Citation: WANG Li, MA Jun-Hong. Synthesis and Electrocatalytic Properties of Pt Nanoparticles on Nitrogen-Doped Reduced Graphene Oxide for Methanol Oxidation[J]. Acta Physico-Chimica Sinica, ;2014, 30(7): 1267-1273. doi: 10.3866/PKU.WHXB201405052 shu

Synthesis and Electrocatalytic Properties of Pt Nanoparticles on Nitrogen-Doped Reduced Graphene Oxide for Methanol Oxidation

WANG Li ¹ ,
MA Jun-Hong ^1,2,

1.
1. College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China;
2. Key Laboratory of Advanced Functional Materials, Autonomous Region, Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, P. R. China

Received Date: 22 March 2014
Available Online: 5 May 2014
Fund Project:

Nitrogen-doped reduced graphene oxide materials (N-R ) derived from pyrolysis of graphene oxide ( )/polyaniline composites were used as a support for the immobilization of Pt nanoparticles. The morphologies and structures of N-R and Pt/N-R were comprehensively characterized by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and Raman spectroscopy. The electrocatalytic activities of the as-prepared catalysts for CO stripping and methanol oxidation were investigated by cyclic voltammetry and chronoamperometry. The results showed that was reduced to multilayer graphene by thermal annealing accompanied with successful incorporation of N atoms into R . Moreover, the presence of the doped N atoms enhanced the surface defects and electrical conductivity of the R materials. Pt nanoparticles on N-R were more evenly dispersed, had better CO tolerance, and had higher activity/stability for methanol oxidation than those on R without N doping.
- Polyaniline,
- Reduced graphene oxide,
- Nitrogen-doped,
- Platinum electrocatalyst,
- Methanol oxidation
1. [1]
  
