Citation: LIU Meng, LI Guo-Bao, WANG Jia-Guo, LIAO Fu-Hui, LIN Jian-Hua. Low-Temperature Synthesis of Superconductor Ba_1-xK_xBiO₃[J]. Acta Physico-Chimica Sinica, ;2014, 30(9): 1611-1615. doi: 10.3866/PKU.WHXB201406201 shu

Low-Temperature Synthesis of Superconductor Ba_1-xK_xBiO₃

1.
1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, Zhejiang Province, P. R. China;
2. Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 8 April 2014
Available Online: 20 June 2014
Fund Project:

Ba_1-xK_xBiO₃ (BKBO) was synthesized using a topotactic reaction, which involves a conventional solidstate synthesis of pure BaBiO₃, using BaCO₃ and Bi₂O₃ as the raw materials, and subsequent treatment of BaBiO₃ in a KOH flux at low temperature. All samples were characterized using X-ray diffraction (XRD) and magnetic susceptibility measurements. The XRD patterns show that there is no apparent impurity in the obtained Ba_1-xK_xBiO₃ samples, and all the diffraction data can be indexed using a pseudo-cubic cell. All the samples showed superconductivity, and the highest superconducting transition temperature (T_c) was 30.6 K. The influences of the reaction time and the ratio of the precursor to the molten salts on the transition temperature were investigated. The best reaction conditions were treatment at 450 ℃ for 4 h, with BaBiO₃:KOH:KF mass ratio of 1:5:2.5.
- Ba_1-xK_xBiO₃,
- X-ray diffraction,
- Bismuthate superconductor,
- Topotactic reaction
1. [1]
  
  (1) Cava, R. J.; Batlogg, B.; Krajewski, J. J.; Farrow, R.; Rupp, L. W., Jr.; White, A. E.; Short, K.; Peck,W. F.; Kometani, T. Nature 1988, 332, 814. doi: 10.1038/332814a0
2. [2]
  (2) Park, C.; Snyder, R. L. J. Am. Ceram. Soc. 1995, 78, 3171. doi: 10.1111/jace.1995.78.issue-12
3. [3]
  (3) Shaikh, F. I.; Kalubarme, R. S.; Pawar, S. H. Applied Surface Science 2008, 254, 5772. doi: 10.1016/j.apsusc.2008.03.143
4. [4]
  (4) Hinks, D. G.; Dabrowski, B.; Jorgensen, J. D.; Mitchell, A.W.; Richards, D. R.; Pei, S.; Shi, D. Nature 1988, 333, 836. doi: 10.1038/333836a0
5. [5]
  (5) Kim, D. C.; Baranov, A. N.; Kim, J. S.; Kang, H. R.; Kim, B. J.; Kim, Y. C.; Pshirkov, J. S.; Antipov, E. V.; Park, Y.W. Journal of Superconductivity 2002, 15, 331. doi: 10.1023/A:1021009927768
6. [6]
  (6) Kim, D. C.; Baranov, A. N.; Kim, J. S.; Kang, H. R.; Kim, B. J.; Kim, Y. C.; Pshirkov, J. S.; Antipov, E. V.; Park, Y.W. Physica C 2003, 383, 343. doi: 10.1016/S0921-4534(02)01332-1
7. [7]
  (7) Shiryaey, S. V.; Barilo, S. N.; Ustinovich, S. N.; Fedotova, V. V.; Gatalskaya, V. I.; Szymczak, H.; Szymczak, R.; Baran, M. J. Cryst. Growth 2000, 211, 471. doi: 10.1016/S0022-0248(99)00766-6
8. [8]
  (8) Zhang, G. H.; Li, G. B.; Huang, F. Q.; Liao, F. H.; Li, K.;Wang, Y. X.; Lin, J. H. J. Alloy. Compd. 2011, 509, 9804. doi: 10.1016/j.jallcom.2011.08.031
9. [9]
  (9) Cui, Y. J.; Chen, Y. L.;Wang, F. S.; Li, J.; Zhang, Y.; Zhao, Y. Rare Metal Materials and Engineering 2009, 38, 583. doi: 10.1016/S1875-5372(10)60030-6
10. [10]
  (10) Liu, S. F.; Fu,W. T. Mater. Res. Bull. 2001, 36, 1505. doi: 10.1016/S0025-5408(01)00609-2
11. [11]
  (11) Chen, Y. L.; Cui, Y. J.; Yang, Y.; Zhang, Y.; Zhao, Y. Physica C 2011, 471, 704. doi: 10.1016/j.physc.2011.05.032
12. [12]
  (12) Kohler, J. Angew. Chem. Int. Edit. 2001, 40, 2435.(13) Nagata, Y.; Mishiro, A.; Uchida, T.; Ohtsuka, M.; Samata, H. J. Phys. Chem. Solids 1999, 60, 1933. doi: 10.1016/S0022-3697(99)00217-6
13. [13]
  (14) Sleight, A.W.; Gillson, J. L.; Bierstedt, P. E. Solid State Commun. 1975, 17, 27. doi: 10.1016/0038-1098(75)90327-0
14. [14]
  (15) Wignacourt, J. P.; Swinnea, J. S.; Steinfink, H.; odenough, J. B. Appl. Phys. Lett. 1988, 53, 1753. doi: 10.1063/1.100430
15. [15]
  (16) Cui, Y. J. Molten Salt Technique Preparation of Bismuthate Superconductors and Researches on the Doping Effect. Ph. D. Dissertation, Southwest Jiaotong University, Sichuan, 2009. [崔雅静. 铋酸盐超导体的熔盐制备技术以及掺杂效应的研究 [D]. 成都: 西南交通大学, 2009.](17) Guner, S. B.; rur, O.; Celik, S.; Dogruer, M.; Yildirim, G.; Varilci, A.; Terzioglu, C. J. Alloy. Compd. 2012, 540, 260. doi: 10.1016/j.jallcom.2012.06.082
16. [16]
  (18) Sagsoz, M. E.; Ertugrul, M.; Cevik, U. Mater. Lett. 2006, 60, 1778. doi: 10.1016/j.matlet.2005.12.020
17. [17]
  (19) Liu, X. Y.; Huang, Y.; Zeng, Z. M. Materials Science and Engineering Journal 2003, 21, 104. [刘心宇, 黄蛹, 曾中明. 材料科学与工程学报, 2003, 21, 104.](20) Cui, Y. J.; Chen, Y. L.; Zhang, Y.; Zhao, Y. Journal of Low Temperature Physics 2008, 30, 129. [崔雅静, 陈永亮, 张勇, 赵勇. 低温物理学报, 2008, 30, 129.](21) Hiramatsu, H.; Katase, T.; Kamiya, T.; Hirano, M.; Hosono, H. Appl. Phys. Lett. 2008, 93, 162504. doi: 10.1063/1.2996591
18. [18]
  (22) Yang, C. X.; Ju, J.; Zhao, S. D.; Xu, H. Y.; Liu, M.; Liao, F. H.; Li, G. B.; Lin, J. H. Acta Phys. -Chim. Sin. 2013, 29, 2661. [杨承旭, 鞠晶, 赵世迪, 徐航宇, 刘孟, 廖复辉, 李国宝, 林建华. 物理化学学报, 2013, 29, 2661.] doi: 10.3866/PKU.WHXB201310151
19. [19]
  (23) Zhang, K. L.; Sun, J. T.; Yuan, L. J. Inorganic Synthesis Chemistry;Wuhan University Press:Wuhan, 2004; pp 134-139. [张克立, 孙聚堂, 袁良杰. 无机合成化学. 武汉: 武汉大学出版社, 2004: 134-139.](24) Wang, H.;Wang, C. H.; Li, G. B.; Jin, T. N.; Liao, F. H.; Lin, J. H. Inorg. Chem. 2010, 49, 5262. doi: 10.1021/ic100361y
