Citation: YAO Man-Li, DONG Yan-Yan, XIE Jing, JIA Ai-Ping, XIE Guan-Qun, HU Geng-Shen, LUO Meng-Fei. Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption[J]. Acta Physico-Chimica Sinica, ;2014, 30(4): 789-796. doi: 10.3866/PKU.WHXB201402123 shu

Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption

1.
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, Zhejiang Province, P. R. China

Received Date: 30 December 2013
Available Online: 12 February 2014
Fund Project:

Mesoporous ethane-silica nanotubes (E-SNTs) were synthesized using P123 as a template and 1,2-bis(trimethoxysilyl)ethane (BTME) as a silica source. E-SNTs were modified with polyethylenimine (PEI) as sorbents for CO₂ adsorption. These new composite sorbents were characterized by transmission electron microscopy (TEM), nitrogen adsorption/desorption, Fourier transform infrared (FTIR) spectroscopy, and thermal gravimetric analysis (TGA). We found that 75 ℃ is the optimal temperature for CO₂ adsorption. E-SNTs with a 50% (w) PEI loading (E-SNTs-50) exhibited a higher CO₂ adsorption capacity (3.32 mmol·g^-1) than the other materials. The E-SNTs-based sorbents show better CO₂ capture performance than the SBA-15-based sorbents. Additionally, CO₂ uptake was further enhanced to 3.75 mmol·g^-1 in the presence of moisture. Cyclic CO₂ adsorption-desorption test results indicated that the composite sorbents are stable and can be regenerated.
- Mesoporoussilica nanotube,
- Polyethylenimine,
- Adsorption,
- CO₂ capture
1. [1]
  
