Citation: LI Shan-Shan, XIA Hai-Ping, FU Li, DONG Yan-Ming, ZHANG Jia-Zhong, GU Xue-Mei, ZHANG Jian-Li, WANG Dong-Jie, JIANG Hao-Chuan, CHEN Bao-Jiu. Fluorescent Emissions (1800 nm) of LiLuF₄ Single Crystals Doped with Various Tm³⁺ Concentrations[J]. Acta Physico-Chimica Sinica, ;2014, 30(9): 1752-1757. doi: 10.3866/PKU.WHXB201406183 shu

Fluorescent Emissions (1800 nm) of LiLuF₄ Single Crystals Doped with Various Tm³⁺ Concentrations

1.
1. Key Laboratory of Photo-electronic Materials, Ningbo University, Ningbo 315211, Zhejiang Province, P. R. China;
2. Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315211, Zhejiang Province, P. R. China;
3. Department of Physics, Dalian Maritime University, Dalian 116026, Liaoning Province, P. R. China

Received Date: 8 May 2014
Available Online: 18 June 2014
Fund Project:

LiLuF₄ single crystals doped with molar fractions of 0.45%, 0.90%, 1.63%, and 3.25% (x, molar fraction) Tm³⁺ ions were fabricated by an improved Bridgman method. Absorption spectra in the 400-2000 nm region of the crystals were measured. The emissions from 1400 to 2000 nm under excitation of an 808-nm laser diode (LD) were carried out and compared. Two emission bands at 1470 and 1800 nm were observed. First, the emission intensity at 1800 nm increased with the increase in Tm³⁺ concentration, reaching a maximum value when the Tm³⁺ concentration was ca 0.90%. Thereafter, it decreased considerably as the Tm³⁺ doping levels further increased to 3.25%. However, the emission intensity at 1470 nm showed the contrary tendency to that at 1800 nm. It was found that the 1800-nm emission lifetime of the Tm³⁺:³F₄ manifold systematically decreased with an increase in Tm³⁺ concentration. The trend in the fluorescent intensity change can be explained by the cross-relaxation (³H₆, ³H₄→³F₄, ³F₄) between the Tm³⁺ ions and the concentration quenching effect of Tm³⁺. Meanwhile, the emission cross-section was calculated, providing a maximum of 0.392×10^-20 cm² at 1890 nm for the 0.90% doped sample. Based on the measured lifetime and calculated radiative lifetime, the largest quantum efficiency between Tm³⁺ ions reached ~120%.
- Tm³⁺-doped LiLuF₄ crystal,
- Cross-relaxation,
- Fluorescent intensity,
- Concentration quenching
1. [1]
  
