Citation: REN Xiang-Zhong, SUN Ling-Na, ZHANG Pei-Xin, . Preparation and Electrochemical Performances of Li_1.2Mn_0.54-xNi_0.13Co_0.13Zr_xO₂ Cathode Materials for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2014, 30(9): 1641-1649. doi: 10.3866/PKU.WHXB201406172 shu

Preparation and Electrochemical Performances of Li_1.2Mn_0.54-xNi_0.13Co_0.13Zr_xO₂ Cathode Materials for Lithium-Ion Batteries

1.
College of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060, Guangdong Province, P. R. China

Corresponding author: ,
Received Date: 18 April 2014
Available Online: 17 June 2014
Fund Project:

To improve the cycling performance of lithium-rich cathode materials, Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ and Li_1.2Mn_0.54-xNi_0.13Co_0.13Zr_xO₂ (x=0.00, 0.01, 0.02, 0.03, and 0.06) were synthesized by a combustion method. The structure and morphology were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The electrochemical performances were examined by cyclic voltammetry (CV), electrochemical AC impedance spectroscopy, and galvanostatic charge-discharge cycling. The results indicate that all of the doped samples have a layer of α-NaFeO₂. When charged and discharged at 0.1C and 1.0C (1.0C=180 mA·g^-1) in the voltage range of 2.0-4.8 V, the initial discharge capacities of Li_1.2Mn_0.52Ni_0.13Co_0.13Zr_0.02O₂ were 280.3 and 206.4 mAh·g^-1, respectively. Moreover, the capacity retention after 50 cycles improved from 73.2% to 88.9% at 1.0C at room temperature. Meanwhile, this system delivered a higher discharge capacity of 76.5 mAh·g^-1 than that of the bare materials (15 mAh·g^-1) at 5.0C after 50 cycles. Electrochemical performances of the doped samples were improved at a 2.0C rate at different temperatures (50, 25, and -10 ℃). Furthermore, compared with the undoped material, the specific discharge capacity increased by 61.1% at -10 ℃ after 50 cycles.
- Combustion method,
- Lithium-ion battery,
- Cathode material,
- Lithium-rich material,
- Doping
1. [1]
  
