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Citation: LIU Jian-Hua, LIU Bin-Hong, LI Zhou-Peng. Fe3O4/Graphene Composites with a Porous 3D Network Structure Synthesized through Self-Assembly under Electrostatic Interactions as Anode Materials of High-Performance Li-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2014, 30(9): 1650-1658. doi: 10.3866/PKU.WHXB201406181 shu

Fe3O4/Graphene Composites with a Porous 3D Network Structure Synthesized through Self-Assembly under Electrostatic Interactions as Anode Materials of High-Performance Li-Ion Batteries

  • 1.

    1. Depatment of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, P. R. China;
    2. Department of Chemical & Biological Engineering, Zhejiang University, Hangzhou 310027, P. R. China

  • Received Date: 27 March 2014
    Available Online: 18 June 2014

    Fund Project:

  • Fe3O4/graphene composites with a conductive, porous three-dimensional (3D) graphene network were synthesized through a facile method. In the preparation process, Fe(OH)3 colloid was formed in situ by adding FeCl3 solution to a boiling graphene oxide ( ) suspension, with Fe(OH)3/ precipitated because of the electrostatic interaction between the two components. The precipitate was separated and added to a second suspension to achieve additional encapsulation. This self-assembled Fe(OH)3/ precursor was then hydrothermally and heat treated, resulting in the formation of Fe3O4/graphene composites. X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and Raman spectroscopy results revealed that the Fe3O4/graphene composites possess a favorable 3D porous graphene network embedding 50- to 100-nm-sized Fe3O4 nanoparticles. The Fe3O4/graphene composites exhibit od electrochemical performance as an anode material for Li-ion batteries. The electrode composed of the Fe3O4/graphene composite delivered a capacity of 1390 mAh·g-1 for the first lithiation and retained a capacity of 819 mAh·g-1 after 50 cycles. The electrodes also exhibited od rate capability. The present results demonstrate that the electrochemical performance of the Fe3O4/graphene composite is highly sensitive to its preparation procedure and to the resulting nanostructure. Each of the four preparation procedures was experimentally shown to be important for achieving the final nanostructure and od electrochemical performance. A formation mechanism for the Fe3O4/graphene composite is also proposed.

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    1. [1]

      (1) Tarascon, J. M.; Armand, M. Nature 2001, 414, 359. doi: 10.1038/35104644

    2. [2]

      (2) Armand, M.; Tarascon, J. M. Nature 2008, 451, 652. doi: 10.1038/451652a

    3. [3]

      (3) odenough, J. B.; Kim, Y. Chem. Mater. 2010, 22, 587. doi: 10.1021/cm901452z

    4. [4]

      (4) Gao, B.; Sinha, S.; Fleming, L.; Zhou, O. Adv. Mater. 2001, 13, 816. doi: 10.1002/1521-4095(200106)13:11<816::AIDADMA816>3.0.CO;2-P

    5. [5]

      (5) Lee, K. T.; Jung, Y. S.; Oh, S. M. J. Am. Chem. Soc. 2003, 125, 5652. doi: 10.1021/ja0345524

    6. [6]

      (6) Poizot, P.; Laruelle, S.; Grugeon, S.; Dupont, L.; Tarascon, J. M. Nature 2000, 407, 496. doi: 10.1038/35035045

    7. [7]

      (7) Park, C. M.; Kim, J. H.; Kim, H.; Sohn, H. J. Chem. Soc. Rev. 2010, 39, 3115. doi: 10.1039/b919877f

    8. [8]

      (8) Cabana, J.; Monconduit, L.; Larcher, D.; Palacin, M. R. Adv. Mater. 2010, 22, E170.

    9. [9]

      (9) Ji, L.W.; Lin, Z.; Alcoutlabi, M.; Zhang, X.W. Energy Environ. Sci. 2011, 4, 2683.

    10. [10]

      (10) Zhang, L. S.; Jiang, L. Y.; Yan, H. J.;Wang,W. D.;Wang,W.; Song,W. G.; Guo, Y. G.;Wan, L. J. J. Mater. Chem. 2010, 20, 5462. doi: 10.1039/c0jm00672f

    11. [11]

      (11) Chen, J.; Huang, K. L.; Liu, S. Q. Chin. J. Inorg. Chem. 2008, 24, 621. [陈洁, 黄可龙, 刘素琴. 无机化学学报, 2008, 24, 621.]

    12. [12]

      (12) Cheng, F.; Huang, K. L.; Liu, S. Q.; Fang, X. S.; Zhang, X. Acta Phys. -Chim. Sin. 2011, 27 (6), 1439. [程风, 黄可龙, 刘素琴, 房雪松, 张新. 物理化学学报, 2011, 27 (6), 1439.] doi: 10.3866/PKU.WHXB20110607

    13. [13]

      (13) Liang, J. F.; Zhou, J.; Guo, L. Science Foundation in China 2013, 21 (1), 59.

    14. [14]

      (14) Tang, Y. P.;Wang, S. M.; Hou, G. Y.; Zheng, G. Q. Battery Bimonthly 2014, 44 (1), 50. [唐谊平, 王诗明, 侯广亚, 郑国渠. 电池, 2014, 44 (1), 50.]

    15. [15]

      (15) Sun, J.; Zhao, D. L.; Liu, H.; Jing, L.; Chi,W. D.; Shen, Z. M. J. Function Materials 2012, 43 (15), 2027. [孙杰, 赵东林,刘辉, 景磊, 迟伟东, 沈曾民. 功能材料, 2012, 43 (15), 2027.]