  (1) Wei, D.; Liu, Y.;Wang, Y.; Zhang, H.; Huang, L.; Yu, G. Nano Lett. 2009, 9, 1752. doi: 10.1021/nl803279t
2. [2]
  (2) Yang, Z.; Yao, Z.; Li, G.; Fang, G.; Nie, H.; Liu, Z.; Zhou, X.; Chen, X.; Huang, S. ACS Nano 2012, 6, 205. doi: 10.1021/nn203393d
3. [3]
  (3) Shao, Y. Y.; Sui, J. H.; Yin, G. P.; Gao, Y. Z. Appl. Catal. B 2008, 79 (1), 89. doi: 10.1016/j.apcatb.2007.09.047
4. [4]
  (4) Xiong, B.; Zhou, Y. K.; O′Hayre, R.; Shao, Z. P. Appl. Surf. Sci. 2013, 266, 433. doi: 10.1016/j.apsusc.2012.12.053
5. [5]
  (5) Wu, J.; Hu, F.; Hu, X.;Wei, Z. D.; Shen, P. K. Electrochimica Acta 2008, 53 (28), 8341. doi:10.1016/j.electacta.2008.06.051
6. [6]
  (6) Zhou, C.W.; Kong, J.; Yenilmez, E.; Dai, H. J. Science 2000, 290, 1552. doi: 10.1126/science.290.5496.1552
7. [7]
  (7) He, D. P.; Jiang, Y. L.; Lv, H. F.; Pan, M.; Mu, S. C. Applied Catalysis B: Environmental 2013, 132 -133, 379.
8. [8]
  (8) Xiao, X.; Zhou, Y. K.; Lu, J. M.; Tian, X. H.; Zhu, H. X.; Liu, J. G. Electrochimica Acta 2014, 120, 439. doi: 10.1016/j. electacta.2013.12.062
9. [9]
  (9) Zhang, L. S.; Liang, X. Q.; Song,W. G.;Wu, Z. Y. Phys. Chem. Chem. Phys. 2010, 12, 12055. doi: 10.1039/c0cp00789g
10. [10]
  (10) Sun, L.;Wang, L.; Tian, G. G.; Tan, T. X.; Xie, Y.; Shi, K. Y.; Li, M. T.; Fu, H. G. RSC Adv. 2012, 2, 4498. doi: 10.1039/c2ra01367c
11. [11]
  (11) Wang, Y.; Shao, Y. Y.; Matson, D.W.; Li, J. H.; Lin, Y. H. ACS Nano 2010, 4, 1790.
12. [12]
  (12) Hassan, F. M.; Chabot, V.; Li, J. D.; Kim, B. K.; Ricardez-Sandoval, L.; Yu, A. P. J. Mater. Chem. A 2013, 1, 2904.
13. [13]
  (13) Xu, X.; Zhou, Y. K.; Yuan, T.; Li, Y.W. Electrochimica Acta 2013, 112, 587. doi: 10.1016/j.electacta.2013.09.038
14. [14]
  (14) Lin, Z. Y.;Waller, G.; Liu, Y.; Liu, M. L.;Wong, C. P. Adv. Energy Mater. 2012, 2 (7), 884.
15. [15]
  (15) Lin, Z.Y.; Song, M. K.; Ding, Y.; Liu, Y.; Liu, M. L.;Wong, C. P. Phys. Chem. Chem. Phys. 2012, 14, 3381. doi: 10.1039/c2cp00032f
16. [16]
  (16) Sheng, Z. H.; Shao, L.; Chen, J. J.; Bao,W. J.;Wang, F. B.; Xia, X. H. ACS Nano 2011, 5, 4350. doi: 10.1021/nn103584t
17. [17]
  (17) Lin, Z. Y.;Waller, G.; Liu, Y.; Liu, M. L.;Wong, C. P. Nano Energy 2013, 2, 241. doi: 10.1016/j.nanoen.2012.09.002
18. [18]
  (18) Lai, L. F.; Potts, J. R.; Zhan, D.;Wang, L.; Poh, C. K.; Tang, C. H.; ng, H.; Shen, Z. X.; Lin, J. Y.; Rodney, S. R. Energy Environ. Sci. 2012, 5, 7936. doi: 10.1039/c2ee21802j
19. [19]
  (19) Wu, G.; Mack, N. H.; Gao,W.; Ma, S. G.; Zhong, R. Q.; Han, J. T.; Baldwin, J. K.; Zelenay, P. ACS Nano 2012, 6 (11), 9764. doi: 10.1021/nn303275d
20. [20]
  (20) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339. doi: 10.1021/ja01539a017
21. [21]
  (21) Wu, G.; Swaidan, R. J.; Li, D. Y.; Li, N. Electrochimica Acta 2008, 53, 7622. doi: 10.1016/j.electacta.2008.03.082
22. [22]
  (22) Stankovicha, S.; Dikina, D. A.; Piner, R. D.; Kohlhaas, K. A.; Kleinhammes, A.; Jia, Y. Y.;Wu, Y.; Nguyen, S. B. T.; Ruoff, R. S. Carbon 2007, 45 (7), 1558. doi: 10.1016/j.carbon.2007.02.034
23. [23]
  (23) Liu, S.;Wang, J.; Zeng, J.; Ou, J.; Li, Z.; Liu, X.; Yang, S. G. J. Power Sources 2010, 195 (15), 4628. doi: 10.1016/j. jpowsour.2010.02.024
24. [24]
  (24) Ferrari, A. C.; Meyer, J. C.; Scardaci, V.; Casiraghi, C.; Lazzeri, M.; Mauri, F.; Piscanec, S.; Jiang, D.; Novoselov, K. S.; Roth, S.; Geim, A. K. Phys. Rev. Lett. 2006, 97, 187401. doi: 10.1103/PhysRevLett.97.187401
25. [25]
  (25) Kudin, K. N.; Ozbas, B.; Schniepp, H. C.; Prud′homme, R. K.; Aksay, I. A.; Car, R. Nano Lett. 2008, 8, 36. doi: 10.1021/nl071822y
26. [26]
  (26) Xin, Y. C.; Liu, J. G.; Zhou, Y.; Liu,W. M.; Gao, J.; Xie, Y.; Yin, Y.; Zou, Z. G. Electrochimica Acta 2012, 60, 354. doi: 10.1016/j.electacta.2011.11.062
27. [27]
  (27) Kuo, P. L.; Chen,W. F.; Huang, H. Y.; Chang, I. C.; Dai, S. A. J. Phys. Chem. B 2006, 110, 3071.
28. [28]
  (28) Wu, G.; Li, D.; Dai, C.;Wang, D.; Li, N. Langmuir 2008, 24, 3566. doi: 10.1021/la7029278
29. [29]
  (29) Groves, M. N.; Chan, A. S.W.; Malardier, J. C.; Jugroot, M. Chem. Phys. Lett. 2009, 481, 214. doi: 10.1016/j.cplett.2009.09.074
30. [30]
  (30) Zhou, Y.; Neyerlin, K.; Olson, T. S.; Pylypenko, S.; Bult, J.; Dinh, H. N.; Gennett, T.; Shao, Z. P.; O'Hayre, R. Energy Environ. Sci. 2010, 3 (10), 1437. doi: 10.1039/c003710a
31. [31]
  (31) Wang, S. Y.; Jiang, S. P.;Wang, X.; Guo, J. Electrochimica Acta 2011, 56, 1563. doi: 10.1016/j.electacta.2010.10.055
32. [32]
  (32) Zheng, S. F.; Hu, J. S.; Zhong, L. S.;Wan, L. J.; Song,W. G. J. Phys. Chem. C 2007, 111, 11174. doi: 10.1021/jp0727042
33. [33]
  (33) Zheng, B.; Zheng,W. T.; Zhang, K.;Wen, Q. B.; Zhu, J. Q.; Meng, S. H.; He, X. D.; Han, J. C. Carbon 2006, 44, 962. doi: 10.1016/j.carbon.2005.10.009
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