  (1) Samanta, A.; Zhao, A.; Shimizu, G. K. H.; Sarkar, P.; Gupta, R. Ind. Eng. Chem. Res. 2012, 51, 1438. doi: 10.1021/ie200686q
2. [2]
  (2) Liu, L.; Deng, Q. F.; Hou, X. X.; Yuan, Z. Y. J. Mater. Chem. 2012, 22, 15540.
3. [3]
  (3) Kamarudin, K. S. N.; Alias, N. Fuel Process. Technol. 2013, 106, 332. doi: 10.1016/j.fuproc.2012.08.017
4. [4]
  (4) Gupta, M.; da Silva, E. F.; Hartono, A.; Svendsen, H. F. J. Phys. Chem. B 2013, 117, 9457. doi: 10.1021/jp404356e
5. [5]
  (5) Zoannou, K. S.; Sapsford, D. J.; Griffiths, A. J. International Journal of Greenhouse Gas Control 2013, 17, 423. doi: 10.1016/j.ijggc.2013.05.026
6. [6]
  (6) Khoshnevisan, B.; Rafiee, S.; Omid, M.; Mousazadeh, H. Energy 2013, 55, 676. doi: 10.1016/j.energy.2013.04.021
7. [7]
  (7) Sema, T.; Naami, A.; Fu, K. Y.; Chen, G. Y.; Liang, Z. W.; Idem, R.; Tontiwachwuthikul, P. Chem. Eng. Sci. 2013, 100, 183. doi: 10.1016/j.ces.2012.12.030
8. [8]
  (8) Wang, X. X.; Schwartz, V.; Clark, J. C.; Ma, X. L.; Overbury, S. H.; Xu, X. C.; Song, C. S. J. Phys. Chem. C 2009, 113, 7260. doi: 10.1021/jp809946y
9. [9]
  (9) Veawab, A.; Tontiwachwuthikul;, P.; Chakma., A. Ind. Eng. Chem. Res. 1999, 38, 3917. doi: 10.1021/ie9901630
10. [10]
  (10) Xu, X.; Song, C.; Wincek, R.; Andresen, J. M.; Miller, B. G.; Scaroni, A. W. Fuel Chemistry Division Preprints 2003, 48, 162.
11. [11]
  (11) Wang, X. X.; Ma, X. L.; Song, C. S.; Locke, D. R.; Siefert, S.; Winans, R. E.; Mollmer, J.; Lange, M.; Moller, A.; Glaser, R. Microporous Mesoporous Mater. 2013, 169, 103. doi: 10.1016/j.micromeso.2012.09.023
12. [12]
  (12) Choi, D. H.; Ryoo, R. J. Mater. Chem. 2010, 20, 5544. doi: 10.1039/c0jm00671h
13. [13]
  (13) Belmabkhout, Y.; Serna-Guerrero, R.; Sayari, A. Ind. Eng. Chem. Res. 2010, 49, 359. doi: 10.1021/ie900837t
14. [14]
  (14) Jo, C.; Kim, K.; Ryoo, R. Microporous Mesoporous Mater. 2009, 124, 45. doi: 10.1016/j.micromeso.2009.04.037
15. [15]
  (15) Liu, L.; Deng, Q. F.; Ma, T. Y.; Lin, X. Z.; Hou, X. X.; Liu, Y. P.; Yuan, Z. Y. J. Mater. Chem. 2011, 21, 16001. doi: 10.1039/c1jm12887f
16. [16]
  (16) Xu, X.; Song, C.; Andresen, J. M.; Miller, B. G.; Scaroni, A. W. Energy Fuels 2002, 16, 1463. doi: 10.1021/ef020058u
17. [17]
  (17) Ma, X. L.; Wang, X. X.; Song, C. S. J. Am. Chem. Soc. 2009, 131, 5777. doi: 10.1021/ja8074105
18. [18]
  (18) Liu, X.; Li, X. B.; Guan, Z. H.; Liu, J.; Zhao, J.; Yang, Y.; Yang, Q. H. Chem. Commun. 2011, 47, 8073. doi: 10.1039/c1cc12136g
19. [19]
  (19) Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, doi: 10.3878/j.issn.1006-9895.2013.13159
20. [20]
  (20) Feng, X. X.; Hu, G. S.; Hu, X.; Xie, G. Q.; Xie, Y. L.; Lu, J. Q.; Luo, M. F. Ind. Eng. Chem. Res. 2013, 52, 4221. 10.1021/ie301946p
21. [21]
  (21) Feng, X.X; Xie, J.; Hu, G. S.; Jia, A. P.; Xie, G. Q.; Luo, M.F. Acta Phys. -Chim. Sin. 2013, 29, 1266. [冯星星, 谢菁, 胡庚申, 贾爱平, 谢冠群, 罗孟飞. 物理化学学报. 2013, 29, 1266.] doi: 10.3866/PKU.WHXB201304091
22. [22]
  (22) Xu, X.; Song, C.; Andrésen, J. M.; Miller, B. G.; Scaroni, A. W. Microporous Mesoporous Mater. 2003, 62, 29. 10.1016/S1387-1811(03)00388-3
23. [23]
  (23) Son, W. J.; Choi, J. S.; Ahn, W. S. Microporous Mesoporous Mater. 2008, 113, 31. doi: 10.1016/j.micromeso.2007.10.049
24. [24]
  (24) Satyapal, S.; Filburn, T.; Trela, J.; Strange, J. Energy Fuels 2001, 15, 250. doi: 10.1021/ef0002391
1. [1]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
2. [2]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
3. [3]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
4. [4]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
5. [5]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
6. [6]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
7. [7]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
8. [8]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
9. [9]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
10. [10]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
11. [11]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
12. [12]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
13. [13]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
14. [14]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
15. [15]
  Muhammad Humayun , Mohamed Bououdina , Abbas Khan , Sajjad Ali , Chundong Wang . Designing single atom catalysts for exceptional electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100193-100193. doi: 10.1016/j.cjsc.2023.100193
16. [16]
  Hong Dong , Feng-Ming Zhang . Covalent organic frameworks for artificial photosynthetic diluted CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100307-100307. doi: 10.1016/j.cjsc.2024.100307
17. [17]
  Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
18. [18]
  Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO₂ adsorption and conversion: Modification methods, reaction condition, and CO₂ hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
19. [19]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
20. [20]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421

Get Citation

PDF

XML

Metrics

PDF Downloads(572)
Abstract views(753)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO2 Adsorption

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption