Citation: LIU Fen, XIE Dan-Hua, ZHAO Jian-Xi. Salt Effects on the Network-Like Aggregates of Gemini Surfactant Studied by Dynamic Light Scattering[J]. Acta Physico-Chimica Sinica, ;2014, 30(6): 1142-1147. doi: 10.3866/PKU.WHXB201404011 shu

Salt Effects on the Network-Like Aggregates of Gemini Surfactant Studied by Dynamic Light Scattering

1.
Institute of Colloid and Interface Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China

Received Date: 21 January 2014
Available Online: 1 April 2014
Fund Project:

The effects of different salts on the self-assembly of the carboxylate Gemini surfactant O,O'-bis (sodium 2-dodecylcarboxylate)-p-dibenzenediol (referred to as C₁₂φ₂C₁₂) were studied using dynamic light scattering measurements. The results showed that the addition of salts induced the transition of the networklike aggregates into two new aggregates with small (hydrodynamic radii R_h,app of several nanometers) and large (R_h,app>100 nm) sizes, which coexisted in solution. A solubilization test using a 1,6-diphenyl-1,3,5-hexatriene (DPH) probe confirmed that the small aggregates were spherical micelles with a core-shell structure. Rheological measurements suggested that the large aggregates were threadlike micelles. The aggregate transition was attributed to the instability of the initially formed network-like aggregates. The added counter-ions associated with the head-groups of C₁₂φ₂C₁₂, which destroyed the hydrophile-lipophile balance and resulted in the aggregate transition. The salt effect followed the order: MgCl₂>NaCl, Bu₄NBr>Me₄NBr>Et₄NBr>Pr₄NBr, where Bu₄NBr is special and not in the order of electrostatic attraction since it provides an additional force through the hydrophobic interaction of its butyls with the alkyl tails of C₁₂φ₂C₁₂.
- Gemini surfactant,
- Long rigid spacer,
- Network-like aggregate,
- Aggregate transition,
- Salt effect
1. [1]
  
  (1) Zana, R.; Benrraou, M.; Rueff, R. Langmuir 1991, 7, 1072. doi: 10.1021/la00054a008
2. [2]
  (2) Alami, E.; Beinert, G.; Marie, P.; Zana, R. Langmuir 1993, 9, 1465.
3. [3]
  (3) Danino, D.; Talmon, Y.; Zana, R. Langmuir 1995, 11, 1448. doi: 10.1021/la00005a008
4. [4]
  (4) Zana, R.; In, M.; Lévy, H.; Duportail, G. Langmuir 1997, 13, 5552. doi: 10.1021/la970369a
5. [5]
  (5) Hirata, H.; Hattori, N.; Ishida, M.; Okabayashi, H.; Frusaka, M.; Zana, R. J. Phys. Chem. 1995, 99, 17778. doi: 10.1021/j100050a017
6. [6]
  (6) De, S.; Aswal, V. K.; yal, P. S.; Bhattacharya, S. J. Phys. Chem. 1996, 100, 11664. doi: 10.1021/jp9535598
7. [7]
  (7) Zana, R. J. Colloid Interface Sci. 2002, 248, 203. doi: 10.1006/jcis.2001.8104
8. [8]
  (8) Zana, R. Adv. Colloid Interface Sci. 2002, 97, 205. doi: 10.1016/S0001-8686(01)00069-0
9. [9]
  (9) Xie, D. H.; Zhao, J. X. Langmuir 2013, 29, 545. doi: 10.1021/la304160s
10. [10]
  (10) Song, B. L.; Hu, Y. F.; Zhao, J. X. J. Colloid Interface Sci. 2009, 333, 820. doi: 10.1016/j.jcis.2009.02.030
11. [11]
  (11) Song, B. L.; Hu, Y. F.; Song, Y. M.; Zhao, J. X. J. Colloid Interface Sci. 2010, 341, 94. doi: 10.1016/j.jcis.2009.09.023
12. [12]
  (12) Xie, D. H.; Zhao, J. X.; You, Y. Soft Matter 2013, 9, 6532. doi: 10.1039/c3sm50694k
13. [13]
  (13) Xie, D. H.; Zhao, J. X.; Liu, L.; You, Y.;Wei, X. L. Acta Phys. -Chim. Sin. 2013, 29, 1534. [谢丹华, 赵剑曦, 刘琳, 游毅, 魏西莲. 物理化学学报, 2013, 29, 1534.] doi: 10.3866/PKU.WHXB201304252
14. [14]
  (14) Brown,W.; Johansson, K.; Almgren, M. J. Phys. Chem. 1989, 93, 5888.
15. [15]
  (15) Tanford, C. J. Phys. Chem. 1972, 76, 3020. doi: 10.1021/j100665a018
16. [16]
  (16) Khatua, D.; Dey, J. J. Phys. Chem. B 2007, 111, 124. doi: 10.1021/jp065225w
17. [17]
  (17) Berr, S. S.; Coleman, M. J.; Marriott Jones, R. R.; Johnson, J. S., Jr. J. Phys. Chem. 1986, 90, 6492. doi: 10.1021/j100282a017
18. [18]
  (18) Almgren, M.; Swarup, S. J. Phys. Chem. 1983, 87, 876. doi: 10.1021/j100228a036
19. [19]
  (19) Mazer, N. A.; Benedek, G. B.; Carey, M. C. J. Phys. Chem. 1976, 80, 1075. doi: 10.1021/j100551a011
20. [20]
  (20) Imae, T.; Ikeda, S. J. Phys. Chem. 1986, 90, 5216. doi: 10.1021/j100412a065
21. [21]
  (21) Shrestha, R. G.; Shrestha, L. K.; Aramaki, K. J. Colloid Interface Sci. 2007, 311, 276. doi: 10.1016/j.jcis.2007.02.050
22. [22]
  (22) Macosko, C.W. Rheology: Principles, Measurements and Applications;Wiley-VCH: New York, 1994.
23. [23]
  (23) Oda, R.; Narayanan, J.; Hassan, P. A.; Manohar, C.; Salkar, R. A.; Kern, F.; Candau, S. J. Langmuir 1998, 14, 4364. doi: 10.1021/la971369d
1. [1]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
2. [2]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
3. [3]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
4. [4]
  Yanyang Li , Zongpei Zhang , Kai Li , Shuangquan Zang . Ideological and Political Design for the Comprehensive Experiment of the Synthesis and Aggregation-Induced Emission (AIE) Performance Study of Salicylaldehyde Schiff-Base. University Chemistry, 2024, 39(2): 105-109. doi: 10.3866/PKU.DXHX202307020
5. [5]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
6. [6]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
7. [7]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
8. [8]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
9. [9]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
10. [10]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
11. [11]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
12. [12]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
13. [13]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
14. [14]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
15. [15]
  Quanliang Chen , Zhaohui Zhou . Research on the Active Site of Nitrogenase over Fifty Years. University Chemistry, 2024, 39(7): 287-293. doi: 10.3866/PKU.DXHX202310133
16. [16]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
17. [17]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
18. [18]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
19. [19]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
20. [20]
  Honglian Liang , Xiaozhe Kuang , Fuping Wang , Yu Chen . Exploration and Practice of Integrating Ideological and Political Education into Physical Chemistry: a Case on Surface Tension and Gibbs Free Energy. University Chemistry, 2024, 39(10): 433-440. doi: 10.12461/PKU.DXHX202405073

Get Citation

PDF

XML

Metrics

PDF Downloads(448)
Abstract views(501)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142