  (1) Gao, M.; Liu, N.;Wang,W.; Li, C.; Zhang, H.; Chen, Y.; Yu, Z.; Huang, Y. Solid State Ionics 2014, 258, 8. doi: 10.1016/j.ssi.2014.01.041
2. [2]
  (2) Wang, Z.;Wu, F.; Su, Y. F.; Bao, L. Y.; Chen, L.; Li, N.; Chen, S. Acta Phys. -Chim. Sin. 2012, 28, 823. [王昭, 吴锋, 苏岳锋, 包丽颖, 陈来, 李宁, 陈实. 物理化学学报, 2012, 28, 823.] doi: 10.3866/PKU.WHXB201202102
3. [3]
  (3) Cao, Y. B.; Duan, J. G.; Jiang, F.; Hu, Y. R.; Peng, Z. D.; Du, K. Acta Phys. -Chim. Sin. 2012, 28, 1183. [曹雁冰, 段建国, 姜锋, 胡园荣, 彭忠东, 杜柯. 物理化学学报, 2012, 28, 1183.] doi: 10.3866/PKU.WHXB201202221
4. [4]
  (4) Ohzuku, T.; Ueda, A. J. Electrochem. Soc. 1994, 141, 2972. doi: 10.1149/1.2059267
5. [5]
  (5) Hosono, E.; Kudo, T.; Honma, I.; Matsuda, H.; Zhou, H. Nano Lett. 2009, 9, 1045. doi: 10.1021/nl803394v
6. [6]
  (6) Padhi, A. K.; Nanjundaswamy, K. S.; odenough, J. B. J. Electrochem. Soc. 1997, 144, 1188. doi: 10.1149/1.1837571
7. [7]
  (7) Wang, Z.; Liu, E.; He, C.; Shi, C.; Li, J.; Zhao, N. J. Power Sources 2013, 236, 25. doi: 10.1016/j.jpowsour.2013.02.022
8. [8]
  (8) Nie,W. B.; Xiao, Q. C.;Wang, J. L.; Lei, G. T.; Xiao, Q. Z.; Li, C. H. J. Inorg. Mater. 2014, 29, 258. [聂文波, 肖其昌, 王京亮, 雷钢铁, 肖启振, 李朝晖. 无机材料学报, 2014, 29, 258.]
9. [9]
  (9) Song, B.; Lai, M. O.; Lu, L. Electrochim. Acta 2012, 80, 187. doi: 10.1016/j.electacta.2012.06.118
10. [10]
  (10) Jafta, C. J.; Ozoemena, K. I.; Mathe, M. K.; Roos,W. D. Electrochim. Acta 2012, 85, 411. doi: 10.1016/j.electacta.2012.08.074
11. [11]
  (11) Ren, X. Z.; Hu, S. M.; Shi, C.; Zhang, P. X.; Yuan, Q. H.; Liu, J. H. J. Solid State Electrochem. 2012, 16, 2135. doi: 10.1007/s10008-011-1630-2
12. [12]
  (12) Ding, C. X.; Bai, Y. C.; Feng, X. Y.; Chen, C. H. Solid State Ionics 2011, 189, 69. doi: 10.1016/j.ssi.2011.02.015
13. [13]
  (13) Zhang, K. K.; Jia, M. K.; Tang, H.; Guo, G. H. Wu Han Univ. Technol., Nat. Sci. 2002, 48, 409. [张克立, 贾漫珂, 汤昊,郭光辉. 武汉大学学报: 理学版, 2002, 48, 409.]
14. [14]
  (14) Dai, K. H.; Zhang, Y.; Jin, Q. J.; Zhai, Y. C. J. Power Sources 2013, 37, 1111. [代克化, 张莹, 金秋瑾, 翟玉春. 电源技术, 2013, 37, 1111.]
15. [15]
  (15) Yamada, A.; Chung, S. C.; Hinokuma, K. J. J. Electrochem. Soc. 2001, 148, 224. doi: 10.1149/1.1348257
16. [16]
  (16) Prosini, P. P.; Carewska, M.; Scaccia, S.;Wisniewski, P.; Passerini, S.; Pasquali, M. J. Electrochem. Soc. 2002, 149, A886.
17. [17]
  (17) Yoon,W. S.; Iannopollo, S.; Grey, C. P.; Carlier, D.; rman, J.; Reed, J.; Ceder, G. Electrochem. Solid-State Lett. 2004, 7, A167.
18. [18]
  (18) Cheng, C. X.; Tan, L.; Liu, H.W.; Huang, X. T. Mater. Res. Bull. 2011, 46, 2032. doi: 10.1016/j.materresbull.2011.07.004
19. [19]
  (19) ng, Z. L.; Liu, H. S.; Guo, X. J.; Zhang, Z. R.; Yong, Y. J. Power Sources 2004, 136, 139. doi: 10.1016/j.jpowsour.2004.05.022
20. [20]
  (20) Oh, S. H.; Lee, S, M.; Cho,W. I. Electrochim. Acta 2006, 51, 3637. doi: 10.1016/j.electacta.2005.10.023
21. [21]
  (21) Johnson, C. S.; Li, N.; Lefief, C.; Thackeray, M. M. Electrochem. Commun. 2007, 9, 787. doi: 10.1016/j.elecom.2006.11.006
22. [22]
  (22) Wu, Y.; Manthiram, A. Solid State Ionics 2009, 180, 50. doi: 10.1016/j.ssi.2008.11.002
23. [23]
  (23) Xiong, X. D.; Li, X. Q.; Li,W. S. J. Power Sources 2013, 230, 89.
24. [24]
  (24) Park, S. H.; Kang, S. H.; Johnson, C.; Amine, K.; Thackeray, M. Electrochem. Commun. 2007, 9, 262. doi: 10.1016/j.elecom.2006.09.014
25. [25]
  (25) Riley, L. A.; Atta, A. V.; Cavanagh, A. S.; Yan, Y. F.; George, S. M.; Liu, P.; Dillon, A. C.; Lee, S. H. J. Power Sources 2011, 196, 3317. doi: 10.1016/j.jpowsour.2010.11.124
26. [26]
  (26) Huang, Y. Y.; Chen, J. T.; Ni, J. F.; Zhou, H. H.; Zhang, X. X. J. Power Sources 2009, 188, 538. doi: 10.1016/j.jpowsour.2008.12.037
27. [27]
  (27) Jiang, Z. Q.; Jiang, Z. G. J. Alloy. Compd. 2012, 537, 308.
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
5. [5]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
6. [6]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
7. [7]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
8. [8]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
9. [9]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
10. [10]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
11. [11]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
12. [12]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
13. [13]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
14. [14]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
15. [15]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
16. [16]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
17. [17]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
18. [18]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
19. [19]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
20. [20]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002

Get Citation

PDF

XML

Metrics

PDF Downloads(589)
Abstract views(805)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrochemical Performances of Li1.2Mn0.54-xNi0.13Co0.13ZrxO2 Cathode Materials for Lithium-Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Performances of Li_1.2Mn_0.54-xNi_0.13Co_0.13Zr_xO₂ Cathode Materials for Lithium-Ion Batteries