Citation: HUA Wei-Bo, ZHENG Zhuo, LI Long-Yan, GUO Xiao-Dong, LIU Heng, SHEN Chong-Heng, WU Zhen-Guo, ZHONG Ben-He, HUANG Ling. Synthesis of Nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ by Ammonia-Evaporation-Induced Synthesis and Its Electrochemical Properties as a Cathode Material for a High-Power Li-Ion Battery[J]. Acta Physico-Chimica Sinica, ;2014, 30(8): 1481-1486. doi: 10.3866/PKU.WHXB201405303 shu

Synthesis of Nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ by Ammonia-Evaporation-Induced Synthesis and Its Electrochemical Properties as a Cathode Material for a High-Power Li-Ion Battery

1.
1. Phosphorus Resources Comprehensive Utilization & Clean Processing Center of Ministry of Education, School of Chemical Engineering, Sichuan University, Chengdu 610065, P. R. China;
2. School of Materials Science and Engineering, Sichuan University, Chengdu 610065, P. R. China;
3. State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 23 April 2014
Available Online: 30 May 2014
Fund Project:

We report on an ammonia-evaporation-induced synthetic method for nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ cathode material. Powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high- resolution transmission electron microscopy (HRTEM), energy- dispersive X- ray spectroscopy (EDS), Brunauer-Emmett-Teller nitrogen sorption, and galvanostatic charge-discharge tests were applied to analyze the crystal structure, micromorphology, and electrochemical properties of nanostructured LiNi_1/3Co_1/3Mn_1/3O₂. The results show that it has a well-ordered layered α-NaFeO₂ with little cation mixing. Awalnutkernel- like morphology is formed by nanosheets, leading to a nanoporous material. The lateral plane of nanosheets are {010}-faceted, which could provide multiple channels for Li⁺-ion migration. The electrochemical properties of the lithium cells used this material as cathode are excellent: the specific discharge capacity at 0.5C,1C, 3C, 5C and 10C is, respectively, up to 172.90, 153.95, 147.09, 142.16, and 131.23 mAh·g^-1 between 3.0 and 4.6 V at room temperature. These excellent features will make the nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ become a positive electrode material of potential interest for useful applications, such as in electric vehicles and hybrid electric vehicles.
- Lithium-ion battery,
- Cathode material,
- LiNi_1/3Co_1/3Mn_1/3O₂,
- Nanostructure,
- Ammonia-evaporation-induced synthetic method,
- Electrochemical property
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Nanostructured LiNi1/3Co1/3Mn1/3O2 by Ammonia-Evaporation-Induced Synthesis and Its Electrochemical Properties as a Cathode Material for a High-Power Li-Ion Battery

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ by Ammonia-Evaporation-Induced Synthesis and Its Electrochemical Properties as a Cathode Material for a High-Power Li-Ion Battery