Citation: LI Shan-Shan, XIA Hai-Ping, FU Li, DONG Yan-Ming, ZHANG Jia-Zhong, GU Xue-Mei, ZHANG Jian-Li, WANG Dong-Jie, JIANG Hao-Chuan, CHEN Bao-Jiu. Fluorescent Emissions (1800 nm) of LiLuF₄ Single Crystals Doped with Various Tm³⁺ Concentrations[J]. Acta Physico-Chimica Sinica, ;2014, 30(9): 1752-1757. doi: 10.3866/PKU.WHXB201406183 shu

Fluorescent Emissions (1800 nm) of LiLuF₄ Single Crystals Doped with Various Tm³⁺ Concentrations

1.
1. Key Laboratory of Photo-electronic Materials, Ningbo University, Ningbo 315211, Zhejiang Province, P. R. China;
2. Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315211, Zhejiang Province, P. R. China;
3. Department of Physics, Dalian Maritime University, Dalian 116026, Liaoning Province, P. R. China

Received Date: 8 May 2014
Available Online: 18 June 2014
Fund Project:

LiLuF₄ single crystals doped with molar fractions of 0.45%, 0.90%, 1.63%, and 3.25% (x, molar fraction) Tm³⁺ ions were fabricated by an improved Bridgman method. Absorption spectra in the 400-2000 nm region of the crystals were measured. The emissions from 1400 to 2000 nm under excitation of an 808-nm laser diode (LD) were carried out and compared. Two emission bands at 1470 and 1800 nm were observed. First, the emission intensity at 1800 nm increased with the increase in Tm³⁺ concentration, reaching a maximum value when the Tm³⁺ concentration was ca 0.90%. Thereafter, it decreased considerably as the Tm³⁺ doping levels further increased to 3.25%. However, the emission intensity at 1470 nm showed the contrary tendency to that at 1800 nm. It was found that the 1800-nm emission lifetime of the Tm³⁺:³F₄ manifold systematically decreased with an increase in Tm³⁺ concentration. The trend in the fluorescent intensity change can be explained by the cross-relaxation (³H₆, ³H₄→³F₄, ³F₄) between the Tm³⁺ ions and the concentration quenching effect of Tm³⁺. Meanwhile, the emission cross-section was calculated, providing a maximum of 0.392×10^-20 cm² at 1890 nm for the 0.90% doped sample. Based on the measured lifetime and calculated radiative lifetime, the largest quantum efficiency between Tm³⁺ ions reached ~120%.
- Tm³⁺-doped LiLuF₄ crystal,
- Cross-relaxation,
- Fluorescent intensity,
- Concentration quenching
1. [1]
  
