Citation: CAO Xu-Long, LI Jing, YANG Yong, ZHANG Ji-Chao, ZHANG Lei, ZHANG Lu, ZHAO Sui. Effects of Surfactants on Interfacial Shear Rheological Properties of Polymers for Enhanced Oil Recovery[J]. Acta Physico-Chimica Sinica, ;2014, 30(5): 908-916. doi: 10.3866/PKU.WHXB201403073 shu

Effects of Surfactants on Interfacial Shear Rheological Properties of Polymers for Enhanced Oil Recovery

CAO Xu-Long ¹ ,
LI Jing ² ,
YANG Yong ¹ ,
ZHANG Ji-Chao ¹ ,
ZHANG Lei ^2, ,
ZHANG Lu ^2, ,
ZHAO Sui ²

1.
1 Geological and Scientific Research Institute of Shengli Oilfield Co. Ltd., SINOPEC, Dongying 257015, Shandong Province, P. R. China;
2 Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received Date: 16 December 2013
Available Online: 7 March 2014
Fund Project:

The effects of surfactants, namely sodium dodecylbenzenesulfonate (SDBS) and hexadecyltrimethylammonium bromide (CTAB), on the interfacial shear rheological properties of partially hydrolyzed polyacrylamide (PHPAM) and hydrophobically modified polyacrylamide (HMPAM) solutions, which are used in oilfields, were studied using a biconical method. The experimental results show that the interfacial shear complex modulus of HMPAM is significantly higher than that of PHPAM, because an interfacial net structure can be formed by HMPAM molecules through hydrophobic interactions. The SDBS and CTAB molecules can form interfacial aggregates with hydrophobic blocks of HMPAM and destroy the interfacial net structure, which results in a significant decrease in the shear modulus with increasing surfactant concentration. At the same time, the properties of the interfacial film change from viscous to elastic. At low SDBS concentrations, the mixed adsorption film formed by PHPAM and a few SDBS molecules has enhanced strength. However, SDBS molecules can displace PHPAM molecules at the interface and weaken the film at higher surfactant concentrations. The cationic surfactant CTAB neutralizes the negative charge on PHPAM, leading to partial curling of the polymer chain, which decreases the film strength. Relaxation measurements confirmed our mechanism involving destruction of the interfacial net structure of HMPAM by the surfactant.
1. [1]
  
