Citation: ZHU Zhi, QI Lu, LI Wei, LIAO Xi-Ying. Preparation and Electrochemical Performance of 5 V LiNi_0.5Mn_1.5O₄ Cathode Material by the Composite Co-Precipitation Method for High Energy/High Power Lithium Ion Secondary Batteries[J]. Acta Physico-Chimica Sinica, ;2014, 30(4): 669-676. doi: 10.3866/PKU.WHXB201402102 shu

Preparation and Electrochemical Performance of 5 V LiNi_0.5Mn_1.5O₄ Cathode Material by the Composite Co-Precipitation Method for High Energy/High Power Lithium Ion Secondary Batteries

ZHU Zhi ¹ ,
QI Lu ^1, ,
LI Wei ^2,3 ,
LIAO Xi-Ying ³

1.
1 College of Chemistry and Molecular Engineering, Peking University, Beijing 100190, P. R. China;
2 School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083;
3 SYN Chemicals & Technology (Beijing) Co. Ltd., Beijing 100094, P. R. China

Received Date: 19 November 2013
Available Online: 10 February 2014

This research developed a novel composite co-precipitation method to prepare high performance LiNi_0.5Mn_1.5O₄ based on a traditional solid-state method. Ammonium oxalate/ammonium carbonate was used as a composite precipitator to deposit Ni/Mn ions. Combined with a facile hydrothermal treatment, stoichiometric LiNi_0.5Mn_1.5O₄ was obtained with a pure spinel structure and spherical hierarchical morphology. Electrochemical measurements indicate that the as-prepared LiNi_0.5Mn_1.5O₄ delivers a high capacity of 141.4 mAh·g^-1 and after 200 cycles under 0.3C, 1C, and 3C, the materials retained their capacities up to 96.3%, 94.4%, and 91.1%, respectively. Additionally, the capacity upon exposure to a low voltage of 4.0 V was efficiently eliminated by heat treatment and by a particular cooling process. Furthermore, the LiNi_0.5Mn_1.5O₄ materials with high energy and high power performances of 648.6 mWh·g^-1 and 7000mW·g^-1 were obtained because of different cation ordering.
- Lithium ion battery,
- Spinel lithium nickel magnesium oxide,
- High energy/high power,
- Co-precipitation method,
- Spherical hierarchical morphology
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Preparation and Electrochemical Performance of 5 V LiNi0.5Mn1.5O4 Cathode Material by the Composite Co-Precipitation Method for High Energy/High Power Lithium Ion Secondary Batteries

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通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Performance of 5 V LiNi_0.5Mn_1.5O₄ Cathode Material by the Composite Co-Precipitation Method for High Energy/High Power Lithium Ion Secondary Batteries