Citation: YANG Jia-Ping, YU Hui-Yao, HE Yu-Xiu, XIE Jing-Xuan, BI Wen-Yan, GAO Qing-Yu. Model Simulation and Analysis of Spatiotemporal Dynamics for the Electro-Oxidation of Sulfide on Platinum[J]. Acta Physico-Chimica Sinica, ;2014, 30(4): 686-692. doi: 10.3866/PKU.WHXB201402142 shu

Model Simulation and Analysis of Spatiotemporal Dynamics for the Electro-Oxidation of Sulfide on Platinum

1.
College of Chemical Engineering, China University of Mining and Technology, Xuzhou 221116, Jiangsu Province, P. R. China

Received Date: 6 December 2013
Available Online: 14 February 2014
Fund Project:

Based on the reaction mechanism of the electro-oxidation of sulfide on platinum, we propose a simplified model for studying the spatiotemporal dynamics on the electrode surface in the oscillatory region of the N-shaped negative differential resistance (N-NDR) through numerical simulation. Simple and complex current oscillations were observed during the homogeneous simulation, and these were caused by coupling between one positive feedback, i.e., double-layer potential autocatalysis, and two negative feedbacks consisting of a mass-transport limited step and a poison-adsorption process. To obtain a better simulation of the experimental situation, the transport of electroactive species in both the parallel and vertical directions of the electrode was taken into account to simulate pattern formation on the electrode. The model simulations gave complicated patterns including twinkling-eye patterns and traveling waves, which agree qualitatively with the experimental results and possess the same evolution principles. Meanwhile, for certain parameters more complex patterns were obtained, e.g., two-arm spiral waves of the double-layer potential. This opens an interesting perspective in the explanation and prediction of pattern formation in electrochemical systems.
- N-shaped negative differential resistance,
- Oscillation and complex oscillation,
- Pattern formation,
- Electrochemical oxidation of sulfide,
- Model simulation
1. [1]
  