  (1) Jackson, S. D.; Sabella, A.; Lancaster, D. G. IEEE J. Sel. Topics Quant. Electr. 2007, 13, 567. doi: 10.1109/JSTQE.2007.896087
2. [2]
  (2) Jackson, S. D. Laser Photon Rev. 2009, 3, 466. doi: 10.1002/lpor.v3:5
3. [3]
  (3) Zhang, Z.; Shen, D. Y.; Boyland, A. J.; Sahu, J. K.; Clarkson,W. A.; Ibsen, M. Opt. Lett. 2008, 33, 2059. doi: 10.1364/OL.33.002059
4. [4]
  (4) Hu, H. Y.;Wan, Y. T.; Hu, J. X.; Xia, H. P.; Zhang, Y. P.; Chen, H. B. Chinese Journal of Luminescence 2012, 33, 377. [胡皓阳, 万云涛, 胡建旭, 夏海平, 张约品, 陈红兵. 发光学报, 2012, 33, 377.]
5. [5]
  (5) Li, C.; Zhang, Y.; Zhang, X. J.; Zeng, F. M.; Mauro, T.; Liu, J. H. Journal of Rare Earths 2011, 29, 592. doi: 10.1016/S1002-0721(10)60503-0
6. [6]
  (6) Elder, I. F.; Payne, M. J. P. Opt. Commun. 1998, 148, 265. doi: 10.1016/S0030-4018(97)00714-1
7. [7]
  (7) So, S.; MacKenzie, J. I.; Shepherd, D. P.; Clarkson,W. A.; Betterton, J. G.; rton, E. K. Appl. Phys. B 2006, 84, 389. doi: 10.1007/s00340-006-2286-y
8. [8]
  (8) Lai, K. S.; Phua, P. B.;Wu, R. F.; Lim, Y. L.; Lau, E. S.; Toh, W.; Toh, B. T.; Chng, A. Opt. Lett. 2000, 25, 1591. doi: 10.1364/OL.25.001591
9. [9]
  (9) Duan, X. M.; Yao, B. Q.; Zhang, Y. J.; Song, C.W.; Zheng, L. L.; Ju, Y. L.;Wang, Y. Z. Laser Phys. Lett. 2008, 5, 347. doi: 10.1002/lapl.200810002
10. [10]
  (10) Zhao, G. Y.; Tian, Y.;Wang, X.; Fan, H. Y.; Hu, L. L. J. Lumin. 2013, 134, 837. doi: 10.1016/j.jlumin.2012.06.040
11. [11]
  (11) Zhang, Z. H.; Ren, J.; Yan, Q. Q.; Chen, G. R. J. Non-Cryst. Solids 2014, 383, 209. doi: 10.1016/j.jnoncrysol.2013.05.021
12. [12]
  (12) Fang, Y. Z.; Zhao, G. Y.; Xu, J. Y.; Zhang, N.; Ma, Z. F.; Hu, L. L. Ceram. Int. 2014, 40, 6037. doi: 10.1016/j.ceramint.2013.11.053
13. [13]
  (13) Ranieri, I. M.; Shimamura, K.; Nakano, K.; Fujita, T.; Liu, Z.; Sarukura, N.; Fukuda, T. J. Cryst. Growth 2000, 217, 151. doi: 10.1016/S0022-0248(00)00474-7
14. [14]
  (14) Dexter, D. L. J. Chem. Phys. 1953, 21, 836. doi: 10.1063/1.1699044
15. [15]
  (15) Walsh, B. M.; Barnes, N. P.; Reichle, D. J.; Jiang, S. J. Non-Cryst. Solids 2006, 352, 5344. doi: 10.1016/j.jnoncrysol.2006.08.029
16. [16]
  (16) Hu, J. X.; Xia, H. P.; Hu, H. Y.; Zhang, Y. P.; Jiang, H. C.; Chen, B. J. J. Appl. Phys. 2012, 112, 073518. doi: 10.1063/1.4757925
17. [17]
  (17) Tang, L.; Xia, H. P.;Wang, P. P.; Peng, J. T.; Zhang, Y. P.; Jiang, H. C.; Chen, B. J. Mater. Lett. 2013, 104, 37.
18. [18]
  (18) Yuan, J. H.; Cheng, Y. M.; Zhang, Z. H. Acta Phys. -Chim. Sin. 2005, 21, 1059. [袁剑辉, 程玉民, 张振华. 物理化学学报, 2005, 21, 1059.] doi: 10.3866/PKU.WHXB20050923
19. [19]
  (19) Xiong, J.; Peng, H. Y.; Hu, P. C.; Yin, H. G.; Zhang, L. H. J. Phys. D: Appl. Phys. 2010, 43, 185402. doi: 10.1088/0022-3727/43/18/185402
20. [20]
  (20) Liu,W. P.; Zhang, Q. L.; Sun, D. L.; Luo, J. Q.; Gu, C. J.; Jiang, H. H.; Yin, S. T. J. Cryst. Growth 2011, 331, 83.
21. [21]
  (21) Luo, Z. D.; Chen, X.Y.; Zhao, T. J. Opt. Commun. 1997, 134, 415. doi: 10.1016/S0030-4018(96)00386-0
22. [22]
  (22) Barnes, N. P.; Gettemy, D. J. J. Opt. Soc. Am. 1980, 70, 1244. doi: 10.1364/JOSA.70.001244
23. [23]
  (23) Tsuboi, T.; Murayama, H.; Shimamura, K. J. Alloy. Compd. 2006, 408 -412, 776.
24. [24]
  (24) Peng, B.; Izumitani, T. Opt. Mater. 1995, 4, 797. doi: 10.1016/0925-3467(95)00032-1
25. [25]
  (25) Walsh, B. M.; Barnes, N. P.; Bartolo, B. D. J. Appl. Phys. 1998, 83, 2772. doi: 10.1063/1.367037A
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Fluorescent Emissions (1800 nm) of LiLuF4 Single Crystals Doped with Various Tm3+ Concentrations

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Fluorescent Emissions (1800 nm) of LiLuF₄ Single Crystals Doped with Various Tm³⁺ Concentrations