Citation: ZHANG Chen, ZHAO Jing-Mao. Synergistic Inhibition Effect of Imidazoline Ammonium Salt and Sodium Dodecyl Sulfate in CO₂ System[J]. Acta Physico-Chimica Sinica, ;2014, 30(4): 677-685. doi: 10.3866/PKU.WHXB201402111 shu

Synergistic Inhibition Effect of Imidazoline Ammonium Salt and Sodium Dodecyl Sulfate in CO₂ System

ZHANG Chen ¹ ,
ZHAO Jing-Mao ^1,2,

1.
1 College of Material Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China;
2 Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing 100029, P. R. China

Received Date: 11 September 2013
Available Online: 11 February 2014
Fund Project:

The synergistic inhibition effect of the imidazoline ammonium salt (IAS) and sodium dodecyl sulfate (SDSH) on the corrosion of Q235 carbon steel in a CO₂ saturated brine solution was studied by weight loss, electrochemical impedance spectroscopy (EIS), Tafel polarization measurements, X-ray photoelectron spectrometry (XPS), and scanning electron microscopy (SEM). We found that in the CO₂ saturated brine solution, a od synergistic inhibition effect exists between IAS and low concentrations of SDSH, and the most significant synergistic inhibition occurred at a concentration ratio of 1:1 (50 mg·L^-1:50 mg·L^-1) with an inhibition efficiency of 88.5%. However, anta nism occurs upon mixing IAS with a high concentration of SDSH. In this paper, the mechanisms of the synergistic and anta nistic effects are analyzed using a reasonable adsorption model. od corrosion inhibition on Q235 carbon steel was also found when only using a high concentration of SDSH with an inhibition efficiency of about 90%. Both the adsorption processes of SDSH and IAS on the surface of Q235 carbon steel are spontaneous processes and the former process complies with the Frumkin adsorption model while the later complies with the Temkin adsorption model.
- CO₂ corrosion,
- Anionic surfactant,
- Adsorption,
- Synergistic effect,
- Anta nistic effect
1. [1]
  
