Citation: ZHANG Zhao-Yan, ZHU Quan-Jing, DING Jing, DAI Wei-Lin, ZONG Bao-Ning. Effect of Support on the Structural Evolution and Catalytic Performance of WO₃-Supported Catalysts in the Synthesis of Adipic Acid[J]. Acta Physico-Chimica Sinica, ;2014, 30(8): 1527-1534. doi: 10.3866/PKU.WHXB201406121 shu

Effect of Support on the Structural Evolution and Catalytic Performance of WO₃-Supported Catalysts in the Synthesis of Adipic Acid

1.
1. Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, P. R. China;
2. State Key Laboratory of Catalytic Materials and Reaction Engineering, Research Institute of Petroleum Processing, China Petroleum & Chemical Corporation, Beijing 100083, P. R. China

Received Date: 14 April 2014
Available Online: 12 June 2014
Fund Project:

A series of tungsten-based catalysts were synthesized via a traditional impregnation method using SBA-15, hexa nal mesoporous silica (HMS), and SnO₂ as the support. The supported catalysts were characterized by X-ray powder diffraction (XRD), transmission electron microscopy/field-emission transmission electron microscopy (TEM/FETEM), UV-Vis diffuse reflection spectroscopy (UV-Vis DRS), Raman spectrometry, X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared (FTIR) spectroscopy. It was found that the support was crucial to the dispersion and nature of the tungsten species on the catalyst. In this study, the catalytic performances of catalysts with different supports were investigated for the synthesis of adipic acid (AA) from the selective oxidation of cyclohexene oxide. The excellent catalytic performance of the catalyst was obtained over WO₃/SnO₂, followed by WO₃/HMS and WO₃/SBA-15. The XRD results indicate that the degree of crystallinity of the tungsten species of WO₃/SnO₂ catalyst was low and the particle size of WO₃ was small (~2 nm). TEM and XPS results imply a high dispersion of tungsten species on the SnO₂ support. The UV-Vis DRS spectra demonstrate the existence of [WO₄] and low-polymeric tungsten species. In addition, the W-based catalyst with SnO₂ as the support could retain high activity, even after being reused six times, suggesting that there is strong interaction between tungsten species and the SnO₂-support that enhanced the stability of the catalyst. This shows the potential of the WO₃/SnO₂ as a catalyst for the synthesis of adipic acid.
- Tungsten oxide,
- SBA-15,
- HMS,
- Tin oxide,
- Adipic acid,
- High dispersion
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Effect of Support on the Structural Evolution and Catalytic Performance of WO3-Supported Catalysts in the Synthesis of Adipic Acid

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通讯作者: 陈斌, bchen63@163.com

Effect of Support on the Structural Evolution and Catalytic Performance of WO₃-Supported Catalysts in the Synthesis of Adipic Acid