Citation: YANG Ting, CHEN Li-Ping, CHEN Wang-Hua, ZHANG Cai-Xing, GAO Hai-Su, LU Gui-Bin, ZHOU Yi-Shan. Experimental Method on Rapid Identification of Autocatalysis in Decomposition Reactions[J]. Acta Physico-Chimica Sinica, ;2014, 30(7): 1215-1222. doi: 10.3866/PKU.WHXB201405161 shu

Experimental Method on Rapid Identification of Autocatalysis in Decomposition Reactions

1.
Department of Safety Engineering, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China

Received Date: 28 February 2014
Available Online: 16 May 2014
Fund Project:

Many chemical substances will decompose in an autocatalytic manner, and such autocatalytic behavior can be identified through isothermal measurements, such as using differential scanning calorimetry (DSC) and microcalorimetry (C80). However, since it is difficult to predict the appropriate temperature for isothermal testing, it would be helpful to develop a simple and effective experimental method to distinguish autocatalytic decomposition. Based on the results of Roduit et al., a new technique for identifying autocatalysis is described herein, termed the“interruption and re-scanning”method. The decompositions of 2-ethylhexyl nitrate (EHN), 2,4-dinitrotoluene (2,4-DNT), dicumyl peroxide (DCP), and cumyl hydroperoxide (CHP) were assessed using both this new method and isothermal approach. Based on the results, the decompositions of EHN and DCP were found to proceed accord to the“nth order”law, whereas 2,4-DNT and CHP decomposed autocatalytically. We conclude that the interruption and rescanning method can be used to identify the characteristics of autocatalysis both quickly and effectively.
- Decomposition reaction,
- Autocatalysis,
- Rapid identification,
- Differential scanning calorimetry,
- Isothermal calorimetry,
- Method of interruption and re-scanning
1. [1]
  