  (1) Taylor, K. C.; Nasr-El-Din, H. A. J. Petrol. Sci. Eng. 1998, 19, 265. doi: 10.1016/S0920-4105(97)00048-X
2. [2]
  (2) Taylor, K. C.; Nasr-El-Din, H. A. Colloids Surf. A 1998, 108, 49.
3. [3]
  (3) Shen, P. P.; Yu, J. Y. Fundamental Study on Extensively Enhanced Petroleum Recovery; Petroleum Industry Press: Beijing, 2001; pp 38-44. [沈平平, 俞稼镛. 大幅度提高石油采收率的基础研究. 北京: 石油工业出版社, 2001: 38-44.]
4. [4]
  (4) Wever, D. A. Z.; Picchioni, F.; Broekhuis, A. A. Prog. Polym. Sci. 2011, 36 (11), 1558. doi: 10.1016/j.progpolymsci.2011.05.006
5. [5]
  (5) Sun, H. Q.; Zhang, L.; Li, Z. Q.; Zhang, L.; Luo, L.; Zhao, S. Soft Matter 2011, 7 (17), 7601. doi: 10.1039/c1sm05234a
6. [6]
  (6) Wierenga, P. A.; Kosters, H.; Egmond, M. R.; Voragen, A. G. J.; de Jongh, H. H. J. Adv. Colloid Interface Sci. 2006, 119 (2-3), 131. doi: 10.1016/j.cis.2005.11.001
7. [7]
  (7) Kotsmar, C.; Pradines, V.; Alahverdjieva, V. S.; Aksenenko, E. V.; Fainerman, V. B.; Kovalchuk, V. I.; Kraegel, J.; Leser, M. E.; Noskov, B. A.; Miller, R. Adv. Colloid Interface Sci. 2009, 150 (1), 41.
8. [8]
  (8) Miller, R.; Ferri, J. K.; Javadi, A.; Kragel, J.; Mucic, N.; Wustneck, R. Colloid Polym. Sci. 2010, 288, 937. doi: 10.1007/s00396-010-2227-5
9. [9]
  (9) Kraegel, J.; Derkatch, S. R. Curr. Opin. Colloid Interfaces Sci. 2010, 15 (4), 246. doi: 10.1016/j.cocis.2010.02.001
10. [10]
  (10) Derkach, S. R.; Kragel, J.; Miller, R. Colloid J. 2009, 71 (1), 1. doi: 10.1134/S1061933X09010013
11. [11]
  (11) Wang, Y. Y.; Dai, Y. H.; Zhang, L.; Tang, K.; Luo, L.; ng, Q. T.; Zhao, S.; Li, M. Y.; Wang, E. J.; Yu, J. Y. J. Colloid Interface Sci. 2004, 280, 76. doi: 10.1016/j.jcis.2004.07.016
12. [12]
  (12) Luo, L.; Wang, D. X.; Zhang, L.; Zhao, S.; Yu, J. Y. J. Disper. Sci. Technol. 2007, 28 (2), 263. doi: 10.1080/01932690601059594
13. [13]
  (13) Wang, D. X.; Luo, L.; Zhang, L.; Zhao, S.; Wang, L.; ng, Q. T.; Liao, L.; Chu, Y. P.; Yu, J. Y. J. Disper. Sci. Technol. 2007, 28 (5), 725. doi: 10.1080/01932690701341843
14. [14]
  (14) Zhang, L.; Wang, X. C.; Yan, F.; Luo, L.; Zhang, L.; Zhao, S.; Yu, J. Y. Colloid Polym. Sci. 2008, 286, 1291. doi: 10.1007/s00396-008-1894-y
15. [15]
  (15) Cui, X. H.; Zhang, L.; Luo, L.; Zhang, L.; Zhao, S.; Yu, J. Y. Colloids Surf. A 2010, 369, 106. doi: 10.1016/j.colsurfa.2010.08.012
16. [16]
  (16) Xin, X.; Xu, G. Y.; Ge, L. L.; Chen, Y. J.; Wang, Y.; Zhang, X. H.; Guo, R. J. Disper. Sci. Technol. 2010, 31 (6), 727.
17. [17]
  (17) Ao, M.; Xu, G.; Kang, W.; Meng, L.; ng, H.; Zhou, T. Soft Matter 2011, 7 (3), 1199.
18. [18]
  (18) Lin, M. Q.; Wang, H.; Tian, D.; Mao, L. T.; Zong, H.; Li, M. Y. Petrochemical Technology 2011, 40 (7), 753. [林梅钦, 王浩, 田丹, 毛雷霆, 宗华, 李明远. 石油化工, 2011, 40 (7), 753.]
19. [19]
  (19) Guo, Y. M.; Li, M. Y.; He, Z. H.; Lin, M. Q. Appl. Chem. Ind. 2009, 38 (9), 1300. [郭亚梅, 李明远, 贺辉宗, 林梅钦. 应用化工, 2009, 38 (9), 1300.]
20. [20]
  (20) Kragel, J.; Derkatch, S. R.; Miller, R. Adv. Colloid Interface Sci. 2008, 144 (1-2), 38. doi: 10.1016/j.cis.2008.08.010
21. [21]
  (21) Maestro, A.; Bonales, L. J.; Ritacco, H.; Fischer, T. M.; Rubio, R. G.; Ortega, F. Soft Matter 2011, 7 (17), 7761. doi: 10.1039/c1sm05225j
22. [22]
  (22) Maas, M.; Bodnar, P. M.; Hess, U.; Treccani, L.; Rezwan, K. J. Colloid Interface Sci. 2013, 407, 529.
23. [23]
  (23) Wang, Y.; Dai, Y.; Zhang, L.; Luo, L.; Zhao, S.; Li, M.; Wang, E.; Yu, J. Macromolecules 2004, 37, 2930. doi: 10.1021/ma049923v
24. [24]
  (24) Zhu, Y.W.; Song, X.W.; Luo, L.; Zhang, L.; Zhao, S.; Yu, J. Y. Chem. J. Chin. Uinv. 2010, 31 (12), 2445. [祝仰文, 宋新旺, 罗澜, 张路, 赵濉, 俞稼镛. 高等学校化学学报, 2010, 31 (12), 2445.]
25. [25]
  (25) Zong, H.; Wang, L.; Fang, H. B.; Mao, L. T.; Wang, Y. H.; Zhang, L.; Zhao, S.; Yu, J. Y. Acta Phys. -Chim. Sin. 2010, 26 (11), 2982. [宗华, 王磊, 方洪波, 毛雷霆, 王宇慧, 张路, 赵濉, 俞稼镛. 物理化学学报, 2010, 26 (11), 2982.] doi: 10.3866/PKU.WHXB20101105
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