Citation: WANG Li, MA Jun-Hong. Synthesis and Electrocatalytic Properties of Pt Nanoparticles on Nitrogen-Doped Reduced Graphene Oxide for Methanol Oxidation[J]. Acta Physico-Chimica Sinica, ;2014, 30(7): 1267-1273. doi: 10.3866/PKU.WHXB201405052 shu

Synthesis and Electrocatalytic Properties of Pt Nanoparticles on Nitrogen-Doped Reduced Graphene Oxide for Methanol Oxidation

WANG Li ¹ ,
MA Jun-Hong ^1,2,

1.
1. College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China;
2. Key Laboratory of Advanced Functional Materials, Autonomous Region, Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, P. R. China

Received Date: 22 March 2014
Available Online: 5 May 2014
Fund Project:

Nitrogen-doped reduced graphene oxide materials (N-R ) derived from pyrolysis of graphene oxide ( )/polyaniline composites were used as a support for the immobilization of Pt nanoparticles. The morphologies and structures of N-R and Pt/N-R were comprehensively characterized by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and Raman spectroscopy. The electrocatalytic activities of the as-prepared catalysts for CO stripping and methanol oxidation were investigated by cyclic voltammetry and chronoamperometry. The results showed that was reduced to multilayer graphene by thermal annealing accompanied with successful incorporation of N atoms into R . Moreover, the presence of the doped N atoms enhanced the surface defects and electrical conductivity of the R materials. Pt nanoparticles on N-R were more evenly dispersed, had better CO tolerance, and had higher activity/stability for methanol oxidation than those on R without N doping.
- Polyaniline,
- Reduced graphene oxide,
- Nitrogen-doped,
- Platinum electrocatalyst,
- Methanol oxidation
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