Citation: ZHOU Xin-Wen, DU Juan-Juan, SUN Shi-Gang. Anomalous IR Optical Properties of Monodispersed PtNi Nanoparticles[J]. Acta Physico-Chimica Sinica, ;2014, 30(9): 1681-1687. doi: 10.3866/PKU.WHXB201406193 shu

Anomalous IR Optical Properties of Monodispersed PtNi Nanoparticles

1.
1. College of Biological and Pharmaceutical Science, China Three rges University, Yichang 443002, Hubei Province, P. R. China;
2. Department of Chemistry, College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surface, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 12 May 2014
Available Online: 19 June 2014
Fund Project:

Monodispersed PtNi nanoparticles were synthesized by galvanic displacement reaction and chemical reduction. The monodispersed PtNi nanoparticles demonstrate, by cyclic voltammetry, enhanced electrocatalytic properties for CO oxidation in 0.1 mol·L^-1 H₂SO₄ solution compared with bulk Pt electrode. In situ electrochemical Fourier transform infrared (FTIR) spectroscopy using CO as the probe molecule was studied. The CO adsorbed on either the PtNi/GC (glassy carbon) electrode or PtNi/Au electrode exhibits characteristics of a symmetric bipolar IR feature with a strong enhancement factor. The results of this paper contribute to the understanding of the special properties and origin of the anomalous IR properties of lowdimensional nanomaterials.
- Galvanic displacement reaction,
- Monodispersed PtNi nanoparticle,
- Bipolar IR feature,
- In situ electrochemical FTIR spectroscopy
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