  (1) Jackson, S. D.; Sabella, A.; Lancaster, D. G. IEEE J. Sel. Topics Quant. Electr. 2007, 13, 567. doi: 10.1109/JSTQE.2007.896087
2. [2]
  (2) Jackson, S. D. Laser Photon Rev. 2009, 3, 466. doi: 10.1002/lpor.v3:5
3. [3]
  (3) Zhang, Z.; Shen, D. Y.; Boyland, A. J.; Sahu, J. K.; Clarkson,W. A.; Ibsen, M. Opt. Lett. 2008, 33, 2059. doi: 10.1364/OL.33.002059
4. [4]
  (4) Hu, H. Y.;Wan, Y. T.; Hu, J. X.; Xia, H. P.; Zhang, Y. P.; Chen, H. B. Chinese Journal of Luminescence 2012, 33, 377. [胡皓阳, 万云涛, 胡建旭, 夏海平, 张约品, 陈红兵. 发光学报, 2012, 33, 377.]
5. [5]
  (5) Li, C.; Zhang, Y.; Zhang, X. J.; Zeng, F. M.; Mauro, T.; Liu, J. H. Journal of Rare Earths 2011, 29, 592. doi: 10.1016/S1002-0721(10)60503-0
6. [6]
  (6) Elder, I. F.; Payne, M. J. P. Opt. Commun. 1998, 148, 265. doi: 10.1016/S0030-4018(97)00714-1
7. [7]
  (7) So, S.; MacKenzie, J. I.; Shepherd, D. P.; Clarkson,W. A.; Betterton, J. G.; rton, E. K. Appl. Phys. B 2006, 84, 389. doi: 10.1007/s00340-006-2286-y
8. [8]
  (8) Lai, K. S.; Phua, P. B.;Wu, R. F.; Lim, Y. L.; Lau, E. S.; Toh, W.; Toh, B. T.; Chng, A. Opt. Lett. 2000, 25, 1591. doi: 10.1364/OL.25.001591
9. [9]
  (9) Duan, X. M.; Yao, B. Q.; Zhang, Y. J.; Song, C.W.; Zheng, L. L.; Ju, Y. L.;Wang, Y. Z. Laser Phys. Lett. 2008, 5, 347. doi: 10.1002/lapl.200810002
10. [10]
  (10) Zhao, G. Y.; Tian, Y.;Wang, X.; Fan, H. Y.; Hu, L. L. J. Lumin. 2013, 134, 837. doi: 10.1016/j.jlumin.2012.06.040
11. [11]
  (11) Zhang, Z. H.; Ren, J.; Yan, Q. Q.; Chen, G. R. J. Non-Cryst. Solids 2014, 383, 209. doi: 10.1016/j.jnoncrysol.2013.05.021
12. [12]
  (12) Fang, Y. Z.; Zhao, G. Y.; Xu, J. Y.; Zhang, N.; Ma, Z. F.; Hu, L. L. Ceram. Int. 2014, 40, 6037. doi: 10.1016/j.ceramint.2013.11.053
13. [13]
  (13) Ranieri, I. M.; Shimamura, K.; Nakano, K.; Fujita, T.; Liu, Z.; Sarukura, N.; Fukuda, T. J. Cryst. Growth 2000, 217, 151. doi: 10.1016/S0022-0248(00)00474-7
14. [14]
  (14) Dexter, D. L. J. Chem. Phys. 1953, 21, 836. doi: 10.1063/1.1699044
15. [15]
  (15) Walsh, B. M.; Barnes, N. P.; Reichle, D. J.; Jiang, S. J. Non-Cryst. Solids 2006, 352, 5344. doi: 10.1016/j.jnoncrysol.2006.08.029
16. [16]
  (16) Hu, J. X.; Xia, H. P.; Hu, H. Y.; Zhang, Y. P.; Jiang, H. C.; Chen, B. J. J. Appl. Phys. 2012, 112, 073518. doi: 10.1063/1.4757925
17. [17]
  (17) Tang, L.; Xia, H. P.;Wang, P. P.; Peng, J. T.; Zhang, Y. P.; Jiang, H. C.; Chen, B. J. Mater. Lett. 2013, 104, 37.
18. [18]
  (18) Yuan, J. H.; Cheng, Y. M.; Zhang, Z. H. Acta Phys. -Chim. Sin. 2005, 21, 1059. [袁剑辉, 程玉民, 张振华. 物理化学学报, 2005, 21, 1059.] doi: 10.3866/PKU.WHXB20050923
19. [19]
  (19) Xiong, J.; Peng, H. Y.; Hu, P. C.; Yin, H. G.; Zhang, L. H. J. Phys. D: Appl. Phys. 2010, 43, 185402. doi: 10.1088/0022-3727/43/18/185402
20. [20]
  (20) Liu,W. P.; Zhang, Q. L.; Sun, D. L.; Luo, J. Q.; Gu, C. J.; Jiang, H. H.; Yin, S. T. J. Cryst. Growth 2011, 331, 83.
21. [21]
  (21) Luo, Z. D.; Chen, X.Y.; Zhao, T. J. Opt. Commun. 1997, 134, 415. doi: 10.1016/S0030-4018(96)00386-0
22. [22]
  (22) Barnes, N. P.; Gettemy, D. J. J. Opt. Soc. Am. 1980, 70, 1244. doi: 10.1364/JOSA.70.001244
23. [23]
  (23) Tsuboi, T.; Murayama, H.; Shimamura, K. J. Alloy. Compd. 2006, 408 -412, 776.
24. [24]
  (24) Peng, B.; Izumitani, T. Opt. Mater. 1995, 4, 797. doi: 10.1016/0925-3467(95)00032-1
25. [25]
  (25) Walsh, B. M.; Barnes, N. P.; Bartolo, B. D. J. Appl. Phys. 1998, 83, 2772. doi: 10.1063/1.367037A
1. [1]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
