi: 10.1063/1.4776733
12. [12]
  (12) Rosa, M.; Allegrezza, M.; Canino, M.; Summonte, C.; Desalvo, A. Sol. Energy Mater. Sol. Cells 2011, 95, 2987.
13. [13]
  (13) Kang, M. G.; Tark, S.; Lee, J. C.; Son, C. S.; Kim, D. J. Cryst. Growth 2011, 326, 14. doi: 10.1016/j.jcrysgro.2011.01.042
14. [14]
  (14) Montesdeoca-Santana, A.; Jiménez-Rodríguez, E.; nzález-Díaz, B.; Borchert, D.; Guerrero-Lemus, R. Prog. Photovoltaics Res. Appl. 2012, 20, 191. doi: 10.1002/pip.1117
15. [15]
  (15) Pei, J.; Hao, Y. Z.; Sun, B.; Li, Y. P.; Fan, L. X.; Sun, S.;Wang, S. X. Acta Phys. -Chim. Sin. 2014, 30, 397. [裴娟, 郝彦忠, 孙宝, 李英品, 范龙雪, 孙硕, 王尚鑫. 物理化学学报, 2014, 30, 397.] doi: 10.3866/PKU.WHXB201401202
16. [16]
  (16) Edwards, M.; Bowden, S.; Das, U.; Burrows, M. Sol. Energy Mater. Sol. Cells 2008, 92, 1373. doi: 10.1016/j.solmat.2008.05.011
17. [17]
  (17) Fesquet, L.; Olibet, S.; Damon-Lacoste, J.; DeWolf, S.; Hessler-Wyser, A.; Monachon, C.; Ballif, C. Modification of Textured SiliconWafer Surface Morphology for Fabrication of Heterojunction Solar Cell with Open Circuit Voltage over 700 MV, Photovoltaic Specialists Conference (PVSC), 34th IEEE, Philadelphia, Pennsylvania, USA, June 7-12, 2009; pp 000754-000758.
18. [18]
  (18) Tabata, O.; Asahi, R.; Funabashi, H.; Shimaoka, K.; Sugiyama, S. Sens. Actuators A 1992, 34, 51. doi: 10.1016/0924-4247(92)80139-T
19. [19]
  (19) Sundaram, K. B.; Vijayakumar, A.; Subramanian, G. Microelectron. Eng. 2005, 77, 230. doi: 10.1016/j.mee.2004.11.004
20. [20]
  (20) Biswas, K.; Kal, S. Microelectron. J. 2006, 37, 519.
21. [21]
  (21) You, J. S.; Kim, D.; Huh, J. Y.; Park, H. J.; Pak, J. J.; Kang, C. S. Sol. Energy Mater. Sol. Cells 2001, 66, 37. doi: 10.1016/S0927-0248(00)00156-2
22. [22]
  (22) Kim, H.; Park, S.; Kang, B.; Kim, S.; Tark, S. J.; Kim, D.; Dahiwale, S. Appl. Surf. Sci. 2013, 284, 133 doi: 10.1016/j.apsusc.2013.07.051
23. [23]
  (23) Iencinella, D.; Centurioni, E.; Rizzoli, R.; Zignani, F. Sol. Energy Mater. Sol. Cells 2005, 87, 725 doi: 10.1016/j.solmat.2004.09.020
24. [24]
  (24) Zhao, Z. Y.; Zhang, X. D.;Wang, F. Y.; Jiang, Y. J.; Du, J.; Gao, H. B.; Zhao, Y.; Liu, C. C. Acta Phys. Sin. 2014, 63, 136802. [赵振越, 张晓丹, 王奉友, 姜元建, 杜建, 高海波, 赵颖, 刘彩池. 物理学报, 2014, 63, 136802.]
25. [25]
  (25) Bullis,W. M.; Huff, H. R. J. Electrochem. Soc. 1996, 143, 1399. doi: 10.1149/1.1836650
26. [26]
  (26) Angermann, H.; Conrad, E.; Korte, L.; Rappich, J.; Schulze, T. F.; Schmidt, M. Mater. Sci. Eng. B 2009, 159 -160, 219.
27. [27]
  (27) Das, U.; Burrows, M.; Lu, M.; Bowden, S.; Birkmire, R. Appl. Phys. Lett. 2008, 92, 063504. doi: 10.1063/1.2857465
28. [28]
  (28) Olibet, S.; Monachon, C.; Damon-Lacoste, J.; Ballif, C. Method for Limiting Epitaxial Growth in a Photoelectric Device with Heterojunctions and Photoelectric Device. US Pat. Appl. 20110174371A1, 2008-09-01.
29. [29]
  (29) Wang, H. P.; Lin, T. Y.; Hsu, C.W.; Tsai, M. L.; Huang, C. H.; Wei,W. R.; Huang, M. Y.; Chien, Y. J.; Yang, P. C.; Liu, C.W. ACS Nano 2013, 7, 9325. doi: 10.1021/nn404015y
30. [30]
  (30) Angermann, H.; Rappich, J.; Korte, L.; Sieber, I.; Conrad, E.; Schmidt, M.; Hübener, K.; Polte, J.; Hauschild, J. Appl. Surf. Sci. 2008, 254, 3615. doi: 10.1016/j.apsusc.2007.10.099
31. [31]
  (31) Zhang, Y.; Zhou, Y.; Jiang, Z.; Liu, F.; Zhu, M. Phys. Status Solidi C 2010, 7, 1025.
32. [32]
  (32) Angermann, H.; Korte, L.; Rappich, J.; Conrad, E.; Sieber, I.; Schmidt, M.; Hübener, K.; Hauschild, J. Thin Solid Films 2008, 516, 6775. doi: 10.1016/j.tsf.2007.12.033
1. [1]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
2. [2]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
3. [3]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
4. [4]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
5. [5]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
6. [6]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
7. [7]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
8. [8]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-. doi: 10.3866/PKU.WHXB202407021
9. [9]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
10. [10]
  Yujia Luo , Yunpeng Qi , Huiping Xing , Yuhu Li . The Use of Viscosity Method for Predicting the Life Expectancy of Xuan Paper-based Heritage Objects. University Chemistry, 2024, 39(8): 290-294. doi: 10.3866/PKU.DXHX202401037
11. [11]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
12. [12]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
13. [13]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
14. [14]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
15. [15]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
16. [16]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
17. [17]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
18. [18]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
19. [19]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
20. [20]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014

Get Citation

PDF

XML

Metrics

PDF Downloads(546)
Abstract views(750)
HTML views(34)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142