    16. [16]

      (16) Ban, C. M.;Wu, Z. C.; Gillaspie, D. T.; Chen, L.; Yan, Y. F.; Blackburn, J. L.; Dillon, A. C. Adv. Mater. 2010, 22, E145.

    17. [17]

      (17) Ma, Y.; Zhang, C.; Ji, G.; Lee, J. Y. J. Mater. Chem. 2012, 22, 7845. doi: 10.1039/c2jm30422h

    18. [18]

      (18) Su, J.; Cao, M. H.; Ren, L., Hu, C.W. J. Phys. Chem. C 2011, 115, 14469.

    19. [19]

      (19) Lee, J. K.; Smith, K. B.; Hayner, C. M.; Kung, H. H. Chem. Commun. 2010, 46, 2025. doi: 10.1039/b919738a

    20. [20]

      (20) Chen, S. Q.;Wang, Y. J. Mater. Chem. 2010, 20, 9735. doi: 10.1039/c0jm01573c

    21. [21]

      (21) Wu, Z. S.; Zhou, G.; Yin, L. C.; Ren,W.; Li, F., Chen, H. M. Nano Energy 2012, 1, 107.

    22. [22]

      (22) Xu, C.; Xu, B.; Gu, Y.; Xiong, Z.; Sun, J.; Zhao, X. S. Energy Environ. Sci. 2013, 6, 1388. doi: 10.1039/c3ee23870a

    23. [23]

      (23) Chen, S., Zhu, J.W.;Wu, X. D.; Han, Q. F.;Wang, X. ACS Nano 2010, 4, 2822. doi: 10.1021/nn901311t

    24. [24]

      (24) Zhou, G.;Wang, D.W.; Li, F.; Zhang, L.; Li, N.;Wu, Z. S.; Wen, L.; Lu, G. Q.; Chen, H. M. Chem. Mater. 2010, 22, 5306. doi: 10.1021/cm101532x

    25. [25]

      (25) Zhang, M.; Lei, D. N.; Yin, X. M.; Chen, L. B.; Li, Q. H.;Wang, Y. G.;Wang, T. H. J. Mater. Chem. 2010, 20, 5538. doi: 10.1039/c0jm00638f

    26. [26]

      (26) Behera, S. K. Chem. Commun. 2011, 47, 10371. doi: 10.1039/c1cc13218k

    27. [27]

      (27) Li, B. J.; Cao, H. Q.; Shao, J.; Qu, M. Z.;Warner, J. H. J. Mater. Chem. 2011, 21, 5069. doi: 10.1039/c0jm03717f

    28. [28]

      (28) Chen, Y.; Song, B. H.; Tang, X. S.; Lu, L.; Xu, J. M. J. Mater. Chem. 2012, 22, 17656. doi: 10.1039/c2jm32057f

    29. [29]

      (29) Zhu, X.; Zhu, Y.; Murali, S.; Stroller, M. D.; Ruoff, R. S. ACS Nano 2011, 5, 3333. doi: 10.1021/nn200493r

    30. [30]

      (30) Zai, J. T .; Yu, C.; Zou, Q.; Tao, L. Q.;Wang, K. X.; Han, Q. Y.; Li, B.; Xiao, Y. L.; Qian, X. F.; Qi, R. R. RSC Adv. 2012, 2, 4397. doi: 10.1039/c2ra20319g

    31. [31]

      (31) Fan, Z.; Yan, J.;Wei, T.; Zhi, L.; Ning, G.; Li, T.;Wei, F. Adv. Func. Mater. 2011, 11, 2905.

    32. [32]

      (32) Zhou, J.; Song, H.; Ma, L.; Chen, X. RSC Adv. 2011, 1, 782. doi: 10.1039/c1ra00402f

    33. [33]

      (33) Xu, Y.; Sheng, K.; Li, C.; Shi, G. ACS Nano 2010, 4, 4324. doi: 10.1021/nn101187z

    34. [34]

      (34) Yang, S.; Feng, X.; Ivanovici, S.; Mullen, K. Angew. Chem. Int. Edit. 2010, 49, 8408. doi: 10.1002/anie.201003485

    35. [35]

      (35) Wei,W.; Yang, S.; Zhou, H.; Lieberwirth, I.; Feng, X.; Mullen, K. Adv. Mater. 2013, 25, 2909. doi: 10.1002/adma.v25.21

    36. [36]

      (36) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339. doi: 10.1021/ja01539a017

    37. [37]

      (37) Armelao, L.; Bertoncello, R.; Crociani, L.; Depaoli, G.; Granozzi, G.; Tondello, E.; Bettinelli, M. J. Mater. Chem. 1995, 5, 79. doi: 10.1039/jm9950500079

    38. [38]

      (38) Qu, J.; Yin, Y. X.;Wang, Y. Q.; Yan, Y.; Guo, Y. G.; Song,W. G. ACS Appl. Mater. Interfaces 2013, 5, 3932.

    39. [39]

      (39) Anderson, M. A.; Rubin, A. J. Adsorption of Inorganics at Solid-Liquid Interfaces; Ann Arbor Science Publishers, Inc.: Ann Arbor, USA, 1981.

    40. [40]

      (40) Wang, T. Q.;Wang, X. L.; Lu, Y.; Xiong, Q. Q.; Zhao, X. Y.; Cai, J. B.; Huang, S.; Gu, C. D.; Tu, J. P. RSC Adv. 2014, 4, 322. doi: 10.1039/c3ra45268a


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