Citation: Lü Jiao-Long, LI Feng-Li, LI Xin-Gang. NO_x Storage Reduction Performance of Coupled BaFeO_3-x+Cu-ZSM-5 Catalyst[J]. Acta Physico-Chimica Sinica, ;2014, 30(8): 1550-1558. doi: 10.3866/PKU.WHXB201406031 shu

NO_x Storage Reduction Performance of Coupled BaFeO_3-x+Cu-ZSM-5 Catalyst

Lü Jiao-Long ^1,2 ,
LI Feng-Li ^1,2 ,
LI Xin-Gang ^1,2,

1.
1. Tianjin Key Laboratory of Applied Catalysis Science & Technology, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, P. R. China;
2. The Collaborative Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin 300072, P. R. China

Received Date: 11 April 2014
Available Online: 3 June 2014
Fund Project:

A BaFeO_3-x+Cu-ZSM-5 coupled catalyst was designed and synthesized to eliminate the NO_x emitted from lean-burn exhausts, providing an alternative to the traditional noble-metal-based NO_x storage reduction (NSR) catalysts. During the lean-burn period, the NO oxidation and storage processes mainly occurred over the BaFeO_3-x catalyst. During the fuel-rich period, the released NO_x from the BaFeO_3-x catalyst was further reduced over the Cu-ZSM-5 catalyst. Our results show that, compared with the BaFeO_3-x and Cu-ZSM-5 catalyst alone, the operating temperature window of the coupled BaFeO_3-x+Cu-ZSM-5 catalyst is extended from 250 to 400 ℃, and its NO_x elimination performance is significantly improved. The maximum NO_x conversion of the coupled catalyst was 98%, while the N₂ selectivity was close to 100%.
- Lean-burn,
- Coupled catalyst,
- NO_x,
- Storage,
- Reduction
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沈阳化工大学材料科学与工程学院沈阳 110142

NOx Storage Reduction Performance of Coupled BaFeO3-x+Cu-ZSM-5 Catalyst

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通讯作者: 陈斌, bchen63@163.com

NO_x Storage Reduction Performance of Coupled BaFeO_3-x+Cu-ZSM-5 Catalyst