Citation: LIU Xin, XIE Jing-Ying, ZHAO Hai-Lei, LÜ Peng-Peng, WANG Ke, FENG Zhen-He, WANG Meng-Wei. Synthesis and Properties of FeSn₂-C Composites as Anode Materials for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2014, 30(7): 1281-1289. doi: 10.3866/PKU.WHXB201405071 shu

Synthesis and Properties of FeSn₂-C Composites as Anode Materials for Lithium-Ion Batteries

1.
1. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China;
2. Shanghai Institute of Space Power Sources, Shanghai 200245, P. R. China;
3. Beijing Key Laboratory of New Energy Materials and Technology, Beijing 100083, P. R. China

Received Date: 10 February 2014
Available Online: 7 May 2014
Fund Project:

Tin has a theoretical specific capacity as high as 990 mAh·g^-1, and is thus a potential anode material for high-energy-density lithium-ion batteries. However, it suffers from a huge volume change during lithiation/delithiation process, leading to poor cycle performance. In this paper, core/shell structured FeSn₂-C composites were successfully synthesized by a simple high-energy ball milling technique with Sn, Fe, and graphite powder as raw materials. The FeSn₂-C composite was evaluated as an anode material for lithium-ion batteries. The influence of milling time and final phase composition on the microstructure and electrochemical performance of FeSn₂-C composites was systematically investigated. The failure mechanism of the FeSn₂-C electrode was also analyzed. The results reveal that long milling time can promote the mechanical alloying process of the FeSn₂ phase and reduce the particle size of the FeSn₂-C composite, which are beneficial for the increase of the specific capacity and the improvement of the cycle performance of the FeSn₂-C electrode. A high FeSn₂ phase content leads to a high specific capacity of the FeSn₂-C composites but poor cycling stability of the electrode. The optimized Sn₂₀Fe₁₀C₇₀ composite prepared by ball milling for 24 h (500 r ·min^-1) shows the best electrochemical performance with a capacity about 540 mAh·g^-1 for 100 cycles. The synthesized Sn₂₀Fe₁₀C₇₀ composite is a promising anode material for highenergy-density lithium-ion batteries.
- FeSn₂-C composite,
- Phase composition,
- High-energy ball milling,
- Anode material,
- Lithium-ion battery
1. [1]
  
  (1) Zhamu, A.; Chen, G.; Liu, C.; Neff, D.; Fang Q.; Yu, Z.; Xiong, W.;Wang, Y.;Wang, X.; Jang, B. Z. Energy & Environ. Sci. 2012, 5, 5701.
2. [2]
  (2) Chang, Y. Q.; Huang, L.; Sun, S. G. Acta Phys. -Chim. Sin. 2010, 26, 561. [常玉清, 黄令, 孙世刚. 物理化学学报, 2010, 26, 561.]
3. [3]
  (3) Guo, H.; Zhao, H.; Jia, X.; Li, X.; Qiu,W. Electrochim. Acta 2007, 52, 4853.
4. [4]
  (4) Liang, C.; Gao, M.; Pan, H.; Liu, Y.; Yan, M. J. Alloy. compd. 2013, 575, 246.
5. [5]
  (5) Liu, X.; Xie, J. Y.; Zhao, H. L.;Wang, K.; Tang,W. P.; Pan, Y. L.; Feng, Z. H.; LÜ, P. P. Acta Chim. Sin. 2013, 71, 1011. [刘欣, 解晶莹, 赵海雷, 王可, 汤卫平, 潘延林, 丰震河, 吕鹏鹏. 化学学报, 2013, 71, 1011]
6. [6]
  (6) Zhang,W. J. J. Power Sources 2011, 196, 13.
7. [7]
  (7) Todd, A. D.W.; Mar, R. E.; Dahn, J. R. J. Electrochem. Soc. 2006, 153, A1998.
8. [8]
  (8) Guo, H.; Zhao, H.; Jia, X. Electrochem. Commun. 2007, 9, 2207.
9. [9]
  (9) Fan, X. Y.; Zhuang, Q. C.;Wei, G. Z.; Ke, F. S.; Huang, L.; Dong, Q. F.; Sun, S. G. Acta Phys. -Chim. Sin. 2009, 25, 611. [樊小勇, 庄全超, 魏国祯, 柯福生, 黄令, 董全峰, 孙世刚. 物理化学学报, 2009, 25, 611.]
10. [10]
  (10) Zhang,W. J. J. Power Sources 2011, 196, 877.
11. [11]
  (11) Ferguson, P. P.; Todd, A. D.W.; Dahn, J. R. Electrochem. Commun. 2008, 10, 25.
12. [12]
  (12) Jung, H. R.;Wan, J. L. J. Electrochem. Soc. 2011, 158, A644.
13. [13]
  (13) Mao, O.; Dunlap, R. A.; Dahn, J. R. J. Electrochem. Soc. 1999, 146, 405.
14. [14]
  (14) Mao, O.; Dahn, J. R. J. Electrochem. Soc. 1999, 146, 414.
15. [15]
  (15) Mao, O.; Dahn, J. R. J. Electrochem. Soc. 1999, 146, 423.
16. [16]
  (16) Yoon, S.; Lee, J. M.; Kim, H.; Im, D.; Doo, S. G.; Sohn, H. J. Electrochim. Acta 2009, 54, 2699.
17. [17]
  (17) Lee, J. M.; Jung, H.; Hwa, Y.; Kim, H.; Im, D.; Doo, S. G.; Sohn, H.J. J. Power Sources 2010, 195, 5044.
18. [18]
  (18) Ferguson, P. P.; Liao, P.; Dunlap, R. A.; Dahn, J. R. J. Electrochem. Soc. 2009, 156, A13.
19. [19]
  (19) Holzwarth, U.; Gibson, N. Nat. Nanotechnol. 2011, 6, 534.
20. [20]
  (20) Todd, A. D.W.; Ferguson, P. P.; Fleischauer, M. D.; Dahn, J. R. Int. J. Energy Res. 2010, 34, 535.
21. [21]
  (21) Chamas, M.; Lippens, P. E.; Jumas, J. C.; Boukerma, K.; Dderyvere, R.; nbeau, D.; Hassoun, J.; Panero, S.; Scrosati, B. J. Power Sources 2011, 196, 7011.
22. [22]
  (22) Zhang, C. Q.; Tu, J. P.; Huang, X. H.; Yuan, Y. F.;Wang, S. F.; Mao, F. J. Alloy. Compd. 2008, 457, 81.
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Synthesis and Properties of FeSn₂-C Composites as Anode Materials for Lithium-Ion Batteries