Citation: ZHAO Hai-Na, CHENG Xin-Hao, ZHAO Ou-Di, HUANG Jian-Bin, LIU Chen-Jiang, ZHAO Bo. Mixed Cationic and Anionic Surfactant Systems Achieve Ultra-Low Interfacial Tension in the Karamay Oil Field[J]. Acta Physico-Chimica Sinica, ;2014, 30(4): 693-698. doi: 10.3866/PKU.WHXB201402121 shu

Mixed Cationic and Anionic Surfactant Systems Achieve Ultra-Low Interfacial Tension in the Karamay Oil Field

1.
1 Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, College of Chemistry and chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China;
2 College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China;
3 Xinjiang Keli New Technology Development Ltd., Karamay 834099, Xinjiang Uygur Autonomous Region, P. R. China

Received Date: 31 October 2013
Available Online: 12 February 2014
Fund Project:

Based on cationic and anionic surfactant mixed systems, ultra-low interfacial tension was achieved in the Karamay oil field systems. Upon the addition of a non-ionic third component, the solubility of the mixed cationic-anionic surfactant systems increased significantly. The mixed surfactant ratio and the concentration were determined by the application in the five areas of the Karamay oil field. The interfacial tension in some real systems was found to be around 10^-4 mN·m^-1. These cationic and anionic surfactant mixed systems have a super-resistance adsorption capacity. The results show that after 72 h of quartz adsorption, these systems can still reduce the interfacial tension to an ultra-low level.
- Cationic and anionic surfactant,
- Non-ionic protectant,
- Ultra-low interfacial tension,
- Enhanced oil recovery,
- Resistance adsorption capacity
1. [1]
  
  (1) Ding, Y.; Yuan, Y. T.; Lü, S. J.; Shan, C. J.; Hu, H. B. Inner Mon lia Petrochemical Industry 2004, No. 6, 121. [丁颖, 袁英同, 吕少军, 单长军, 胡红波. 内蒙古石油化工, 2004, No. 6, 121.]
2. [2]
  (2) Kang,W. L.; Liu, S. R.; Meng, L.W.;Wang, Z.W.; Zhou , Y. Oil & Gas Journal 2009, 31 (3), 99. [康万利, 刘述忍, 孟令伟, 王志伟, 周阳. 石油天然气学报, 2009, 31 (3), 99.]
3. [3]
  (3) Pang, L. L.; Ning, Y. Q. Inner Mon lia Petrochemical Industry 2010, No. 8, 142. [庞丽丽, 宁宇清. 内蒙古石油化工, 2010, No. 8, 142.]
4. [4]
  (4) Liu, Q. C. Science Technology and Engineering 2011, 11 (10), 2185. [刘其成. 科学技术与工程, 2011, 11 (10), 2185.]
5. [5]
  (5) Wang, Y. F. Surfactant and Its Applications in Oil Fields; Petroleum Industry Press: Beijing, 1995; pp 2-20. [王云峰. 表面活性剂及其在油气田中的应用. 北京: 石油工业出版社,1995: 2-20.]
6. [6]
  (6) Paul, G.W.; Lake, L.W.; Pope, G. A. A Simplified Predictive Model for Micellar-Polymer Flooding; SPE California Regional Meeting, San Francisco, California, USA, March 24-26, 1982.
7. [7]
  (7) Chen, Z. H.; Li, H. B.; Cao, B. G. Offshore Oil 2005, 25 (3), 53. [陈中华, 李华斌, 曹宝格. 海洋石油, 2005, 25 (3), 53.]
8. [8]
  (8) Lake, L.W.; Stock, L. G.; Lawson, J. B. Screening Estimation of Recovery Efficiency and Chemical Requirements for Chemical Flooding; SPE Symposium on Improved Methods of Oil Recovery, Tulsa, Oklahoma, USA, April 16-17, 1978.
9. [9]
  (9) Kang,W. L.; Liu, Y. J. China Surfactant Detergent & Cosmetics 2000, No. 4, 30. [康万利, 刘永建. 日用化学工业, 2000, No.4, 30.]
10. [10]
  (10) Kang,W. L.; Shan, X. L. Petroleum Geology & Oil Field Development in Daqing 1998, 17 (2), 32. [康万利, 单希林. 大庆石油地质与开发, 1998, 17 (2), 32.]
11. [11]
  (11) Zhang, L.; Luo, L.; Zhao, S.; Yu, J. Y. Acta Phys. -Chim. Sin. 2001, 17 (1), 62. [张路, 罗澜, 赵濉, 俞稼镛. 物理化学学报, 2001, 17 (1), 62.] doi: 10.3866/PKU.WHXB20010113
12. [12]
  (12) Fulcher, R. A., Jr.; Ertekin, T.; Stahl, C. D. Journal of Petroleum Technology 1985, 37 (2), 249.
13. [13]
  (13) Li, Z. Q.; Guo, X. L.;Wang, H. Y.; Li, Q. H.; Yuan, S. L.; Xu, G. Y.; Liu, C. B. Acta Phys. -Chim. Sin. 2009, 25 (1), 6. [李振泉, 郭新利, 王红艳, 李青华, 苑世领, 徐桂英, 刘成卜. 物理化学学报, 2009, 25 (1), 6.] doi: 10.3866/PKU.WHXB20090102
14. [14]
  (14) Li, S. J.; Yang, Z. Y.; Song, K. P.; Kang,W. L. Acta Petrolei Sinica 2003, 24 (5), 72. [李世军, 杨振宇, 宋考平, 康万利. 石油学报, 2003, 24 (5), 72.]
15. [15]
  (15) Zhao, G. X.; Zhu, B. Y. Principles of Surfactant Action; China Light Industry Press: Beijing, 2003; pp 356-382. [赵国玺, 朱瑶. 表面活性剂作用原理. 北京: 中国轻工业出版社,2003: 356-382.]
16. [16]
  (16) Zhu, B. Y.; Shi, H. T.; Huang, J. B.; He, X. Acta Chim. Sin. 2001, 59, 913. [朱瑶, 石洪涛, 黄建滨, 何煦. 化学学报, 2001, 59, 913.]
17. [17]
  (17) Zhao, G. X. Physical Chemistry of Surfactants; Peking University Press: Beijing, 1984; pp 179-230. [赵国玺. 表活性剂物理化学. 北京: 北京大学出版社, 1984: 179-230.]
18. [18]
  (18) Kang,W. L.; Dong, X. G. Application of Surfactant in Oil Field; Chemical Industry Press: Beijing, 2005; pp 32-45. [康万利,董喜贵. 表面活性剂在油田中的应用. 北京: 化学工业出版社,2005: 32-45.]
19. [19]
  (19) Han, X.; Cheng, X. H.;Wang, J.; Huang, J. B. Acta Phys. -Chim. Sin. 2012, 28 (1), 146. [韩霞, 程新皓, 王江, 黄建滨. 物理化学学报, 2012, 28 (1), 146.] doi:10.3866/PKU.WHXB201228146
20. [20]
  (20) Rubingh, D. N. Mixed Micelle Solutions, in Solution Chemistry of Surfactants; Springer: New York, 1979; pp 337-354.
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