20. [20]
  (25) Pei, S.; Jorgensen, J. D.; Dabrowki, B.; Hinks, D. G.; Richards, D. R.; Mitchel, A.W.; Newsam, J. M.; Sinha, S. K.; Vaknin, D.; Jacobson, A. J. Phys. Rev. B 1990, 41, 4126. doi: 10.1103/PhysRevB.41.4126
1. [1]
  Wei Li , Guoqiang Feng , Ze Chang . Teaching Reform of X-ray Diffraction Using Synchrotron Radiation in Materials Chemistry. University Chemistry, 2024, 39(3): 29-35. doi: 10.3866/PKU.DXHX202308060
2. [2]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
3. [3]
  Danqing Wu , Jiajun Liu , Tianyu Li , Dazhen Xu , Zhiwei Miao . Research Progress on the Simultaneous Construction of C—O and C—X Bonds via 1,2-Difunctionalization of Olefins through Radical Pathways. University Chemistry, 2024, 39(11): 146-157. doi: 10.12461/PKU.DXHX202403087
4. [4]
  Hongwei Ma , Fang Zhang , Hui Ai , Niu Zhang , Shaochun Peng , Hui Li . Integrated Crystallographic Teaching with X-ray,TEM and STM. University Chemistry, 2024, 39(3): 5-17. doi: 10.3866/PKU.DXHX202308107
5. [5]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
6. [6]
  Yuqiao Zhou , Weidi Cao , Shunxi Dong , Lili Lin , Xiaohua Liu . Study on the Teaching Reformation of Practical X-ray Crystallography. University Chemistry, 2024, 39(3): 23-28. doi: 10.3866/PKU.DXHX202303003
7. [7]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
8. [8]
  Keke Han , Wenjun Rao , Xiuli You , Haina Zhang , Xing Ye , Zhenhong Wei , Hu Cai . Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO₄⁻, ReO₄⁻). Chinese Chemical Letters, 2024, 35(6): 108809-. doi: 10.1016/j.cclet.2023.108809
9. [9]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
10. [10]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
11. [11]
  Fei Yin , Erli Yang , Xue Ge , Qian Sun , Fan Mo , Guoqiu Wu , Yanfei Shen . Coupling WO₃₋_x dots-encapsulated metal-organic frameworks and template-free branched polymerization for dual signal-amplified electrochemiluminescence biosensing. Chinese Chemical Letters, 2024, 35(4): 108753-. doi: 10.1016/j.cclet.2023.108753
12. [12]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
13. [13]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
14. [14]
  Wentao Lin , Wenfeng Wang , Yaofeng Yuan , Chunfa Xu . Concerted Nucleophilic Aromatic Substitution Reactions. University Chemistry, 2024, 39(6): 226-230. doi: 10.3866/PKU.DXHX202310095
15. [15]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
16. [16]
  Yuting Zhang , Zhiqian Wang . Methods and Case Studies for In-Depth Learning of the Aldol Reaction Based on Its Reversible Nature. University Chemistry, 2024, 39(7): 377-380. doi: 10.3866/PKU.DXHX202311037
17. [17]
  Ruitong Zhang , Zhiqiang Zeng , Xiaoguang Zhang . Improvement of Ethyl Acetate Saponification Reaction and Iodine Clock Reaction Experiments. University Chemistry, 2024, 39(8): 197-203. doi: 10.3866/PKU.DXHX202312004
18. [18]
  Yuan Chun , Lijun Yang , Jinyue Yang , Wei Gao . Ideological and Political Design of BZ Oscillatory Reaction Experiment. University Chemistry, 2024, 39(2): 72-76. doi: 10.3866/PKU.DXHX202308072
19. [19]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
20. [20]
  Rong-Nan Yi , Wei-Min He . Photocatalytic Minisci-type multicomponent reaction for the synthesis of 1-(halo)alkyl-3-heteroaryl bicyclo[1.1.1]pentanes. Chinese Chemical Letters, 2024, 35(10): 110115-. doi: 10.1016/j.cclet.2024.110115

Get Citation

PDF

XML

Metrics

PDF Downloads(722)
Abstract views(783)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Low-Temperature Synthesis of Superconductor Ba1-xKxBiO3

Metrics

通讯作者: 陈斌, bchen63@163.com

Low-Temperature Synthesis of Superconductor Ba_1-xK_xBiO₃