2. [2]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
3. [3]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
4. [4]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
5. [5]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
6. [6]
  Jiajun Wang , Guolin Yi , Shengling Guo , Jianing Wang , Shujuan Li , Ke Xu , Weiyi Wang , Shulai Lei . Computational design of bimetallic TM₂@g-C₉N₄ electrocatalysts for enhanced CO reduction toward C₂ products. Chinese Chemical Letters, 2024, 35(7): 109050-. doi: 10.1016/j.cclet.2023.109050
7. [7]
  Cunling Ye , Xitong Zhao , Hongfang Wang , Zhike Wang . A Formula for the Calculation of Complex Concentrations Arising from Side Reactions and Its Applications. University Chemistry, 2024, 39(4): 382-386. doi: 10.3866/PKU.DXHX202310043
8. [8]
  Ruilin Han , Xiaoqi Yan . Comparison of Multiple Function Methods for Fitting Surface Tension and Concentration Curves. University Chemistry, 2024, 39(7): 381-385. doi: 10.3866/PKU.DXHX202311023
9. [9]
  Qun Wang , Yang Li , Songtao Lu , Hongjun Kang , Yang Hong , Xiaohong Wu . Exploration for the Chemistry Innovative Talent Cultivation from an Interdisciplinary Perspective. University Chemistry, 2024, 39(8): 132-135. doi: 10.3866/PKU.DXHX202401052
10. [10]
  Yuping Wei , Yiting Wang , Jialiang Jiang , Jinxuan Deng , Hong Zhang , Xiaofei Ma , Junjie Li . Interdisciplinary Teaching Practice——Flexible Wearable Electronic Skin for Low-Temperature Environments. University Chemistry, 2024, 39(10): 261-270. doi: 10.12461/PKU.DXHX202404007
11. [11]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
12. [12]
  Luhong Chen , Yan Zhang . Chem&Bio Interdisciplinary Graduates Training in Nanjing University Promoted by Chemistry and Biomedicine Innovation Center. University Chemistry, 2024, 39(6): 12-16. doi: 10.3866/PKU.DXHX202311089
13. [13]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
14. [14]
  Ling Zhang , Jing Kang . Turn Waste into Valuable: Preparation of High-Strength Water-Based Adhesives from Polymethylmethacrylate Wastes: a Comprehensive Chemical Experiments. University Chemistry, 2024, 39(2): 221-226. doi: 10.3866/PKU.DXHX202306075
15. [15]
  Xinyu Liu , Weiran Hu , Zhengkai Li , Wei Ji , Xiao Ni . Algin Lab: Surging Luminescent Sea. University Chemistry, 2024, 39(5): 396-404. doi: 10.3866/PKU.DXHX202312021
16. [16]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
17. [17]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
18. [18]
  Chun-Lin Sun , Yaole Jiang , Yu Chen , Rongjing Guo , Yongwen Shen , Xinping Hui , Baoxin Zhang , Xiaobo Pan . Construction, Performance Testing, and Practical Applications of a Home-Made Open Fluorescence Spectrometer. University Chemistry, 2024, 39(5): 287-295. doi: 10.3866/PKU.DXHX202311096
19. [19]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
20. [20]
  Zishuo Yi , Peng Liu , Yan Xu . Fluorescent “Chameleon”: A Popular Science Experiment Based on Dynamic Luminescence. University Chemistry, 2024, 39(9): 304-310. doi: 10.12461/PKU.DXHX202311079

Get Citation

PDF

XML

Metrics

PDF Downloads(375)
Abstract views(480)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fluorescent Emissions (1800 nm) of LiLuF4 Single Crystals Doped with Various Tm3+ Concentrations

Metrics

通讯作者: 陈斌, bchen63@163.com

Fluorescent Emissions (1800 nm) of LiLuF₄ Single Crystals Doped with Various Tm³⁺ Concentrations