  (1) Long, G. T.; Brems, B. A.; Wight, C. A. Thermochim. Acta 2002, 388 (1), 175.
2. [2]
  (2) Batten, J. J. Int. J. Chem. Kinet. 1985, 17 (10), 1085. doi: 10.1002/kin.550171005
3. [3]
  (3) Li, X. R.; Koseki, H. Thermochim. Acta 2005, 431 (1), 113.
4. [4]
  (4) Stoessel, F. Thermal Safety of Chemical Process: Risk Assessment and Process Design; Science Press: Beijing, 2009; pp 56, 271-287; translated by Chen, W. H., Peng, J. H., Chen, L. P. [Stoessel, F. 化工工艺热安全:风险评估与工艺设计. 陈网桦, 彭金华,陈利平, 译.北京:科学出版社, 2009: 56, 271-287.]
5. [5]
  (5) Dien, J. M.; Fierz, H.; Stoessel, F.; Killé, G. Chima 1994, 48 (12), 542.
6. [6]
  (6) Gao, H. S.; Chen, L. P.; Chen, W. H.; Bao, S. L. Thermochim. Acta 2013, 569, 134. doi: 10.1016/j.tca.2013.07.017
7. [7]
  (7) Grewer, T. Thermochim. Acta 1993, 225 (2), 165. doi: 10.1016/0040-6031(93)80185-D
8. [8]
  (8) Chervina, S.; Bodman, G. T. Process Saf. Prog. 1997, 16 (2), 94. doi: 10.1002/prs.680160211
9. [9]
  (9) Bao, S. L.; Chen, W. H.; Chen, L. P.; Gao, H. S.; Lü, J. Y. Acta Phys. -Chim. Sin. 2013, 29 (3), 479. [鲍士龙,陈网桦, 陈利平,高海素, 吕家育.物理化学学报, 2013, 29 (3), 479.] doi: 10.3866/PKU.WHXB201212141
10. [10]
  (10) Bou-Diab, L.; Fierz, H. J. Hazard. Mater. 2002, 93 (1), 137. doi: 10.1016/S0304-3894(02)00044-4
11. [11]
  (11) Roduit, B.; Hartmanna, M.; Follyb, P.; Sarbach, A. Chem. Eng. Tran. 2013, 31.
12. [12]
  (12) Luo, J. J.;Wu, F. G.; Yu, J. S.; Rui, W.; Yu, Z. W. J. Phys. Chem. B 2011, 115 (28), 8901. doi: 10.1021/jp200296v
13. [13]
  (13) Chervin, S.; Bodman, G. T. Thermochim. Acta 2002, 392, 371.
14. [14]
  (14) Fu, X. C.; Shen, W. X.; Yao, T. Y.; Hou, W. H. Physical Chemistry, 5th ed.; Higher Education Press: Beijing, 2005; pp 156-172. [傅献彩, 沈文霞, 姚天扬, 侯文华.物理化学(第五版).北京:高等教育出版社, 2005: 156-172.]
15. [15]
  (15) Suppes, G. J.; Rui, Y.; Rome, A. C.; Chen, Z. Ind. Eng. Chem. Res. 1997, 36 (10), 4397. doi: 10.1021/ie9702284
16. [16]
  (16) Oxley, J. C.; Smith, J. L.; Rogers, E.; Ye, W. Energy Fuels 2001, 15 (5), 1194. doi: 10.1021/ef010031v
17. [17]
  (17) Bornemann, H.; Scheidt, F.; Sander, W. Int. J. Chem. Kinet. 2002, 34 (1), 34. doi: 10.1002/kin.10017
18. [18]
  (18) Zeng, X. L.; Chen, W. H.; Wang, F. W. Chin. Saf. Sci. J. 2009, 19 (8), 67. [曾秀琳,陈网桦, 王凤武. 中国安全科学学报, 2009, 19 (8), 67.]
19. [19]
  (19) Liu, T. T. A Preliminary Study of Thermal Hazard of Synthesis Process for 2-Ethylhexyl Nitrate by Nitration of Iso-Octanol. Master. Dissertation, Nanjing University of Science and Technology, Nanjing, 2010. [刘婷婷. 异辛醇硝化制备硝酸异辛酯合成工艺热危险性的初步研究[D].南京:南京理工大学, 2010.]
20. [20]
  (20) Chen, L. P.; Liu, T. T.; Yang, Q.; Chen, W. H. J. Loss. Prev. Process. Ind. 2012, 25 (3), 631.doi: 10.1016/j.jlp.2012.01.008
21. [21]
  (21) Somma, I. D.; Marotta, R.; Andreozzi, R.; Caprio, V. J. Hazard. Mater. 2011, 187 (1), 157.
22. [22]
  (22) Lv, J. Y.; Chen, L. P.; Chen, W. H.; Gao, H. S.; Peng, M. J. Thermochim. Acta 2013, 571, 60. doi: 10.1016/j.tca.2013.08.029
23. [23]
  (23) Talouba, I. B.; Balland, L.; Mouhab, N.; Abdelghani-Idrissi, M. A. J. Loss. Prev. Process Ind. 2011, 24 (4), 391. doi: 10.1016/j.jlp.2011.02.001
24. [24]
  (24) Li, X. R.; Koseki, H. J. Loss. Prev. Process Ind. 2005, 18 (4), 460.
25. [25]
  (25) Miyake, A.; Sumino, M.; Oka, Y.; Ogawa, T.; Lizuka, Y. Thermochim. Acta 2000, 352, 181.
26. [26]
  (26) Jin, M. P.; Sun, F.; Shi, N.; Xie, C. X. CIESC Journal 2012, 63 (12), 4096. [金满平, 孙峰,石宁,谢传欣.化工学报, 2012, 63 (12), 4096.]
27. [27]
  (27) Hou, H. Y.; Shu, C. M.; Duh, Y. S. AIChE Journal 2001, 47 (8), 1893. doi: 10.1002/aic.690470819
28. [28]
  (28) Duh, Y. S.; Kao, C. S.; Hwang, H. H.; Lee, W. W. L. Process Saf. Environ. Protect. 1998, 76 (4), 271. doi: 10.1205/095758298529623
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