  (1) Sun, L.; Xu, Q. L.; Fang, J. Welded Pipe & Tube 2009,32(3),23. [孙丽, 徐庆磊, 方炯. 焊管,2009, 32(3), 23]
2. [2]
  (2) Li, Y. T.; Wang, L. Y.; Shi, D. Q. Mater. Prot. 2011, 44(12), 50. [李言涛, 王路遥, 史德青. 材料保护, 2011, 44(12),50.]
3. [3]
  (3) Wu, Y. S.; Zheng, J. S. Electrochemical Protection and Application of Corrosion Inhibitor Technology, 1st ed; Chemical Industry Press: Beijing, 2006; pp 502-506. [吴荫顺, 郑家燊. 电化学保护和缓蚀剂应用技术, 第1 版; 北京:化学工业出版社, 2006: 502-506.]
4. [4]
  (4) Bouklah, M.; Hammouti, B.; Aouniti, A.; Benkaddour, M.; Bouyanzer, A. Appl. Surf. Sci. 2006,252(18), 6236. doi: 10.1016/j.apsusc.2005.08.026
5. [5]
  (5) Çalιskan, N.; Bilgiç, S. Appl. Surf. Sci. 2000, 15(2-3), 128.
6. [6]
  (6) Lv, Z. P.; Zheng, J. S.; Peng, F. M. Corros. Prot. 1999, 20(9), 395. [吕战鹏, 郑家燊, 彭芳明. 腐蚀与防护, 1999, 20(9), 395.]
7. [7]
  (7) Okafor, P. C.; Liu, C. B.; Liu, X.; Zheng, Y. G.; Wang, F.; Liu, C. Y.; Wang, F. J. Solid State Electrochem. 2010, 14(8), 1367. doi: 10.1007/s10008-009-0963-6
8. [8]
  (8) Zhao, J. M.; Liu H. X.; Di W.; Zuo Y. Electrochem. 2004, 10(4), 440. [赵景茂, 刘鹤霞, 狄伟, 左禹. 电化学, 2004, 10(4), 440. ]
9. [9]
  (9) Zhao, J. M.; Chen, G. H. J. Chin. Soc. Corros. Prot. 2013, 33(3), 226. [赵景茂, 陈国浩. 中国腐蚀与防护学报, 2013, 33(3), 226. ]
10. [10]
  (10) Zhao, T. P. J. Kunming Inst. Technol. 1995, 20(2), 95. [赵天培. 昆明工学院学报, 1995, 20(2),95.]
11. [11]
  (11) Mu, C. N.; Li, L.; Zhao, T. P. Chem. Cleaning 1999, 15(1), 1. [木冠南, 李琳, 赵天培. 化学清洗, 1999, 15(1), 1.]
12. [12]
  (12) Yang, S. P.; Xu, H.; Mu, C. Y. J. Zhengzhou Univ. (Nat. Sci. Ed.) 1996, 28(Suppl. 2), 91. [杨仕平,徐虹, 穆翠英. 郑州大学学报(自然科学版), 1996, 28(增刊.2), 91.]
13. [13]
  (13) Deng, S. D.; Li, X. H.; Bai, W.; Fu, H.; Mu, G. N. Cleaning World 2007, 23(7), 1. [邓书端, 李向红, 白玮, 付惠, 木冠南. 清洗世界, 2007, 23(7), 1.]
14. [14]
  (14) Yuan, L. B.; Liu, X. X.; Zhao, Q. R.; Li, X. H.; Mu, G. N. J. Yunnan Norm. Univ.2003, 23(6), 58.[袁朗白, 刘晓轩, 赵黔榕, 李向红, 木冠南. 云南师范大学学报, 2003, 23(6), 58. ]
15. [15]
  (15) Zhang, J.; Zhu, Z. Q.; Zhang, H. B.; Liu, Q. J. J Funct. Mater. 2004, 35, 2069. [张瑾, 朱忠其, 张海斌, 柳清菊. 功能材料, 2004, 35, 2069. ]
16. [16]
  (16) An, Y.; Xu, Q. Plating & Finishing 2012, 34(3), 228. [安洋, 徐强. 电镀与精饰, 2012, 34(3),228. ]
17. [17]
  (17) Xu, X. M.; Ge, H. H.; Wu, J. N.; Sun, R.; Han, J. X.; Xu, H. L.; Liu, Z. Z. Corros. Prot. 2012,33(9), 740. [徐学敏, 葛红花, 吴佳妮, 孙冉, 韩建勋, 许贺丽, 刘坐镇. 腐蚀与防护, 2012,33(9), 740. ]
18. [18]
  (18) Zhao, J. M.; Li, J. Acta Phys.-Chim.Sin.2012, 28 (03), 623. [赵景茂, 李俊. 物理化学学报, 2012, 28 (03), 623.] doi: 10.3866/PKU.WHXB201112293
19. [19]
  (19) Gu, N.; Li, C. M. J Hebei Acad. Sci. 2001, 18(4), 231. [谷宁, 李春梅. 河北省科学院学报, 2001,18(4), 231.]
20. [20]
  (20) Gu, N.; Li, C. M. Surf. Technol. 2003, 32(1), 57. [谷宁, 李春梅. 表面技术, 2003, 32(1), 57]
21. [21]
  (21) Lalitha, A.; Ramesh, S.; Rajeswari, S. Electrochim. Acta. 2005, 51, 47. doi: 10.1016/j.electacta.2005.04.003
22. [22]
  (22) Gao, H.; Li, Q.; Dai, Y.; Luo, F.; Zhang, H. X. Corros. Sci. 2010, 52, 1603. doi: 10.1016/j.corsci.2010.01.033
23. [23]
  (23) Zhao, J. M.; Chen, G. H. Electrochim Acta. 2012, 69, 247. doi: 10.1016/j.electacta.2012.02.101
24. [24]
  (24) Wei, B. M. Metal Corrosion Theory and Application, 1st ed.; Chemical Industry Press: Beijing,1991; pp 272. [魏宝明. 金属腐蚀理论及应用, 第1 版; 北京:化学工业出版社, 1991: 272.]
25. [25]
  (25) Tavakoli, H.; Shahrabi, T.; Hosseini, M. Mater. Chem. Phys. 2008, No.109, 281.
26. [26]
  (26) Shi, J. J.; Sun, W. Corros. Sci. Prot. Technol. 2011, 23(5), 387. [施锦杰, 孙伟. 腐蚀科学与防护技术, 2011, 23(5), 387.]
27. [27]
  (27) Lebrini, M.; Lagrenee, M.; Vezin,H. Corros. Sci. 2005, 47, 485. doi: 10.1016/j.corsci.2004.06.001
28. [28]
  (28) Zhang, G. A.; Chen, C. F.; Lu, M. X. Mater. Chem. Phys. 2007, 105, 331. doi: 10.1016/j.matchemphys.2007.04.076
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Synergistic Inhibition Effect of Imidazoline Ammonium Salt and Sodium Dodecyl Sulfate in CO2 System

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Synergistic Inhibition Effect of Imidazoline Ammonium Salt and Sodium Dodecyl Sulfate in CO₂ System