Citation: HUANG Guo-Yong, XU Sheng-Ming, LI Lin-Yan, WANG Xue-Jun, LU Sha-Sha. Synthesis and Modification of a Lamellar Co₃O₄ Anode for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2014, 30(6): 1121-1126. doi: 10.3866/PKU.WHXB201404221 shu

Synthesis and Modification of a Lamellar Co₃O₄ Anode for Lithium-Ion Batteries

1.
1 Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, P. R. China;
2 Beijing Key Laboratory of Fine Ceramics, Tsinghua University, Beijing 100084, P. R. China

Received Date: 16 January 2014
Available Online: 22 April 2014
Fund Project:

For advanced performance lithium-ion batteries (LIBs) various novel electrode materials with high energy density have been extensively investigated. Cobaltosic oxide (Co₃O₄), commonly used as an anode in LIBs, has attracted much interest because of its high theoretical specific capacity (890 mAh·g^-1), high tap density, and stable chemical properties. However, its practical use has been hindered because of its low electronic conductivity and poor rate capability. To address these problems, we investigated a liquid phase precipitation method followed by thermal treatment and obtained a unique lamellar Co₃O₄ powder. Its X-ray diffraction (XRD) diffraction peaks match the standard pattern for cubic phase Co₃O₄ with od crystallinity. We found that the Co₃O₄ powder consists of many irregular sheets (1.5-3.0 μm in diameter, 100-300 nm in thickness) with numerous poles by scanning electronmicroscopy (SEM).Additionally, the surface area was about 30.5 m²·g^-1, and this was calculated from BET nitrogen adsorption isotherm measurement data. Remarkably, perfect performance was obtained as evaluated by electrochemical measurements, including a high initial discharge capacity (1444.5 mAh·g^-1 at 0.1C) and excellent capacity retention (charge capacity after 50 cycles was still greater than 1100.0 mAh·g^-1 at 0.1C). However, its rate capability was still not adequate (75.3% of the first charge capacity after 50 cycles at 1C). To improve the rate capability, commercial carbon nanotubes (CNTs) mixed with the Co₃O₄ powder was used to enhance the electronic conductivity. The charge capacity retention ratios were 96.3% after 70 cycles at 1C and 97.0% after 50 cycles at 2C. Therefore, enhanced electrochemical performance with impressive rate capability was obtained, as expected.
- Co₃O₄,
- Lamellar,
- Carbon nanotube,
- Lithium-ion battery,
- Anode
1. [1]
  
