Citation: XU Ling-Ling, ZHANG Xiao-Hua, CHEN Jin-Hua. Synthesis and Electrochemical Supercapacitive Properties of Nitrogen-Doped Mesoporous Carbons[J]. Acta Physico-Chimica Sinica, ;2014, 30(7): 1274-1280. doi: 10.3866/PKU.WHXB201405044 shu

Synthesis and Electrochemical Supercapacitive Properties of Nitrogen-Doped Mesoporous Carbons

1.
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China

Received Date: 14 March 2014
Available Online: 4 May 2014
Fund Project:

Nitrogen-doped mesoporous carbons (NMCs) were synthesized by direct carbonization of zeolitic imidazolate framework-8 (ZIF-8) nanopolyhedrons. The surface morphology and structure were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and surface area and pore size analyzer. The electrochemical supercapacitive properties of the NMCs were also investigated. The results showed that the NMCs had a uniformmorphology, mesoporous nanostructure, and high surface area (2737m²·g^-1). On the other hand, based on the excellent surface wettability, pseudocapacitive behavior and electrolyte accessibility resulted fromN-doping and the mesoporous structure, the NMCs exhibited excellent electrochemical supercapacitive properties: a high specific capacitance (307 F·g^-1 in 1.0 mol·L^-1 H₂SO₄ solution, at 1 A·g^-1), od power characteristics, and satisfactory stability (the capacitance retained ratio was 96.9%after 5000 cycles even at a high current density of 10A·g^-1).
- Mesoporous carbon,
- Nitrogen doping,
- Carbonization,
- Capacitive property
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