  (1) O′Brien, J. A.; Hinkley, J. T.; Donne, S.W. Electrochim. Acta 2011, 56, 4224. doi: 10.1016/j.electacta.2011.01.092
2. [2]
  (2) Dutta, P. K.; Rabaey, K.; Yuan, Z.; Keller, J. Water Res. 2008, 42, 4965. doi: 10.1016/j.watres.2008.09.007
3. [3]
  (3) Cai, J.; Zheng, P. Bioresource Technol. 2013, 128, 760. doi: 10.1016/j.biortech.2012.08.046
4. [4]
  (4) Haner, J.; Bejan, D.; Bunce, N. J. J. Appl. Electrochem. 2009, 39, 1733. doi: 10.1007/s10800-009-9873-7
5. [5]
  (5) Helms, H.; Schlömer, E.; Jansen,W. Monatsh. Chem. 1998, 129, 617.
6. [6]
  (6) Miller, B.; Chen, A. J. Electroanal. Chem. 2006, 588, 314. doi: 10.1016/j.jelechem.2006.01.006
7. [7]
  (7) Strasser, P.; Eiswirth, M.; Koper, M. T. M. J. Electroanal. Chem. 1999, 478, 50. doi: 10.1016/S0022-0728(99)00412-X
8. [8]
  (8) Kiss, I. Z.; Sitta, E.; Varela, H. J. Phys. Chem. C 2012, 116, 9561.
9. [9]
  (9) Feng, J.; Gao, Q.; Xu, L.;Wang, J. Electrochem. Commun. 2005, 7, 1471. doi: 10.1016/j.elecom.2005.10.004
10. [10]
  (10) Zhao, Y.;Wang, S.; Varela, H.; Gao, Q.; Hu, X.; Yang, J.; Epstein, I. R. J. Phys. Chem. C 2011, 115, 12965. doi: 10.1021/jp202881h
11. [11]
  (11) Yang, J.; Song, Y.; Varela, H.; Epstein, I. R.; Bi,W.; Yu, H.; Zhao, Y.; Gao, Q. Electrochim. Acta 2013, 98, 116. doi: 10.1016/j.electacta.2013.03.042
12. [12]
  (12) Waterston, K.; Bejan, D.; Bunce, N. J. Appl. Electrochem. 2007, 37, 367. doi: 10.1007/s10800-006-9267-z
13. [13]
  (13) Parker, G. K.;Watling, K. M.; Hope, G. A.;Woods, R. Colloid. Surf. A: Physicochem. Eng. Aspects 2008, 318, 151. doi: 10.1016/j.colsurfa.2007.12.029
14. [14]
  (14) O′Brien, J. A.; Hinkley, J. T.; Donne, S.W.; Lindquist, S. E. Electrochim. Acta 2010, 55, 573. doi: 10.1016/j.electacta.2009.09.067
15. [15]
  (15) Hamilton, I. C.;Woods, R. J. Appl. Electrochem. 1983, 13, 783. doi: 10.1007/BF00615828
16. [16]
  (16) Krischer, K. In Advance in Electrochemical Science and Engineering;Wielry-VCH:Weinheim, 2003; Vol. 8, pp 90-203.
17. [17]
  (17) Kapusta, S.; Viehbeck, A.;Wilhelm, S. M.; Hackerman, N. J. Electroanal. Chem. Interfacial Electrochem. 1983, 153, 157. doi: 10.1016/S0022-0728(83)80011-4
18. [18]
  (18) Krischer, K.; Varela, H.; Bîrzu, A.; Plenge, F.; Bonnefont, A. Electrochim. Acta 2003, 49, 103. doi: 10.1016/j.electacta.2003.04.006
19. [19]
  (19) Mazouz, N.; Krischer, K. J. Phys. Chem. B 2000, 104, 6081. doi: 10.1021/jp000203+
20. [20]
  (20) Koper, M. T. M. Electrochim. Acta 1992, 37, 1771. doi: 10.1016/0013-4686(92)85080-5
21. [21]
  (21) Flätgen, G.; Krischer, K. J. Chem. Phys. 1995, 103, 5428. doi: 10.1063/1.470578
22. [22]
  (22) Galea, N. M.; Kadantsev, E. S.; Ziegler, T. J. Phys. Chem. C 2007, 111, 14457. doi: 10.1021/jp072450k
23. [23]
  (23) Fu, Y.; Zu, C.; Manthiram, A. J. Am. Chem. Soc. 2013, 135 (48), 18044-7. doi: 10.1021/ja409705u
24. [24]
  (24) Flätgen, G.; Krischer, K. Phys. Rev. E 1995, 51, 3397. doi: 10.1103/PhysRevB.51.3397
25. [25]
  (25) Mazouz, N.; Flätgen, G.; Krischer, K. Phys. Rev. E 1997, 55, 2260. doi: 10.1103/PhysRevE.55.2260
26. [26]
  (26) Plenge, F.; Li, Y. J.; Krischer, K. J. Phys. Chem. B 2004, 108, 14255. doi: 10.1021/jp037955z
1. [1]
  Yuan Chun , Lijun Yang , Jinyue Yang , Wei Gao . Ideological and Political Design of BZ Oscillatory Reaction Experiment. University Chemistry, 2024, 39(2): 72-76. doi: 10.3866/PKU.DXHX202308072
2. [2]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
3. [3]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
4. [4]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
5. [5]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
6. [6]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
7. [7]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
8. [8]
  Cunling Ye , Xitong Zhao , Hongfang Wang , Zhike Wang . A Formula for the Calculation of Complex Concentrations Arising from Side Reactions and Its Applications. University Chemistry, 2024, 39(4): 382-386. doi: 10.3866/PKU.DXHX202310043
9. [9]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
10. [10]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
11. [11]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
12. [12]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
13. [13]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
14. [14]
  Ruilin Han , Xiaoqi Yan . Comparison of Multiple Function Methods for Fitting Surface Tension and Concentration Curves. University Chemistry, 2024, 39(7): 381-385. doi: 10.3866/PKU.DXHX202311023
15. [15]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
16. [16]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
17. [17]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
18. [18]
  Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016
19. [19]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
20. [20]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351

Get Citation

PDF

XML

Metrics

PDF Downloads(540)
Abstract views(708)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142