  (1) Dunn, B.; Kamath, H.; Tarascon, J. M. Science 2011, 334, 928. doi: 10.1126/science.1212741
2. [2]
  (2) Chen, J. J. Materials 2013, 6, 156. doi: 10.3390/ma6010156
3. [3]
  (3) Huang, G. Y.; Xu, S. M.;Wang, J. L.; Li, L. Y.;Wang, X. J. Acta Chim. Sin. 2013, 71, 1589. [黄国勇, 徐盛明, 王俊莲, 李林艳, 王学军. 化学学报, 2013, 71, 1589.] doi: 10.6023/A13060656
4. [4]
  (4) Volder, M. F. L. D.; Tawfick, S. H.; Baughman, R. H.; Hart, A. J. Science 2013, 339, 535. doi: 0.1126/science.1222453
5. [5]
  (5) Wang, F.; Lu, C. C.; Qin, Y. F.; Liang, C. C.; Zhao, M. S.; Yang, S. C.; Sun, Z. B.; Song, X. P. J. Power Sources 2013, 235, 67. doi: 10.1016/j.jpowsour.2013.01.190
6. [6]
  (6) Wang, J. Y.; Yang, N. L.; Tang, H. J.; Dong, Z. H.; Jin, Q.; Yang, M.; Kisailus, D.; Zhao, H. J.; Tang, Z. Y.;Wang, D. Angew . Chem. 2013, 125, 1. doi: 10.1002/ange.201209858
7. [7]
  (7) Yan, N.; Hu, L.; Li, Y.;Wang, Y.; Zhong, H.; Hu, X. Y.; Kong, X. K.; Chen, Q.W. J. Phys. Chem. C 2012, 116, 7227. doi: 10.1021/jp2126009
8. [8]
  (8) Hong, S. H.; Bae, J. S.; Ahn, H. J. Met. Mater. Int. 2008, 14, 229. doi: 10.3365/met.mat.2008.04.229
9. [9]
  (9) Zhan, F. M.; Geng, B. Y.; Guo, Y. J. Chem . Eur . J. 2009, 15, 6169. doi: 10.1002/chem.200802561
10. [10]
  (10) Lu, Y.;Wang, Y.; Zou, Y. Q.; Jiao, Z.; Zhao, B.; He, Y. Q.;Wu, M. H. Electrochem. Commun. 2010, 12, 101. doi: 10.1016/j.elecom.2009.10.046
11. [11]
  (11) Shim, H.W.; Jin, Y. H.; Seo, S. D.; Lee, S. H.; Kim, D.W. ACS Nano 2011, 5, 443. doi: 10.1021/nn1021605
12. [12]
  (12) Ding, Y. H.; Zhang, P.; Long, Z. L.; Jiang, Y.; Huang, J. N.; Yan, W. J.; Liu, G. Mater. Lett. 2008, 62, 3410. doi: 10.1016/j.matlet.2008.03.033
13. [13]
  (13) Chou, S. L.;Wang, J. Z.; Liu, H. K.; Dou, S. X. J. Power Sources 2008, 182, 359. doi: 10.1016/j.jpowsour.2008.03.083
14. [14]
  (14) Rui, X. H.; Tan, H. T.; Sim, D. H.; Liu,W. L.; Xu, C.; Hng, H. H.; Yazami, R.; Lim, T. M.; Yan, Q. Y. J. Power Sources 2013, 222, 97. doi: 1016/j.jpowsour.2012.08.094
15. [15]
  (15) Wang, J. T.;Wang, Y.; Huang, B.; Yang, J. Y.; Tan, A.; Lu, S. G. Acta Phys. -Chim. Sin. 2014, 30, 305. [王建涛, 王耀, 黄斌, 杨娟玉, 谭翱, 卢世刚. 物理化学学报, 2014, 30, 305.] doi: 10.3866/PKU.WHXB201312022
16. [16]
  (16) Wang, X.; Guan, H.; Chen, S.; Li, H. Q.; Zhai, T. Y.; Tang, D. M.; Bando, Y.; lberg, D. Chem. Commun. 2011, 47, 12280. doi: 10.1039/c1cc15169j
17. [17]
  (17) Wang, G. L.; Liu, J. C.; Tang, S.; Li, H. Y.; Cao, D. X. J. Solid State Electrochem. 2011, 15, 2587. doi: 10.1007/s10008-010-1254-y
18. [18]
  (18) Park, J.; Moon,W. G.; Kim, G. P.; Nam, I.; Park, S.; Kim, Y.; Yi, J. Electrochim. Acta 2013, 105, 110. doi: 10.1016/j.electacta.2013.04.170
19. [19]
  (19) Cao, F.;Wang, D. Q.; Deng, R. P.; Tang, J. K.; Song, S. Y.; Lei, Y. Q.;Wang, S.; Su, S. Q.; Yang, X. G.; Zhang, H. J. Cryst. Eng. Commun. 2011, 13, 2123. doi: 10.1039/c0ce00392a
20. [20]
  (20) Li, C. C.; Yin, X. M.; Chen, L. B.; Li, Q. H.;Wang, T. H. Chem . Eur . J. 2010, 16, 5215. doi: 10.1002/chem.200901632
21. [21]
  (21) Ding, P.; Xu, Y. L.; Sun, X. F. Acta Phys. -Chim. Sin. 2013, 29, 293. [丁朋, 徐友龙, 孙孝飞. 物理化学学报, 2013, 29, 293.] doi: 10.3866/PKU.WHXB201211142
22. [22]
  (22) Wang, Y.; Xia, H.; Lu, L.; Lin, J. Y. ACS Nano 2010, 4, 1425. doi: 10.1021/nn9012675
23. [23]
  (23) Wang, Y. F.; Zhang, L. J. J. Power Sources 2012, 209, 20. doi: 10.1016/j.jpowsour.2012.02.074
24. [24]
  (24) Zhan, L.;Wang, Y. L.; Qiao,W. M.; Ling, L. C.; Yang, S. B. Electrochim. Acta 2012, 78, 440. doi: 10.1016/j.electacta.2012.06.017
25. [25]
  (25) Liu, D. Q.; Yang, Z. B.;Wang, P.; Li, F.;Wang, D. S.; He, D. Y. Nanoscale 2013, 5, 1917. doi: 10.1039/c2nr33383j
26. [26]
  (26) Keng, P. Y.; Kim, B. Y.; Shim, I. B.; Sahoo, R.; Veneman, P. E.; Armstrong, N. R.; Yoo, H.; Pemberton, J. E.; Bull, M. M.; Griebel, J. J.; Ratcliff, E. L.; Nebesny, K. G.; Pyun, J. ACS Nano 2009, 3, 3143. doi: 10.1021/nn900483w
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
5. [5]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
6. [6]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
7. [7]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
8. [8]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
9. [9]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
10. [10]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
11. [11]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
12. [12]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
13. [13]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
14. [14]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
15. [15]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
16. [16]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
17. [17]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
18. [18]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
19. [19]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
20. [20]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942

Get Citation

PDF

XML

Metrics

PDF Downloads(581)
Abstract views(703)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Modification of a Lamellar Co3O4 Anode for Lithium-Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and Modification of a Lamellar Co₃O₄ Anode for Lithium-Ion Batteries