Citation: HU Jing-Xiu, ZHANG Jing, ZOU Jian-Feng, XIAO Qiang, ZHONG Yi-Jun, ZHU Wei-Dong. Nitrogen-Rich Microporous Carbon Derived from Melamine-Based Porous Polymer for Selective CO₂ Adsorption[J]. Acta Physico-Chimica Sinica, ;2014, 30(6): 1169-1174. doi: 10.3866/PKU.WHXB201404223 shu

Nitrogen-Rich Microporous Carbon Derived from Melamine-Based Porous Polymer for Selective CO₂ Adsorption

1.
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, Zhejiang Province, P. R. China

Received Date: 19 February 2014
Available Online: 22 April 2014
Fund Project:

Nitrogen-rich microporous carbon (NMC) was prepared by the carbonization of a melaminebased porous polymer (POP), which was synthesized via a Schiff base condensation using isophthalaldehyde and melamine as starting materials. N₂ adsorption-desorption and Fourier transform infrared (FTIR) spectroscopy were used to characterize the structural properties of POP and the derived NMC. NMC contains less functional groups and has a higher specific surface area and microporous volume compared to POP. NMC has a N content of up to 12.5% (w), as determined by elemental analysis. Single-component adsorption equilibrium isotherms of CO₂, CH₄, and N₂ on NMC were obtained using a volumetric method. NMC has a od CO₂ capture property and its CO₂ adsorption capacity was 2.34 mmol·g^-1 at 298 K and 100 kPa. Dual-site Langmuir (DSL) or single-site Langmuir (SSL) models appropriately describe the adsorption equilibrium behavior of CO₂, CH₄, and N₂ on NMC. Based on the combined fitting parameters, binary adsorption isotherms were predicted by ideal adsorbed solution theory (IAST). Very high adsorption selectivities of CO₂ over N₂ and CH₄ were obtained and the values were 144.9 and 12.8, respectively.
- Microporous carbon,
- CO₂ adsorption,
- Langmuir model,
- IAST,
- Selectivity
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Nitrogen-Rich Microporous Carbon Derived from Melamine-Based Porous Polymer for Selective CO2 Adsorption

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通讯作者: 陈斌, bchen63@163.com

Nitrogen-Rich Microporous Carbon Derived from Melamine-Based Porous Polymer for Selective CO₂ Adsorption